Year |
Citation |
Score |
2019 |
Panchenko VN, Babushkin DE, Bercaw JE, Brintzinger HH. Catalyst Speciation During -Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy-Formation and Partial Re-Activation of Zr-Allyl Intermediates. Polymers. 11. PMID 31146475 DOI: 10.3390/Polym11060936 |
0.637 |
|
2014 |
Babushkin DE, Panchenko VN, Brintzinger HH. Zirconium allyl complexes as participants in zirconocene-catalyzed α-olefin polymerizations. Angewandte Chemie (International Ed. in English). 53: 9645-9. PMID 25044470 DOI: 10.1002/Anie.201403673 |
0.343 |
|
2013 |
Lenton TN, Bercaw JE, Panchenko VN, Zakharov VA, Babushkin DE, Soshnikov IE, Talsi EP, Brintzinger HH. Formation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: an EPR- and NMR-spectroscopic study. Journal of the American Chemical Society. 135: 10710-9. PMID 23745750 DOI: 10.1021/Ja403170U |
0.771 |
|
2011 |
Baldwin SM, Bercaw JE, Henling LM, Day MW, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides: NMR-spectroscopic identification, crystallographic structure determination, and interconversion with other zirconocene cations. Journal of the American Chemical Society. 133: 1805-13. PMID 21244016 DOI: 10.1021/Ja1050428 |
0.801 |
|
2010 |
Baldwin SM, Bercaw JE, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides as participants in olefin polymerization catalysis. Journal of the American Chemical Society. 132: 13969-71. PMID 20860389 DOI: 10.1021/Ja105040R |
0.798 |
|
2008 |
Baldwin SM, Bercaw JE, Brintzinger HH. Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy. Journal of the American Chemical Society. 130: 17423-33. PMID 19032092 DOI: 10.1021/Ja8054723 |
0.776 |
|
2008 |
Babushkin DE, Panchenko VN, Timofeeva MN, Zakharov VA, Brintzinger HH. Novel zirconocene hydride complexes in homogeneous and in SiO 2-supported olefin-polymerization catalysts modified with diisobutylaluminum hydride or triisobutylaluminum Macromolecular Chemistry and Physics. 209: 1210-1219. DOI: 10.1002/Macp.200800084 |
0.382 |
|
2007 |
Babushkin DE, Brintzinger HH. Modification of methylaluminoxane-activated ansa-zirconocene catalysts with triisobutylaluminum-transformations of reactive cations studied by NMR spectroscopy. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 5294-9. PMID 17385201 DOI: 10.1002/Chem.200601801 |
0.341 |
|
2006 |
Babushkin DE, Naundorf C, Brintzinger HH. Distinct methylalumoxane(MAO)-derived Me-MAO- anions in contact with a zirconocenium cation--a 13C-NMR study. Dalton Transactions (Cambridge, England : 2003). 4539-44. PMID 17016564 DOI: 10.1039/B611028M |
0.313 |
|
2006 |
Wieser U, Schaper F, Brintzinger HH. Methylalumoxane (MAO)-derived MeMAO- anions in zirconocene-based polymerization catalyst systems - A UV-vis spectroscopic study Macromolecular Symposia. 236: 63-68. DOI: 10.1002/Masy.200690068 |
0.576 |
|
2005 |
Bryliakov KP, Kravtsov EA, Pennington DA, Lancaster SJ, Bochmann M, Brintzinger HH, Talsi EP. Active intermediates in ethylene polymerization over titanium bis(phenoxyimine) catalysts Organometallics. 24: 5660-5664. DOI: 10.1021/Om0505920 |
0.389 |
|
2005 |
Bryliakov KP, Babushkin DE, Talsi EP, Voskoboynikov AZ, Gritzo H, Schröder L, Damrau HRH, Wieser U, Schaper F, Brintzinger HH. Ansa-titanocene catalysts for α-Olefin polymerization. Syntheses, structures, and reactions with methylaluminoxane and boron-based activators Organometallics. 24: 894-904. DOI: 10.1021/Om0492496 |
0.665 |
|
2005 |
Schröder L, Brintzinger HH, Babushkin DE, Fischer D, Mülhaupt R. Rac-Me2Si(2-Me-4-t-Bu-C5H2) 2ZrMe+: An alkyl zirconocenium cation stabilized by steric shielding against interaction with ancillary ligands Organometallics. 24: 867-871. DOI: 10.1021/Om049139Z |
0.337 |
|
2005 |
Bhriain NN, Brintzinger HH, Ruchatz D, Fink G. Polymeryl exchange between cmsa-zirconocene catalysts for norbornene-ethene copolymerization and aluminum or zinc alkyls Macromolecules. 38: 2056-2063. DOI: 10.1021/Ma0401166 |
0.368 |
|
2005 |
Kettunen M, Vedder C, Brintzinger HH, Mutikainen I, Leskelä M, Repo T. Alternative coordination modes in palladium(II)-diimino-bispyridine complexes with an axially chiral biphenyl backbone European Journal of Inorganic Chemistry. 1081-1089. DOI: 10.1002/Ejic.200400913 |
0.362 |
|
2005 |
Vedder C, Schaper F, Brintzinger HH, Kettunen M, Babik S, Fink G. Chiral iron(II) and cobalt(II) complexes with biphenyl-bridged bis(pyridylimine) ligands - Syntheses, structures and reactivities European Journal of Inorganic Chemistry. 1071-1080. DOI: 10.1002/Ejic.200400912 |
0.627 |
|
2004 |
Gritzo H, Schaper F, Brintzinger HH. Bis(η3-indenyl)bis(tetrahydrofuran)magnesium(II) Acta Crystallographica Section E: Structure Reports Online. 60: m1108-m1110. DOI: 10.1107/S1600536804016149 |
0.557 |
|
2004 |
Schaper F, Wrobel O, Schwörer R, Brintzinger HH. Me2Si(C5Me4)2Cr: Synthesis and crystal structure of a ligand-free ansa-chromocene Organometallics. 23: 3552-3555. DOI: 10.1021/Om049901X |
0.607 |
|
2004 |
Kettunen M, Vedder C, Schaper F, Leskelä M, Mutikainen I, Brintzinger HH. Chiral zirconium complexes with bianiline-based N4-donor ligands Organometallics. 23: 3800-3807. DOI: 10.1021/Om040011R |
0.619 |
|
2004 |
Wrobel O, Schaper F, Brintzinger HH. Bulky siloxyaluminum alkyls as models for Al2Me6-treated silica gel surfaces. Characterization of a dimethylaniline-stabilized dimethylaluminum cation Organometallics. 23: 900-905. DOI: 10.1021/Om030589L |
0.603 |
|
2003 |
Wrobel O, Schaper F, Wieser U, Gregorius H, Brintzinger HH. Siloxyaluminum alkyl cations: Syntheses, structures, and reactions related to activation of zirconocene catalysts on silica gel surfaces Organometallics. 22: 1320-1325. DOI: 10.1021/Om0207515 |
0.577 |
|
2002 |
Babushkin DE, Brintzinger HH. Activation of dimethyl zirconocene by methylaluminoxane (MAO)-size estimate for Me-MAO(-) anions by pulsed field-gradient NMR. Journal of the American Chemical Society. 124: 12869-73. PMID 12392434 DOI: 10.1021/Ja020646M |
0.361 |
|
2002 |
Selg P, Brintzinger HH, Schultz M, Andersen RA. Solution infrared spectroscopic studies on equilibrium reactions of CO with the decamethylmetallocenes Cp*2MII, where MII = Mg, Ca, Sr, Ba, Sm, Eu, Yb Organometallics. 21: 3100-3107. DOI: 10.1021/Om011045R |
0.308 |
|
2002 |
Wieser U, Schaper F, Brintzinger HH, Mäkelä NI, Knuuttila HR, Leskelä M. Effects of an interannular bridge on spectral and electronic properties of bis(cyclopentadienyl)- and bis(indenyl)zirconium (IV) complexes Organometallics. 21: 541-545. DOI: 10.1021/Om010770Z |
0.587 |
|
2002 |
Wieser U, Babushkin D, Brintzinger HH. Methyl-versus-chloride exchange as a measure of electron density at the metal center of ring-substituted zirconocene complexes Organometallics. 21: 920-923. DOI: 10.1021/Om0107688 |
0.371 |
|
2002 |
Schaper F, Geyer A, Brintzinger HH. Displacement of H3CB(C6F5)3 - anions from zirconocene methyl cations by neutral ligand molecules: Equilibria, kinetics, and mechanisms Organometallics. 21: 473-483. DOI: 10.1021/Om010671L |
0.626 |
|
2002 |
Hüttenhofer M, Schaper F, Brintzinger HH. 8-sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes: Formation from biscyclopentadienyl silanes by reaction with aminostannanes Journal of Organometallic Chemistry. 660: 85-90. DOI: 10.1016/S0022-328X(02)01775-8 |
0.617 |
|
2002 |
Royo E, Brintzinger HH. Mass spectrometry of polystyrene and polypropene ruthenium complexes. A new tool for polymer characterization Journal of Organometallic Chemistry. 663: 213-220. DOI: 10.1016/S0022-328X(02)01770-9 |
0.301 |
|
2002 |
Hüttenhofer M, Weeber A, Brintzinger HH. Mechanisms of Sn-to-Zr cyclopentadienyl transfer in the formation of Me2Si-bridged zirconocenes from sila-stanna-tetrahydro-s-indacenes Journal of Organometallic Chemistry. 663: 58-62. DOI: 10.1016/S0022-328X(02)01653-4 |
0.357 |
|
2001 |
Schaper F, Brintzinger H. Tetrahydrothiophene tris(pentafluorophenyl)borane Acta Crystallographica Section E Structure Reports Online. 58: o77-o78. DOI: 10.1107/S160053680102027X |
0.56 |
|
2001 |
Damrau HRH, Royo E, Obert S, Schaper F, Weeber A, Brintzinger HH. Racemo-selective synthesis of ansa-zirconocene derivates from zirconium biphenolate complexes Organometallics. 20: 5258-5265. DOI: 10.1021/Om010605J |
0.625 |
|
2001 |
Beck S, Lieber S, Schaper F, Geyer A, Brintzinger HH. Anion exchange in alkyl-zirconocene borate ion pairs. Are solvated alkyl-zirconocene cations relevant intermediates? Journal of the American Chemical Society. 123: 1483-1489. DOI: 10.1021/Ja003531W |
0.548 |
|
2000 |
Schaper F, Brintzinger HH. [{Me(4)C(2)(C(5)H(4))(2)}Zr(BH(4))(2)], a bis(tetrahydroborate) complex of a bridged zirconocene. Acta Crystallographica. Section C, Crystal Structure Communications. 56: E78. PMID 15263202 DOI: 10.1107/S0108270100002250 |
0.569 |
|
2000 |
Weeber A, Harder S, Brintzinger HH, Knoll K. Homoleptic and Heteroleptic Barium Benzyl Complexes: Synthesis and Reactivity as Initiators for Anionic Styrene Polymerizations Organometallics. 19: 1325-1332. DOI: 10.1021/Om990705D |
0.643 |
|
2000 |
Lieber S, Prosenc MH, Brintzinger HH. Zirconocene allyl complexes: Dynamics in solution, reaction with aluminum alkyls, B(C6F5)3-induced propene insertion, and density-functional calculations on possible formation and reaction pathways Organometallics. 19: 377-387. DOI: 10.1021/Om9906058 |
0.466 |
|
2000 |
Schneider N, Schaper F, Schmidt K, Kirsten R, Geyer A, Brintzinger HH. Zirconocene complexes with cyclopenta[l]phenanthrene ligands: syntheses, structural dynamics, and properties as olefin polymerization catalysts Organometallics. 19: 3597-3604. DOI: 10.1021/Om000149J |
0.577 |
|
2000 |
Lieber S, Brintzinger HH. Propene polymerization with catalyst mixtures containing different ansa-zirconocenes: chain transfer to alkylaluminum cocatalysts and formation of stereoblock polymers Macromolecules. 33: 9192-9199. DOI: 10.1021/Ma000691J |
0.309 |
|
1999 |
Ringwald M, Stürmer R, Brintzinger HH. Asymmetric thermal transformation, a new way to enantiopure biphenyl- bridged titanocene and zirconocene complexes: Efficient catalysts for asymmetric imine hydrogenation Journal of the American Chemical Society. 121: 1524-1527. DOI: 10.1021/Ja983524W |
0.372 |
|
1999 |
Brintzinger HH, Prosenc MH, Schaper F, Weeber A, Wieser U. Alternative force field models for ansa-zirconocene complexes - Vibrational and structural studies on Me2Si-bridged and tert-butyl- substituted representatives Journal of Molecular Structure. 485: 409-419. DOI: 10.1016/S0022-2860(99)00184-2 |
0.597 |
|
1998 |
Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-Zirconocene via a Novel S -Symmetric Spirobis(silastannaindacene) Compound. Angewandte Chemie (International Ed. in English). 37: 2268-2270. PMID 29711458 DOI: 10.1002/(Sici)1521-3773(19980904)37:16<2268::Aid-Anie2268>3.0.Co;2-Y |
0.595 |
|
1998 |
Leyser N, Schmidt K, Brintzinger HH. Phosphonium-bridged alkali and alkaline-earth metallocene complexes Organometallics. 17: 2155-2161. DOI: 10.1021/Om971122B |
0.375 |
|
1998 |
Beck S, Prosenc MH, Brintzinger HH. Displacement of weakly coordinating anions from zirconocene alkyl cations by trialkyl phosphines: A model for olefin coordination in homogeneous Ziegler-Natta catalysis Journal of Molecular Catalysis a: Chemical. 128: 41-52. DOI: 10.1016/S1381-1169(97)00161-1 |
0.362 |
|
1998 |
Damrau HRH, Geyer A, Prosenc MH, Weeber A, Schaper F, Brintzinger HH. Ansa-Metallocene derivatives1: XLI. Chiral ansa-Magnesocene complexes-syntheses, crystal structures and structural dynamics in solution Journal of Organometallic Chemistry. 553: 331-343. DOI: 10.1016/S0022-328X(97)00618-9 |
0.627 |
|
1998 |
Beck S, Brintzinger HH, Suhm J, Mülhaupt R. Propene polymerization with rac-Me2Si(2-Me-Benz[e]Ind)2ZrX2 [X = Cl, Me] using different cation-generating reagents Macromolecular Rapid Communications. 19: 235-239. DOI: 10.1002/(Sici)1521-3927(19980501)19:5<235::Aid-Marc235>3.0.Co;2-S |
0.334 |
|
1998 |
Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-zirconocene via a novel S4-symmetric spirobis(silastannaindacene) compound Angewandte Chemie - International Edition. 37: 2268-2270. DOI: 10.1002/(SICI)1521-3773(19980904)37:16<2268::AID-ANIE2268>3.0.CO;2-Y |
0.453 |
|
1998 |
Hüttenhofer M, Schaper F, Brintzinger HH. Synthese eines Ansa-Zirconocens über eine neueS4-symmetrische Spirobis(silastannaindacen)-Verbindung Angewandte Chemie. 110: 2378-2380. DOI: 10.1002/(Sici)1521-3757(19980817)110:16<2378::Aid-Ange2378>3.0.Co;2-W |
0.503 |
|
1997 |
Dorer B, Prosenc MH, Rief U, Brintzinger HH. ansa-vanadocene complexes - Syntheses, structures and ligand exchange reactions Collection of Czechoslovak Chemical Communications. 62: 265-278. DOI: 10.1135/Cccc19970265 |
0.486 |
|
1997 |
Prosenc MH, Brintzinger HH. Zirconium-alkyl isomerizations in zirconocene-catalyzed olefin polymerization: A density functional study Organometallics. 16: 3889-3894. DOI: 10.1021/Om970227B |
0.426 |
|
1997 |
Schneider N, Huttenloch ME, Stehling U, Kirsten R, Schaper F, Brintzinger HH. Ansa-Zirconocene complexes with modified benzindenyl ligands: syntheses, crystal structure, and properties as propene polymerization catalysts Organometallics. 16: 3413-3420. DOI: 10.1021/Om970131H |
0.58 |
|
1997 |
Schmidt K, Reinmuth A, Rief U, Diebold J, Brintzinger HH. Photochemical isomerization of Me2Si-bridged zirconocene complexes. Application to stereoselective syntheses of ansa-zirconocene binaphtholate stereoisomers Organometallics. 16: 1724-1728. DOI: 10.1021/Om961089D |
0.375 |
|
1997 |
Schneider MJ, Suhm J, Mülhaupt R, Prosenc MH, Brintzinger HH. Influence of indenyl ligand substitution pattern on metallocene-catalyzed ethene copolymerization with 1-octene Macromolecules. 30: 3164-3168. DOI: 10.1021/Ma961844Z |
0.375 |
|
1997 |
Sacchi MC, Barsties E, Tritto I, Locatelli P, Brintzinger HH, Stehling U. Stereochemistry of first monomer insertion into metal-methyl bond: A tool for evaluating ligand-monomer interactions in propene polymerization with metallocene catalysts Macromolecules. 30: X-3957. DOI: 10.1021/Ma960720J |
0.404 |
|
1997 |
Langhauser F, Fischer D, Kerth Ju, Schweier Gu, Barsties E, Brintzinger H, Schaible S, Roell W. Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems Journal of Molecular Catalysis a-Chemical. 125: 174. DOI: 10.1016/S1381-1169(98)80087-3 |
0.376 |
|
1997 |
Schneider N, Prosenc MH, Brintzinger HH. Cyclopenta[l]phenanthrene titanium trichloride derivatives: Syntheses, crystal structure and properties as catalysts for styrene polymerization Journal of Organometallic Chemistry. 545: 291-295. DOI: 10.1016/S0022-328X(97)00251-9 |
0.384 |
|
1997 |
Huttenloch ME, Dorer B, Rief U, Prosenc MH, Schmidt K, Brintzinger HH. Ansa-metallocene derivatives XXXIX: Biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium: Syntheses, crystal structures and enantioseparation Journal of Organometallic Chemistry. 541: 219-232. DOI: 10.1016/S0022-328X(97)00064-8 |
0.379 |
|
1997 |
Schaper F, Rentzsch M, Prosenc MH, Rief U, Schmidt K, Brintzinger HH. ansa-Metallocene derivatives XXXVI. Dimethylsilyl-bridged permethyl chromocene carbonyl complexes - Syntheses, crystal structures and interconversion reactions Journal of Organometallic Chemistry. 534: 67-79. DOI: 10.1016/S0022-328X(96)06895-7 |
0.643 |
|
1996 |
Hüttenhofer M, Prosenc MH, Rief U, Schaper F, Brintzinger HH. Substituted silastannatetrahydro-s-indacenes as cyclopentadienyl transfer agents in the synthesis of silanediyl-bridged zirconocene complexes Organometallics. 15: 4816-4822. DOI: 10.1021/Om960305F |
0.576 |
|
1996 |
Bühl M, Hopp G, Von Philipsborn W, Beck S, Prosenc MH, Rief U, Brintzinger HH. Zirconium-91 chemical shifts and line widths as indicators of coordination geometry distortions in zirconocene complexes Organometallics. 15: 778-785. DOI: 10.1021/Om950757C |
0.327 |
|
1996 |
Leclerc MK, Brintzinger HH. Zr-alkyl isomerization in ansa-zirconocene-catalyzed olefin polymerizations. Contributions to stereoerror formation and chain termination Journal of the American Chemical Society. 118: 9024-9032. DOI: 10.1021/Ja961157N |
0.301 |
|
1996 |
Beck S, Prosenc MH, Brintzinger HH, Goretzki R, Herfert N, Fink G. Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systems Journal of Molecular Catalysis a: Chemical. 111: 67-79. DOI: 10.1016/1381-1169(96)00168-9 |
0.351 |
|
1996 |
Barsties E, Schaible S, Prosenc MH, Rief U, Röll W, Weyand O, Dorer B, Brintzinger HH. ansa-metallocene derivatives XXXIII. 2-Dimethylamino-substituted bis-indenyl zirconium dichloride complexes with and without a dimethylsilyl bridge: Syntheses, crystal structures and properties in propene polymerization catalysis Journal of Organometallic Chemistry. 520: 63-68. DOI: 10.1016/0022-328X(96)06263-8 |
0.443 |
|
1996 |
Mansel S, Rief U, Prosenc MH, Kirsten R, Brintzinger HH. ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: Syntheses, crystal structures and properties as olefin polymerization catalysts Journal of Organometallic Chemistry. 512: 225-236. DOI: 10.1016/0022-328X(95)06073-6 |
0.421 |
|
1995 |
Leclerc MK, Brintzinger HH. Origins of stereoselectivity and stereoerror formation in ansa-zirconocene-catalyzed isotactic propene polymerization. A deuterium labeling study Journal of the American Chemical Society. 117: 1651-1652. DOI: 10.1021/Ja00110A027 |
0.308 |
|
1995 |
Jüngling S, Mülhaupt R, Stehling U, Brintzinger H, Fischer D, Langhauser F. The role of dormant sites in propene polymerization using methylalumoxane activated metallocene catalysts Macromolecular Symposia. 97: 205-216. DOI: 10.1002/Masy.19950970121 |
0.332 |
|
1995 |
Brintzinger H. Corrigendum : ["Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts" by H. H. Brintzinger et al. (Angew. Chem. Int. Ed. Engl. 1995, 34, 1143-1170)] Angewandte Chemie. 34: 1368-1368. DOI: 10.1002/Anie.199513681 |
0.315 |
|
1995 |
Selg P, Brintzinger HH, Andersen RA, Horváth IT. Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca] Angewandte Chemie (International Edition in English). 34: 791-793. DOI: 10.1002/Anie.199507911 |
0.362 |
|
1993 |
Scott P, Rief U, Diebold J, Brintzinger HH. Homo- and heterobimetallic bis(fulvalene) complexes from bis(cyclopentadienyl)- and bis(indenyl)-substituted ferrocenes Organometallics. 12: 3094-3101. DOI: 10.1021/Om00032A036 |
0.427 |
|
1993 |
Mengele W, Diebold J, Troll G, Röll W, Brintzinger HH. ansa-metallocene derivatives. 27. Chiral zirconocene complexes with two dimethylsilylene bridges Organometallics. 12: 1931-1935. DOI: 10.1021/Om00029A057 |
0.376 |
|
1993 |
Katz TJ, Gilbert AM, Huttenloch ME, Min-Min G, Brintzinger HH. Palladium-catalyzed coupling of 2,2t - ́dihalobiaryls with metallated cyclopentenes. An easy synthesis for spiro[cyclopentene-1,9-[9H]fluorene]s Tetrahedron Letters. 34: 3551-3554. DOI: 10.1016/S0040-4039(00)73633-1 |
0.373 |
|
1993 |
Rieger B, Reinmuth A, Röll W, Brintzinger HH. Highly isotactic polypropene prepared with rac-dimethylsilyl-bis (2-methyl-4-t-butyl-cyclopentadienyl) zirconiumdichloride: An NMR investigation of the polymer microstructure Journal of Molecular Catalysis. 82: 67-73. DOI: 10.1016/0304-5102(93)80071-2 |
0.302 |
|
1993 |
Niemann U, Diebold J, Troll C, Rief U, Brintzinger HH. Zirconocene dipicolinate and related dicarboxylate complexes: Coordination geometries and reactivities Journal of Organometallic Chemistry. 456: 195-204. DOI: 10.1016/0022-328X(93)80426-C |
0.433 |
|
1993 |
Hortmann K, Diebold J, Brintzinger HH. Ketene acetal metallocene complexes. Crystal structure of (C5H5) 2Ti(Cl)OC(OCH3)C(CH3)2 Journal of Organometallic Chemistry. 445: 107-109. DOI: 10.1016/0022-328X(93)80194-G |
0.4 |
|
1992 |
Dorer B, Diebold J, Weyand O, Brintzinger HH. ansa-Metallocene derivatives. XXV. Synthesis, crystal structure and reactions of a tetramethylethano-bridged vanadocene dichloride, (CH3)4C2(C5H4)2VCl2 Journal of Organometallic Chemistry. 427: 245-255. DOI: 10.1016/0022-328X(92)83088-Y |
0.384 |
|
1991 |
Burger P, Brintzinger HH. ansa-Metallocene derivatives. XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction Journal of Organometallic Chemistry. 407: 207-213. DOI: 10.1016/0022-328X(91)86118-A |
0.588 |
|
1991 |
Burger P, Hortmann K, Diebold J, Brintzinger HH. ansa-Metallocene derivatives. XXIII . Aryl-substituted titanocene and zirconocene complexes with interannular tetramethylethano- or dimethylsilano-bridges. Crystal structures of representative examples Journal of Organometallic Chemistry. 417: 9-27. DOI: 10.1016/0022-328X(91)80157-F |
0.571 |
|
1990 |
Gutmann S, Burger P, Prosenc MH, Brintzinger HH. ansa-Metallocene derivatives XX. An assignment of 1H- and 13C-NMR signals in ansa-metallocene complexes with 16-electron and 18-electron configuration Journal of Organometallic Chemistry. 397: 21-28. DOI: 10.1016/0022-328X(90)85310-U |
0.519 |
|
1990 |
Krauledat H, Brintzinger H. Isotopeneffekte bei der α-Olefineinschiebung in Zirconocen-Polymerisationskatalysatoren : Hinweise auf einen Übergangszustand mit α-agostischer Wechselwirkung Angewandte Chemie. 102: 1459-1460. DOI: 10.1002/Ange.19901021219 |
0.301 |
|
1989 |
Mönkeberg S, van Raaij E, Kiesele H, Brintzinger HH. CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes. Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis Journal of Organometallic Chemistry. 365: 285-295. DOI: 10.1016/0022-328X(89)87027-5 |
0.416 |
|
1989 |
Wiesenfeldt H, Reinmuth A, Barsties E, Evertz K, Brintzinger HH. ansa-Metallocene derivatives. XVII. Racemic and meso diastereomers of group IV metallocene derivatives with symmetrically substituted, dimethylsilanediyl-bridged ligand frameworks. Crystal structure of R,S-Me2Si(3-t-Bu-5-MeC5H2)2ZrCl2 Journal of Organometallic Chemistry. 369: 359-370. DOI: 10.1016/0022-328X(89)85186-1 |
0.349 |
|
1989 |
Gutmann S, Burger P, Hund HU, Hofmann J, Brintzinger HH. ansa-Metallocene derivatives. XVI. Chiral titanocene and zirconocene derivatives with symmetrically substituted, tetramethylethanediyl-bridged ligand frameworks. Crystal structures of representative examples Journal of Organometallic Chemistry. 369: 343-357. DOI: 10.1016/0022-328X(89)85185-X |
0.569 |
|
1989 |
Luinstra GA, Teuben JH, Brintzinger HH. IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I) Journal of Organometallic Chemistry. 375: 183-190. DOI: 10.1016/0022-328X(89)85112-5 |
0.779 |
|
1989 |
Burger P, Hund HU, Evertz K, Brintzinger HH. ansa-Metallocene derivatives XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors Journal of Organometallic Chemistry. 378: 153-161. DOI: 10.1016/0022-328X(89)80004-X |
0.536 |
|
1988 |
van Raaij EU, Brintzinger HH. ansa-Metallocene derivatives. XV. Reversible coordination of a second CO ligand to (C5H5)2Cr(CO) and its tetramethylethanediyl-bridged analogue. Evidence for an electron-transfer catalysed ring-slippage reaction. IR studies at elevated gas pressure. II Journal of Organometallic Chemistry. 356: 315-323. DOI: 10.1016/0022-328X(88)83149-8 |
0.425 |
|
1988 |
van Raaij EU, Mönkeberg S, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. XIV. Electrochemical reactions of unbridged and of tetramethylethanediyl-bridged chromocene carbonyl complexes Journal of Organometallic Chemistry. 356: 307-314. DOI: 10.1016/0022-328X(88)83148-6 |
0.377 |
|
1988 |
Meirim MG, Neuse EW, Rhemtula M, Schmitt S, Brintzinger HH. Aqueous-phase synthesis of di-(η5-cyclopentadienyl)salicylato- anddi-(η5-cyclopentadienyl)phthalatotitanium(IV) complexes Transition Metal Chemistry. 13: 272-276. DOI: 10.1007/Bf01025672 |
0.424 |
|
1987 |
Schäfer A, Karl E, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides Journal of Organometallic Chemistry. 328: 87-99. DOI: 10.1016/S0022-328X(00)99770-5 |
0.312 |
|
1987 |
Van Raaij EU, David Schmulbach C, Brintzinger HH. Equilibria and kinetics in the CO-induced, reversible disproportionation of ((C5H5)2TiCl)2 to (C5H5)2TiCl2 and (C5H52Ti(CO)2. An IR study at elevated CO gas pressures Journal of Organometallic Chemistry. 328: 275-285. DOI: 10.1016/0022-328X(87)80245-0 |
0.372 |
|
1987 |
Röll W, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 322: 65-70. DOI: 10.1016/0022-328X(85)80104-2 |
0.388 |
|
1986 |
Wochner F, Brintzinger HH. ansa-metallocene derivatives. X. Hydrogenolysis of the zirconium-alkyl bond in bridged and unbridged alkyl zirconocene derivatives. Evidence for direct and ring-mediated hydrogen transfer reactions Journal of Organometallic Chemistry. 309: 65-75. DOI: 10.1016/S0022-328X(00)99574-3 |
0.426 |
|
1986 |
Leik R, Zsolnai L, Huttner G, Neuse EW, Brintzinger HH. Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes. Synthesis and structural characterization as pentacoordinate titanocene derivatives Journal of Organometallic Chemistry. 312: 177-182. DOI: 10.1016/0022-328X(86)80296-0 |
0.417 |
|
1985 |
Schwemlein H, Tritschler W, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. IX. Electrochemical reactions of tetramethylethylene-bridged titanocene dichloride and dicarbonyl derivatives Journal of Organometallic Chemistry. 293: 353-364. DOI: 10.1016/0022-328X(85)80304-1 |
0.369 |
|
1985 |
Wochner F, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. VIII. Syntheses and crystal structures of ethylene-bridged titanocene and zirconocene derivatives with permethylated ring ligands Journal of Organometallic Chemistry. 288: 69-77. DOI: 10.1016/0022-328X(85)80105-4 |
0.395 |
|
1983 |
Schwemlein H, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. VI. Synthesis and molecular structure of a stable tetramethylethylene-bridged chromocene carbonyl complex, (CH3)4C2(C5H4)2Cr(CO) Journal of Organometallic Chemistry. 256: 285-289. DOI: 10.1016/S0022-328X(00)99205-2 |
0.415 |
|
1983 |
Schwemlein H, Brintzinger HH. ansa-Metallocene derivatives. V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling Journal of Organometallic Chemistry. 254: 69-73. DOI: 10.1016/0022-328X(83)85118-3 |
0.359 |
|
1982 |
Wild FRWP, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene Derivatives. IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 232: 233-247. DOI: 10.1016/S0022-328X(82)80018-1 |
0.39 |
|
1982 |
Wochner F, Keller E, Brintzinger HH. Molecular structure and chemical properties of a binuclear cyclopentadienylcobalt nitrosyl cation Journal of Organometallic Chemistry. 236: 267-272. DOI: 10.1016/S0022-328X(00)87082-5 |
0.328 |
|
1981 |
Lee WS, Koola JD, Brintzinger HH. Benzene complexes in cyclopentadienylcobalt(I) reaction systems Journal of Organometallic Chemistry. 206: C4-C6. DOI: 10.1016/S0022-328X(00)93472-7 |
0.398 |
|
1981 |
Smith JA, Brintzinger HH. Ansa-metallocene derivatives. III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives Journal of Organometallic Chemistry. 218: 159-167. DOI: 10.1016/S0022-328X(00)86097-0 |
0.315 |
|
1981 |
Lee WS, Brintzinger HH. Generation of reactive cyclopentadienylcobalt(I) derivatives by reduction of dicyclopentadienyldicobalt tetraiodide Journal of Organometallic Chemistry. 209: 401-406. DOI: 10.1016/S0022-328X(00)81196-1 |
0.383 |
|
1979 |
Brintzinger HH. Mechanisms of dihydrogen activation by zirconocene alkyl and hydride derivatives. A molecular orbital analysis of a 'direct hydrogen transfer' reaction mode Journal of Organometallic Chemistry. 171: 337-344. DOI: 10.1016/S0022-328X(00)82657-1 |
0.413 |
|
1979 |
Smith JA, von Seyerl J, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. Molecular structure and proton magnetic resonance spectra or methylene- and ethylene-bridged dicyclopentadienyltitanium compounds Journal of Organometallic Chemistry. 173: 175-185. DOI: 10.1016/S0022-328X(00)81287-5 |
0.364 |
|
1979 |
Otto EEH, Brintzinger HH. Ligand exchange and ligand migration reactions involving dicyclopentadienylniobium(III) carbonyl derivatives Journal of Organometallic Chemistry. 170: 209-216. DOI: 10.1016/S0022-328X(00)81085-2 |
0.404 |
|
1978 |
Wild FRWP, Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. III. Silica-gel-supported iron and cobalt derivatives Journal of Organometallic Chemistry. 148: 73-80. DOI: 10.1016/S0022-328X(00)90952-5 |
0.382 |
|
1978 |
Otto EEH, Brintzinger HH. Reactive intermediates derived from dicyclopentadienyl niobium(III) carbonyl compounds Journal of Organometallic Chemistry. 148: 29-33. DOI: 10.1016/S0022-328X(00)90947-1 |
0.406 |
|
1978 |
Huttner G, Brintzinger HH, Bell LG, Friedrich P, Bejenke V, Neugebauer D. The structure of (C5H52W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand Journal of Organometallic Chemistry. 145: 329-333. DOI: 10.1016/S0022-328X(00)81301-7 |
0.358 |
|
1977 |
Gubitosa G, Boldt M, Brintzinger HH. Supported cyclopentadienyl metal carbonyl complexes. 1. Mononuclear iron(II) and cobalt(I) derivatives stabilized by attachment to a polystyrene support [1] Journal of the American Chemical Society. 99: 5174-5175. DOI: 10.1021/Ja00457A044 |
0.321 |
|
1977 |
Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals Journal of Organometallic Chemistry. 140: 187-193. DOI: 10.1016/S0022-328X(00)93194-2 |
0.355 |
|
1977 |
Lee WS, Brintzinger HH. Reactive intermediates in the photolysis of cyclopentadienylcobalt(I) dicarbonyl and in the reduction of cyclopentadienylcobalt(III) carbonyl diiodide Journal of Organometallic Chemistry. 127: 87-92. DOI: 10.1016/S0022-328X(00)84198-4 |
0.322 |
|
1977 |
Weber SR, Brintzinger HH. Reactions of bis(hexamethylbenzene)iron(0) with carbon monoxide and with unsaturated hydrocarbons Journal of Organometallic Chemistry. 127: 45-54. DOI: 10.1016/S0022-328X(00)84196-0 |
0.392 |
|
1975 |
Tang Wong KL, Brintzinger HH. Reactivity patterns of chromocene, molybdenocene, and tungstenocene reaction systems. I. Carbonyl complex formation as a probe of coordinative unsaturation Journal of the American Chemical Society. 97: 5143-5146. DOI: 10.1021/Ja00851A020 |
0.401 |
|
1974 |
Tang Wong KL, Thomas JL, Brintzinger HH. Photogeneration of coordinatively unsaturated sandwich compounds of molybdenum and tungsten from their carbonyl complexes [35] Journal of the American Chemical Society. 96: 3694-3695. DOI: 10.1021/Ja00818A077 |
0.374 |
|
1972 |
Bercaw JE, Marvich RH, Bell LG, Brintzinger HH. Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen Journal of the American Chemical Society. 94: 1219-1238. DOI: 10.1021/Ja00759A032 |
0.633 |
|
1972 |
BERCAW JE, MARVICH RH, BELL LG, BRINTZINGER HH. ChemInform Abstract: TITANOCEN ALS ZWISCHENPRODUKT IN RK. MIT MOLEKULAREM SAUERSTOFF UND STICKSTOFF Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197220366 |
0.555 |
|
1971 |
Bercaw JE, Brintzinger HH. Bis(pentamethylcyclopentadienyl)titanium(II). Isolation and reactions with hydrogen, nitrogen, and carbon monoxide [1] Journal of the American Chemical Society. 93: 2045-2046. DOI: 10.1021/Ja00737A033 |
0.625 |
|
1971 |
BERCAW JE, BRINTZINGER HH. ChemInform Abstract: BIS-(PENTAMETHYLCYCLOPENTADIENYL)-TITAN(II), ISOLIERUNG UND REAKTIONEN MIT WASSERSTOFF, STICKSTOFF UND KOHLENMONOXID Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197128032 |
0.579 |
|
1970 |
Brintzinger H, Bercaw JE. Nature of so-called titanocene, (C10H10Ti)2 Journal of the American Chemical Society. 92: 6182-6185. DOI: 10.1021/Ja00724A013 |
0.566 |
|
1970 |
BRINTZINGER HH, BERCAW JE. ChemInform Abstract: STRUKTUR DES SOGENANNTEN TITANOCENS (C10H10TI)2 Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197052061 |
0.55 |
|
1970 |
BERCAW JE, BRINTZINGER HH. ChemInform Abstract: DI-MY-HYDRIDO-BIS-(DICYCLOPENTADIENYLTITAN(III)), EIN UEBERGANGSMETALLKOMPLEX MIT EINER DIBORAN-ARTIGEN DOPPELTEN WASSERSTOFFBRUECKENBINDUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197013346 |
0.615 |
|
1969 |
Bercaw JE, Brintzinger HH. Di-μ-hydrido-bis(dicyclopentadienyltitanium(III)), a transition metal complex with a diborane-like double hydrogen bridge Journal of the American Chemical Society. 91: 7301-7306. DOI: 10.1021/Ja01054A018 |
0.647 |
|
1967 |
Brintzinger H. Hydride, alkyl, and alyl complexes of bis(.pi.-cyclopentadienyl)thitanium(III) Journal of the American Chemical Society. 89: 6871-6877. DOI: 10.1021/Ja01002A011 |
0.419 |
|
1967 |
Brintzinger HH. Hydride, alkyl, and allyl complexes of bis (π-cyclopentadienyl ) titanium(III) Journal of the American Chemical Society. 89: 6871-6877. |
0.337 |
|
1966 |
Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. II. Di-μ-imino-bis(dicyclopentadienyltitanium(III)) as a product of the reaction between di-μ-hydrido-bis(dicyclopentadienyltitanium(III)) and molecular nitrogen [40] Journal of the American Chemical Society. 88: 4307-4308. DOI: 10.1021/Ja00970A067 |
0.398 |
|
1966 |
Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. I. The formation of dimeric dicyclopentadienyltitanium(III) hydride as an intermediate in the vol'pin-shur nitrogen-fixing system [39] Journal of the American Chemical Society. 88: 4305-4307. DOI: 10.1021/Ja00970A066 |
0.332 |
|
1966 |
Brintzinger H, Hammes GG. Inner- and outer-sphere complex formation in aqueous solutions of nickel(II)-methyl phosphate Inorganic Chemistry. 5: 1286-1287. DOI: 10.1021/Ic50041A050 |
0.339 |
|
1959 |
BRINTZINGER H, FALLAB S, ERLENMEYER H. [Metal specificity of hexokinase]. Experientia. 15: 96-7. PMID 13652940 DOI: 10.1007/BF02166692 |
0.663 |
|
1955 |
Brintzinger H, Fallab S, Erlenmeyer H. Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung. Metallionen und biologische Wirkung, 33. Mitteilung Helvetica Chimica Acta. 38: 557-559. DOI: 10.1002/Hlca.19550380302 |
0.73 |
|
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