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Hans-Herbert Brintzinger - Publications

Affiliations: 
Chemistry University of Konstanz, Konstanz, Germany 
 1965-1973 Chemistry University of Michigan, Ann Arbor, Ann Arbor, MI 
Area:
reactivities of organometallic compounds, e.g. as catalysts for polymerization reactions
Website:
http://www.chemie.uni-konstanz.de/~agbri/brintzinger.html

126/236 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Panchenko VN, Babushkin DE, Bercaw JE, Brintzinger HH. Catalyst Speciation During -Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy-Formation and Partial Re-Activation of Zr-Allyl Intermediates. Polymers. 11. PMID 31146475 DOI: 10.3390/Polym11060936  0.637
2014 Babushkin DE, Panchenko VN, Brintzinger HH. Zirconium allyl complexes as participants in zirconocene-catalyzed α-olefin polymerizations. Angewandte Chemie (International Ed. in English). 53: 9645-9. PMID 25044470 DOI: 10.1002/Anie.201403673  0.343
2013 Lenton TN, Bercaw JE, Panchenko VN, Zakharov VA, Babushkin DE, Soshnikov IE, Talsi EP, Brintzinger HH. Formation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: an EPR- and NMR-spectroscopic study. Journal of the American Chemical Society. 135: 10710-9. PMID 23745750 DOI: 10.1021/Ja403170U  0.771
2011 Baldwin SM, Bercaw JE, Henling LM, Day MW, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides: NMR-spectroscopic identification, crystallographic structure determination, and interconversion with other zirconocene cations. Journal of the American Chemical Society. 133: 1805-13. PMID 21244016 DOI: 10.1021/Ja1050428  0.801
2010 Baldwin SM, Bercaw JE, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides as participants in olefin polymerization catalysis. Journal of the American Chemical Society. 132: 13969-71. PMID 20860389 DOI: 10.1021/Ja105040R  0.798
2008 Baldwin SM, Bercaw JE, Brintzinger HH. Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy. Journal of the American Chemical Society. 130: 17423-33. PMID 19032092 DOI: 10.1021/Ja8054723  0.776
2008 Babushkin DE, Panchenko VN, Timofeeva MN, Zakharov VA, Brintzinger HH. Novel zirconocene hydride complexes in homogeneous and in SiO 2-supported olefin-polymerization catalysts modified with diisobutylaluminum hydride or triisobutylaluminum Macromolecular Chemistry and Physics. 209: 1210-1219. DOI: 10.1002/Macp.200800084  0.382
2007 Babushkin DE, Brintzinger HH. Modification of methylaluminoxane-activated ansa-zirconocene catalysts with triisobutylaluminum-transformations of reactive cations studied by NMR spectroscopy. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 5294-9. PMID 17385201 DOI: 10.1002/Chem.200601801  0.341
2006 Babushkin DE, Naundorf C, Brintzinger HH. Distinct methylalumoxane(MAO)-derived Me-MAO- anions in contact with a zirconocenium cation--a 13C-NMR study. Dalton Transactions (Cambridge, England : 2003). 4539-44. PMID 17016564 DOI: 10.1039/B611028M  0.313
2006 Wieser U, Schaper F, Brintzinger HH. Methylalumoxane (MAO)-derived MeMAO- anions in zirconocene-based polymerization catalyst systems - A UV-vis spectroscopic study Macromolecular Symposia. 236: 63-68. DOI: 10.1002/Masy.200690068  0.576
2005 Bryliakov KP, Kravtsov EA, Pennington DA, Lancaster SJ, Bochmann M, Brintzinger HH, Talsi EP. Active intermediates in ethylene polymerization over titanium bis(phenoxyimine) catalysts Organometallics. 24: 5660-5664. DOI: 10.1021/Om0505920  0.389
2005 Bryliakov KP, Babushkin DE, Talsi EP, Voskoboynikov AZ, Gritzo H, Schröder L, Damrau HRH, Wieser U, Schaper F, Brintzinger HH. Ansa-titanocene catalysts for α-Olefin polymerization. Syntheses, structures, and reactions with methylaluminoxane and boron-based activators Organometallics. 24: 894-904. DOI: 10.1021/Om0492496  0.665
2005 Schröder L, Brintzinger HH, Babushkin DE, Fischer D, Mülhaupt R. Rac-Me2Si(2-Me-4-t-Bu-C5H2) 2ZrMe+: An alkyl zirconocenium cation stabilized by steric shielding against interaction with ancillary ligands Organometallics. 24: 867-871. DOI: 10.1021/Om049139Z  0.337
2005 Bhriain NN, Brintzinger HH, Ruchatz D, Fink G. Polymeryl exchange between cmsa-zirconocene catalysts for norbornene-ethene copolymerization and aluminum or zinc alkyls Macromolecules. 38: 2056-2063. DOI: 10.1021/Ma0401166  0.368
2005 Kettunen M, Vedder C, Brintzinger HH, Mutikainen I, Leskelä M, Repo T. Alternative coordination modes in palladium(II)-diimino-bispyridine complexes with an axially chiral biphenyl backbone European Journal of Inorganic Chemistry. 1081-1089. DOI: 10.1002/Ejic.200400913  0.362
2005 Vedder C, Schaper F, Brintzinger HH, Kettunen M, Babik S, Fink G. Chiral iron(II) and cobalt(II) complexes with biphenyl-bridged bis(pyridylimine) ligands - Syntheses, structures and reactivities European Journal of Inorganic Chemistry. 1071-1080. DOI: 10.1002/Ejic.200400912  0.627
2004 Gritzo H, Schaper F, Brintzinger HH. Bis(η3-indenyl)bis(tetrahydrofuran)magnesium(II) Acta Crystallographica Section E: Structure Reports Online. 60: m1108-m1110. DOI: 10.1107/S1600536804016149  0.557
2004 Schaper F, Wrobel O, Schwörer R, Brintzinger HH. Me2Si(C5Me4)2Cr: Synthesis and crystal structure of a ligand-free ansa-chromocene Organometallics. 23: 3552-3555. DOI: 10.1021/Om049901X  0.607
2004 Kettunen M, Vedder C, Schaper F, Leskelä M, Mutikainen I, Brintzinger HH. Chiral zirconium complexes with bianiline-based N4-donor ligands Organometallics. 23: 3800-3807. DOI: 10.1021/Om040011R  0.619
2004 Wrobel O, Schaper F, Brintzinger HH. Bulky siloxyaluminum alkyls as models for Al2Me6-treated silica gel surfaces. Characterization of a dimethylaniline-stabilized dimethylaluminum cation Organometallics. 23: 900-905. DOI: 10.1021/Om030589L  0.603
2003 Wrobel O, Schaper F, Wieser U, Gregorius H, Brintzinger HH. Siloxyaluminum alkyl cations: Syntheses, structures, and reactions related to activation of zirconocene catalysts on silica gel surfaces Organometallics. 22: 1320-1325. DOI: 10.1021/Om0207515  0.577
2002 Babushkin DE, Brintzinger HH. Activation of dimethyl zirconocene by methylaluminoxane (MAO)-size estimate for Me-MAO(-) anions by pulsed field-gradient NMR. Journal of the American Chemical Society. 124: 12869-73. PMID 12392434 DOI: 10.1021/Ja020646M  0.361
2002 Selg P, Brintzinger HH, Schultz M, Andersen RA. Solution infrared spectroscopic studies on equilibrium reactions of CO with the decamethylmetallocenes Cp*2MII, where MII = Mg, Ca, Sr, Ba, Sm, Eu, Yb Organometallics. 21: 3100-3107. DOI: 10.1021/Om011045R  0.308
2002 Wieser U, Schaper F, Brintzinger HH, Mäkelä NI, Knuuttila HR, Leskelä M. Effects of an interannular bridge on spectral and electronic properties of bis(cyclopentadienyl)- and bis(indenyl)zirconium (IV) complexes Organometallics. 21: 541-545. DOI: 10.1021/Om010770Z  0.587
2002 Wieser U, Babushkin D, Brintzinger HH. Methyl-versus-chloride exchange as a measure of electron density at the metal center of ring-substituted zirconocene complexes Organometallics. 21: 920-923. DOI: 10.1021/Om0107688  0.371
2002 Schaper F, Geyer A, Brintzinger HH. Displacement of H3CB(C6F5)3 - anions from zirconocene methyl cations by neutral ligand molecules: Equilibria, kinetics, and mechanisms Organometallics. 21: 473-483. DOI: 10.1021/Om010671L  0.626
2002 Hüttenhofer M, Schaper F, Brintzinger HH. 8-sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes: Formation from biscyclopentadienyl silanes by reaction with aminostannanes Journal of Organometallic Chemistry. 660: 85-90. DOI: 10.1016/S0022-328X(02)01775-8  0.617
2002 Royo E, Brintzinger HH. Mass spectrometry of polystyrene and polypropene ruthenium complexes. A new tool for polymer characterization Journal of Organometallic Chemistry. 663: 213-220. DOI: 10.1016/S0022-328X(02)01770-9  0.301
2002 Hüttenhofer M, Weeber A, Brintzinger HH. Mechanisms of Sn-to-Zr cyclopentadienyl transfer in the formation of Me2Si-bridged zirconocenes from sila-stanna-tetrahydro-s-indacenes Journal of Organometallic Chemistry. 663: 58-62. DOI: 10.1016/S0022-328X(02)01653-4  0.357
2001 Schaper F, Brintzinger H. Tetrahydrothiophene tris(pentafluorophenyl)borane Acta Crystallographica Section E Structure Reports Online. 58: o77-o78. DOI: 10.1107/S160053680102027X  0.56
2001 Damrau HRH, Royo E, Obert S, Schaper F, Weeber A, Brintzinger HH. Racemo-selective synthesis of ansa-zirconocene derivates from zirconium biphenolate complexes Organometallics. 20: 5258-5265. DOI: 10.1021/Om010605J  0.625
2001 Beck S, Lieber S, Schaper F, Geyer A, Brintzinger HH. Anion exchange in alkyl-zirconocene borate ion pairs. Are solvated alkyl-zirconocene cations relevant intermediates? Journal of the American Chemical Society. 123: 1483-1489. DOI: 10.1021/Ja003531W  0.548
2000 Schaper F, Brintzinger HH. [{Me(4)C(2)(C(5)H(4))(2)}Zr(BH(4))(2)], a bis(tetrahydroborate) complex of a bridged zirconocene. Acta Crystallographica. Section C, Crystal Structure Communications. 56: E78. PMID 15263202 DOI: 10.1107/S0108270100002250  0.569
2000 Weeber A, Harder S, Brintzinger HH, Knoll K. Homoleptic and Heteroleptic Barium Benzyl Complexes: Synthesis and Reactivity as Initiators for Anionic Styrene Polymerizations Organometallics. 19: 1325-1332. DOI: 10.1021/Om990705D  0.643
2000 Lieber S, Prosenc MH, Brintzinger HH. Zirconocene allyl complexes: Dynamics in solution, reaction with aluminum alkyls, B(C6F5)3-induced propene insertion, and density-functional calculations on possible formation and reaction pathways Organometallics. 19: 377-387. DOI: 10.1021/Om9906058  0.466
2000 Schneider N, Schaper F, Schmidt K, Kirsten R, Geyer A, Brintzinger HH. Zirconocene complexes with cyclopenta[l]phenanthrene ligands: syntheses, structural dynamics, and properties as olefin polymerization catalysts Organometallics. 19: 3597-3604. DOI: 10.1021/Om000149J  0.577
2000 Lieber S, Brintzinger HH. Propene polymerization with catalyst mixtures containing different ansa-zirconocenes: chain transfer to alkylaluminum cocatalysts and formation of stereoblock polymers Macromolecules. 33: 9192-9199. DOI: 10.1021/Ma000691J  0.309
1999 Ringwald M, Stürmer R, Brintzinger HH. Asymmetric thermal transformation, a new way to enantiopure biphenyl- bridged titanocene and zirconocene complexes: Efficient catalysts for asymmetric imine hydrogenation Journal of the American Chemical Society. 121: 1524-1527. DOI: 10.1021/Ja983524W  0.372
1999 Brintzinger HH, Prosenc MH, Schaper F, Weeber A, Wieser U. Alternative force field models for ansa-zirconocene complexes - Vibrational and structural studies on Me2Si-bridged and tert-butyl- substituted representatives Journal of Molecular Structure. 485: 409-419. DOI: 10.1016/S0022-2860(99)00184-2  0.597
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-Zirconocene via a Novel S -Symmetric Spirobis(silastannaindacene) Compound. Angewandte Chemie (International Ed. in English). 37: 2268-2270. PMID 29711458 DOI: 10.1002/(Sici)1521-3773(19980904)37:16<2268::Aid-Anie2268>3.0.Co;2-Y  0.595
1998 Leyser N, Schmidt K, Brintzinger HH. Phosphonium-bridged alkali and alkaline-earth metallocene complexes Organometallics. 17: 2155-2161. DOI: 10.1021/Om971122B  0.375
1998 Beck S, Prosenc MH, Brintzinger HH. Displacement of weakly coordinating anions from zirconocene alkyl cations by trialkyl phosphines: A model for olefin coordination in homogeneous Ziegler-Natta catalysis Journal of Molecular Catalysis a: Chemical. 128: 41-52. DOI: 10.1016/S1381-1169(97)00161-1  0.362
1998 Damrau HRH, Geyer A, Prosenc MH, Weeber A, Schaper F, Brintzinger HH. Ansa-Metallocene derivatives1: XLI. Chiral ansa-Magnesocene complexes-syntheses, crystal structures and structural dynamics in solution Journal of Organometallic Chemistry. 553: 331-343. DOI: 10.1016/S0022-328X(97)00618-9  0.627
1998 Beck S, Brintzinger HH, Suhm J, Mülhaupt R. Propene polymerization with rac-Me2Si(2-Me-Benz[e]Ind)2ZrX2 [X = Cl, Me] using different cation-generating reagents Macromolecular Rapid Communications. 19: 235-239. DOI: 10.1002/(Sici)1521-3927(19980501)19:5<235::Aid-Marc235>3.0.Co;2-S  0.334
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-zirconocene via a novel S4-symmetric spirobis(silastannaindacene) compound Angewandte Chemie - International Edition. 37: 2268-2270. DOI: 10.1002/(SICI)1521-3773(19980904)37:16<2268::AID-ANIE2268>3.0.CO;2-Y  0.453
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthese eines Ansa-Zirconocens über eine neueS4-symmetrische Spirobis(silastannaindacen)-Verbindung Angewandte Chemie. 110: 2378-2380. DOI: 10.1002/(Sici)1521-3757(19980817)110:16<2378::Aid-Ange2378>3.0.Co;2-W  0.503
1997 Dorer B, Prosenc MH, Rief U, Brintzinger HH. ansa-vanadocene complexes - Syntheses, structures and ligand exchange reactions Collection of Czechoslovak Chemical Communications. 62: 265-278. DOI: 10.1135/Cccc19970265  0.486
1997 Prosenc MH, Brintzinger HH. Zirconium-alkyl isomerizations in zirconocene-catalyzed olefin polymerization: A density functional study Organometallics. 16: 3889-3894. DOI: 10.1021/Om970227B  0.426
1997 Schneider N, Huttenloch ME, Stehling U, Kirsten R, Schaper F, Brintzinger HH. Ansa-Zirconocene complexes with modified benzindenyl ligands: syntheses, crystal structure, and properties as propene polymerization catalysts Organometallics. 16: 3413-3420. DOI: 10.1021/Om970131H  0.58
1997 Schmidt K, Reinmuth A, Rief U, Diebold J, Brintzinger HH. Photochemical isomerization of Me2Si-bridged zirconocene complexes. Application to stereoselective syntheses of ansa-zirconocene binaphtholate stereoisomers Organometallics. 16: 1724-1728. DOI: 10.1021/Om961089D  0.375
1997 Schneider MJ, Suhm J, Mülhaupt R, Prosenc MH, Brintzinger HH. Influence of indenyl ligand substitution pattern on metallocene-catalyzed ethene copolymerization with 1-octene Macromolecules. 30: 3164-3168. DOI: 10.1021/Ma961844Z  0.375
1997 Sacchi MC, Barsties E, Tritto I, Locatelli P, Brintzinger HH, Stehling U. Stereochemistry of first monomer insertion into metal-methyl bond: A tool for evaluating ligand-monomer interactions in propene polymerization with metallocene catalysts Macromolecules. 30: X-3957. DOI: 10.1021/Ma960720J  0.404
1997 Langhauser F, Fischer D, Kerth Ju, Schweier Gu, Barsties E, Brintzinger H, Schaible S, Roell W. Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems Journal of Molecular Catalysis a-Chemical. 125: 174. DOI: 10.1016/S1381-1169(98)80087-3  0.376
1997 Schneider N, Prosenc MH, Brintzinger HH. Cyclopenta[l]phenanthrene titanium trichloride derivatives: Syntheses, crystal structure and properties as catalysts for styrene polymerization Journal of Organometallic Chemistry. 545: 291-295. DOI: 10.1016/S0022-328X(97)00251-9  0.384
1997 Huttenloch ME, Dorer B, Rief U, Prosenc MH, Schmidt K, Brintzinger HH. Ansa-metallocene derivatives XXXIX: Biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium: Syntheses, crystal structures and enantioseparation Journal of Organometallic Chemistry. 541: 219-232. DOI: 10.1016/S0022-328X(97)00064-8  0.379
1997 Schaper F, Rentzsch M, Prosenc MH, Rief U, Schmidt K, Brintzinger HH. ansa-Metallocene derivatives XXXVI. Dimethylsilyl-bridged permethyl chromocene carbonyl complexes - Syntheses, crystal structures and interconversion reactions Journal of Organometallic Chemistry. 534: 67-79. DOI: 10.1016/S0022-328X(96)06895-7  0.643
1996 Hüttenhofer M, Prosenc MH, Rief U, Schaper F, Brintzinger HH. Substituted silastannatetrahydro-s-indacenes as cyclopentadienyl transfer agents in the synthesis of silanediyl-bridged zirconocene complexes Organometallics. 15: 4816-4822. DOI: 10.1021/Om960305F  0.576
1996 Bühl M, Hopp G, Von Philipsborn W, Beck S, Prosenc MH, Rief U, Brintzinger HH. Zirconium-91 chemical shifts and line widths as indicators of coordination geometry distortions in zirconocene complexes Organometallics. 15: 778-785. DOI: 10.1021/Om950757C  0.327
1996 Leclerc MK, Brintzinger HH. Zr-alkyl isomerization in ansa-zirconocene-catalyzed olefin polymerizations. Contributions to stereoerror formation and chain termination Journal of the American Chemical Society. 118: 9024-9032. DOI: 10.1021/Ja961157N  0.301
1996 Beck S, Prosenc MH, Brintzinger HH, Goretzki R, Herfert N, Fink G. Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systems Journal of Molecular Catalysis a: Chemical. 111: 67-79. DOI: 10.1016/1381-1169(96)00168-9  0.351
1996 Barsties E, Schaible S, Prosenc MH, Rief U, Röll W, Weyand O, Dorer B, Brintzinger HH. ansa-metallocene derivatives XXXIII. 2-Dimethylamino-substituted bis-indenyl zirconium dichloride complexes with and without a dimethylsilyl bridge: Syntheses, crystal structures and properties in propene polymerization catalysis Journal of Organometallic Chemistry. 520: 63-68. DOI: 10.1016/0022-328X(96)06263-8  0.443
1996 Mansel S, Rief U, Prosenc MH, Kirsten R, Brintzinger HH. ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: Syntheses, crystal structures and properties as olefin polymerization catalysts Journal of Organometallic Chemistry. 512: 225-236. DOI: 10.1016/0022-328X(95)06073-6  0.421
1995 Leclerc MK, Brintzinger HH. Origins of stereoselectivity and stereoerror formation in ansa-zirconocene-catalyzed isotactic propene polymerization. A deuterium labeling study Journal of the American Chemical Society. 117: 1651-1652. DOI: 10.1021/Ja00110A027  0.308
1995 Jüngling S, Mülhaupt R, Stehling U, Brintzinger H, Fischer D, Langhauser F. The role of dormant sites in propene polymerization using methylalumoxane activated metallocene catalysts Macromolecular Symposia. 97: 205-216. DOI: 10.1002/Masy.19950970121  0.332
1995 Brintzinger H. Corrigendum : ["Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts" by H. H. Brintzinger et al. (Angew. Chem. Int. Ed. Engl. 1995, 34, 1143-1170)] Angewandte Chemie. 34: 1368-1368. DOI: 10.1002/Anie.199513681  0.315
1995 Selg P, Brintzinger HH, Andersen RA, Horváth IT. Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca] Angewandte Chemie (International Edition in English). 34: 791-793. DOI: 10.1002/Anie.199507911  0.362
1993 Scott P, Rief U, Diebold J, Brintzinger HH. Homo- and heterobimetallic bis(fulvalene) complexes from bis(cyclopentadienyl)- and bis(indenyl)-substituted ferrocenes Organometallics. 12: 3094-3101. DOI: 10.1021/Om00032A036  0.427
1993 Mengele W, Diebold J, Troll G, Röll W, Brintzinger HH. ansa-metallocene derivatives. 27. Chiral zirconocene complexes with two dimethylsilylene bridges Organometallics. 12: 1931-1935. DOI: 10.1021/Om00029A057  0.376
1993 Katz TJ, Gilbert AM, Huttenloch ME, Min-Min G, Brintzinger HH. Palladium-catalyzed coupling of 2,2t - ́dihalobiaryls with metallated cyclopentenes. An easy synthesis for spiro[cyclopentene-1,9-[9H]fluorene]s Tetrahedron Letters. 34: 3551-3554. DOI: 10.1016/S0040-4039(00)73633-1  0.373
1993 Rieger B, Reinmuth A, Röll W, Brintzinger HH. Highly isotactic polypropene prepared with rac-dimethylsilyl-bis (2-methyl-4-t-butyl-cyclopentadienyl) zirconiumdichloride: An NMR investigation of the polymer microstructure Journal of Molecular Catalysis. 82: 67-73. DOI: 10.1016/0304-5102(93)80071-2  0.302
1993 Niemann U, Diebold J, Troll C, Rief U, Brintzinger HH. Zirconocene dipicolinate and related dicarboxylate complexes: Coordination geometries and reactivities Journal of Organometallic Chemistry. 456: 195-204. DOI: 10.1016/0022-328X(93)80426-C  0.433
1993 Hortmann K, Diebold J, Brintzinger HH. Ketene acetal metallocene complexes. Crystal structure of (C5H5) 2Ti(Cl)OC(OCH3)C(CH3)2 Journal of Organometallic Chemistry. 445: 107-109. DOI: 10.1016/0022-328X(93)80194-G  0.4
1992 Dorer B, Diebold J, Weyand O, Brintzinger HH. ansa-Metallocene derivatives. XXV. Synthesis, crystal structure and reactions of a tetramethylethano-bridged vanadocene dichloride, (CH3)4C2(C5H4)2VCl2 Journal of Organometallic Chemistry. 427: 245-255. DOI: 10.1016/0022-328X(92)83088-Y  0.384
1991 Burger P, Brintzinger HH. ansa-Metallocene derivatives. XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction Journal of Organometallic Chemistry. 407: 207-213. DOI: 10.1016/0022-328X(91)86118-A  0.588
1991 Burger P, Hortmann K, Diebold J, Brintzinger HH. ansa-Metallocene derivatives. XXIII . Aryl-substituted titanocene and zirconocene complexes with interannular tetramethylethano- or dimethylsilano-bridges. Crystal structures of representative examples Journal of Organometallic Chemistry. 417: 9-27. DOI: 10.1016/0022-328X(91)80157-F  0.571
1990 Gutmann S, Burger P, Prosenc MH, Brintzinger HH. ansa-Metallocene derivatives XX. An assignment of 1H- and 13C-NMR signals in ansa-metallocene complexes with 16-electron and 18-electron configuration Journal of Organometallic Chemistry. 397: 21-28. DOI: 10.1016/0022-328X(90)85310-U  0.519
1990 Krauledat H, Brintzinger H. Isotopeneffekte bei der α-Olefineinschiebung in Zirconocen-Polymerisationskatalysatoren : Hinweise auf einen Übergangszustand mit α-agostischer Wechselwirkung Angewandte Chemie. 102: 1459-1460. DOI: 10.1002/Ange.19901021219  0.301
1989 Mönkeberg S, van Raaij E, Kiesele H, Brintzinger HH. CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes. Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis Journal of Organometallic Chemistry. 365: 285-295. DOI: 10.1016/0022-328X(89)87027-5  0.416
1989 Wiesenfeldt H, Reinmuth A, Barsties E, Evertz K, Brintzinger HH. ansa-Metallocene derivatives. XVII. Racemic and meso diastereomers of group IV metallocene derivatives with symmetrically substituted, dimethylsilanediyl-bridged ligand frameworks. Crystal structure of R,S-Me2Si(3-t-Bu-5-MeC5H2)2ZrCl2 Journal of Organometallic Chemistry. 369: 359-370. DOI: 10.1016/0022-328X(89)85186-1  0.349
1989 Gutmann S, Burger P, Hund HU, Hofmann J, Brintzinger HH. ansa-Metallocene derivatives. XVI. Chiral titanocene and zirconocene derivatives with symmetrically substituted, tetramethylethanediyl-bridged ligand frameworks. Crystal structures of representative examples Journal of Organometallic Chemistry. 369: 343-357. DOI: 10.1016/0022-328X(89)85185-X  0.569
1989 Luinstra GA, Teuben JH, Brintzinger HH. IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I) Journal of Organometallic Chemistry. 375: 183-190. DOI: 10.1016/0022-328X(89)85112-5  0.779
1989 Burger P, Hund HU, Evertz K, Brintzinger HH. ansa-Metallocene derivatives XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors Journal of Organometallic Chemistry. 378: 153-161. DOI: 10.1016/0022-328X(89)80004-X  0.536
1988 van Raaij EU, Brintzinger HH. ansa-Metallocene derivatives. XV. Reversible coordination of a second CO ligand to (C5H5)2Cr(CO) and its tetramethylethanediyl-bridged analogue. Evidence for an electron-transfer catalysed ring-slippage reaction. IR studies at elevated gas pressure. II Journal of Organometallic Chemistry. 356: 315-323. DOI: 10.1016/0022-328X(88)83149-8  0.425
1988 van Raaij EU, Mönkeberg S, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. XIV. Electrochemical reactions of unbridged and of tetramethylethanediyl-bridged chromocene carbonyl complexes Journal of Organometallic Chemistry. 356: 307-314. DOI: 10.1016/0022-328X(88)83148-6  0.377
1988 Meirim MG, Neuse EW, Rhemtula M, Schmitt S, Brintzinger HH. Aqueous-phase synthesis of di-(η5-cyclopentadienyl)salicylato- anddi-(η5-cyclopentadienyl)phthalatotitanium(IV) complexes Transition Metal Chemistry. 13: 272-276. DOI: 10.1007/Bf01025672  0.424
1987 Schäfer A, Karl E, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides Journal of Organometallic Chemistry. 328: 87-99. DOI: 10.1016/S0022-328X(00)99770-5  0.312
1987 Van Raaij EU, David Schmulbach C, Brintzinger HH. Equilibria and kinetics in the CO-induced, reversible disproportionation of ((C5H5)2TiCl)2 to (C5H5)2TiCl2 and (C5H52Ti(CO)2. An IR study at elevated CO gas pressures Journal of Organometallic Chemistry. 328: 275-285. DOI: 10.1016/0022-328X(87)80245-0  0.372
1987 Röll W, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 322: 65-70. DOI: 10.1016/0022-328X(85)80104-2  0.388
1986 Wochner F, Brintzinger HH. ansa-metallocene derivatives. X. Hydrogenolysis of the zirconium-alkyl bond in bridged and unbridged alkyl zirconocene derivatives. Evidence for direct and ring-mediated hydrogen transfer reactions Journal of Organometallic Chemistry. 309: 65-75. DOI: 10.1016/S0022-328X(00)99574-3  0.426
1986 Leik R, Zsolnai L, Huttner G, Neuse EW, Brintzinger HH. Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes. Synthesis and structural characterization as pentacoordinate titanocene derivatives Journal of Organometallic Chemistry. 312: 177-182. DOI: 10.1016/0022-328X(86)80296-0  0.417
1985 Schwemlein H, Tritschler W, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. IX. Electrochemical reactions of tetramethylethylene-bridged titanocene dichloride and dicarbonyl derivatives Journal of Organometallic Chemistry. 293: 353-364. DOI: 10.1016/0022-328X(85)80304-1  0.369
1985 Wochner F, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. VIII. Syntheses and crystal structures of ethylene-bridged titanocene and zirconocene derivatives with permethylated ring ligands Journal of Organometallic Chemistry. 288: 69-77. DOI: 10.1016/0022-328X(85)80105-4  0.395
1983 Schwemlein H, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. VI. Synthesis and molecular structure of a stable tetramethylethylene-bridged chromocene carbonyl complex, (CH3)4C2(C5H4)2Cr(CO) Journal of Organometallic Chemistry. 256: 285-289. DOI: 10.1016/S0022-328X(00)99205-2  0.415
1983 Schwemlein H, Brintzinger HH. ansa-Metallocene derivatives. V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling Journal of Organometallic Chemistry. 254: 69-73. DOI: 10.1016/0022-328X(83)85118-3  0.359
1982 Wild FRWP, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene Derivatives. IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 232: 233-247. DOI: 10.1016/S0022-328X(82)80018-1  0.39
1982 Wochner F, Keller E, Brintzinger HH. Molecular structure and chemical properties of a binuclear cyclopentadienylcobalt nitrosyl cation Journal of Organometallic Chemistry. 236: 267-272. DOI: 10.1016/S0022-328X(00)87082-5  0.328
1981 Lee WS, Koola JD, Brintzinger HH. Benzene complexes in cyclopentadienylcobalt(I) reaction systems Journal of Organometallic Chemistry. 206: C4-C6. DOI: 10.1016/S0022-328X(00)93472-7  0.398
1981 Smith JA, Brintzinger HH. Ansa-metallocene derivatives. III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives Journal of Organometallic Chemistry. 218: 159-167. DOI: 10.1016/S0022-328X(00)86097-0  0.315
1981 Lee WS, Brintzinger HH. Generation of reactive cyclopentadienylcobalt(I) derivatives by reduction of dicyclopentadienyldicobalt tetraiodide Journal of Organometallic Chemistry. 209: 401-406. DOI: 10.1016/S0022-328X(00)81196-1  0.383
1979 Brintzinger HH. Mechanisms of dihydrogen activation by zirconocene alkyl and hydride derivatives. A molecular orbital analysis of a 'direct hydrogen transfer' reaction mode Journal of Organometallic Chemistry. 171: 337-344. DOI: 10.1016/S0022-328X(00)82657-1  0.413
1979 Smith JA, von Seyerl J, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. Molecular structure and proton magnetic resonance spectra or methylene- and ethylene-bridged dicyclopentadienyltitanium compounds Journal of Organometallic Chemistry. 173: 175-185. DOI: 10.1016/S0022-328X(00)81287-5  0.364
1979 Otto EEH, Brintzinger HH. Ligand exchange and ligand migration reactions involving dicyclopentadienylniobium(III) carbonyl derivatives Journal of Organometallic Chemistry. 170: 209-216. DOI: 10.1016/S0022-328X(00)81085-2  0.404
1978 Wild FRWP, Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. III. Silica-gel-supported iron and cobalt derivatives Journal of Organometallic Chemistry. 148: 73-80. DOI: 10.1016/S0022-328X(00)90952-5  0.382
1978 Otto EEH, Brintzinger HH. Reactive intermediates derived from dicyclopentadienyl niobium(III) carbonyl compounds Journal of Organometallic Chemistry. 148: 29-33. DOI: 10.1016/S0022-328X(00)90947-1  0.406
1978 Huttner G, Brintzinger HH, Bell LG, Friedrich P, Bejenke V, Neugebauer D. The structure of (C5H52W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand Journal of Organometallic Chemistry. 145: 329-333. DOI: 10.1016/S0022-328X(00)81301-7  0.358
1977 Gubitosa G, Boldt M, Brintzinger HH. Supported cyclopentadienyl metal carbonyl complexes. 1. Mononuclear iron(II) and cobalt(I) derivatives stabilized by attachment to a polystyrene support [1] Journal of the American Chemical Society. 99: 5174-5175. DOI: 10.1021/Ja00457A044  0.321
1977 Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals Journal of Organometallic Chemistry. 140: 187-193. DOI: 10.1016/S0022-328X(00)93194-2  0.355
1977 Lee WS, Brintzinger HH. Reactive intermediates in the photolysis of cyclopentadienylcobalt(I) dicarbonyl and in the reduction of cyclopentadienylcobalt(III) carbonyl diiodide Journal of Organometallic Chemistry. 127: 87-92. DOI: 10.1016/S0022-328X(00)84198-4  0.322
1977 Weber SR, Brintzinger HH. Reactions of bis(hexamethylbenzene)iron(0) with carbon monoxide and with unsaturated hydrocarbons Journal of Organometallic Chemistry. 127: 45-54. DOI: 10.1016/S0022-328X(00)84196-0  0.392
1975 Tang Wong KL, Brintzinger HH. Reactivity patterns of chromocene, molybdenocene, and tungstenocene reaction systems. I. Carbonyl complex formation as a probe of coordinative unsaturation Journal of the American Chemical Society. 97: 5143-5146. DOI: 10.1021/Ja00851A020  0.401
1974 Tang Wong KL, Thomas JL, Brintzinger HH. Photogeneration of coordinatively unsaturated sandwich compounds of molybdenum and tungsten from their carbonyl complexes [35] Journal of the American Chemical Society. 96: 3694-3695. DOI: 10.1021/Ja00818A077  0.374
1972 Bercaw JE, Marvich RH, Bell LG, Brintzinger HH. Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen Journal of the American Chemical Society. 94: 1219-1238. DOI: 10.1021/Ja00759A032  0.633
1972 BERCAW JE, MARVICH RH, BELL LG, BRINTZINGER HH. ChemInform Abstract: TITANOCEN ALS ZWISCHENPRODUKT IN RK. MIT MOLEKULAREM SAUERSTOFF UND STICKSTOFF Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197220366  0.555
1971 Bercaw JE, Brintzinger HH. Bis(pentamethylcyclopentadienyl)titanium(II). Isolation and reactions with hydrogen, nitrogen, and carbon monoxide [1] Journal of the American Chemical Society. 93: 2045-2046. DOI: 10.1021/Ja00737A033  0.625
1971 BERCAW JE, BRINTZINGER HH. ChemInform Abstract: BIS-(PENTAMETHYLCYCLOPENTADIENYL)-TITAN(II), ISOLIERUNG UND REAKTIONEN MIT WASSERSTOFF, STICKSTOFF UND KOHLENMONOXID Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197128032  0.579
1970 Brintzinger H, Bercaw JE. Nature of so-called titanocene, (C10H10Ti)2 Journal of the American Chemical Society. 92: 6182-6185. DOI: 10.1021/Ja00724A013  0.566
1970 BRINTZINGER HH, BERCAW JE. ChemInform Abstract: STRUKTUR DES SOGENANNTEN TITANOCENS (C10H10TI)2 Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197052061  0.55
1970 BERCAW JE, BRINTZINGER HH. ChemInform Abstract: DI-MY-HYDRIDO-BIS-(DICYCLOPENTADIENYLTITAN(III)), EIN UEBERGANGSMETALLKOMPLEX MIT EINER DIBORAN-ARTIGEN DOPPELTEN WASSERSTOFFBRUECKENBINDUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197013346  0.615
1969 Bercaw JE, Brintzinger HH. Di-μ-hydrido-bis(dicyclopentadienyltitanium(III)), a transition metal complex with a diborane-like double hydrogen bridge Journal of the American Chemical Society. 91: 7301-7306. DOI: 10.1021/Ja01054A018  0.647
1967 Brintzinger H. Hydride, alkyl, and alyl complexes of bis(.pi.-cyclopentadienyl)thitanium(III) Journal of the American Chemical Society. 89: 6871-6877. DOI: 10.1021/Ja01002A011  0.419
1967 Brintzinger HH. Hydride, alkyl, and allyl complexes of bis (π-cyclopentadienyl ) titanium(III) Journal of the American Chemical Society. 89: 6871-6877.  0.337
1966 Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. II. Di-μ-imino-bis(dicyclopentadienyltitanium(III)) as a product of the reaction between di-μ-hydrido-bis(dicyclopentadienyltitanium(III)) and molecular nitrogen [40] Journal of the American Chemical Society. 88: 4307-4308. DOI: 10.1021/Ja00970A067  0.398
1966 Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. I. The formation of dimeric dicyclopentadienyltitanium(III) hydride as an intermediate in the vol'pin-shur nitrogen-fixing system [39] Journal of the American Chemical Society. 88: 4305-4307. DOI: 10.1021/Ja00970A066  0.332
1966 Brintzinger H, Hammes GG. Inner- and outer-sphere complex formation in aqueous solutions of nickel(II)-methyl phosphate Inorganic Chemistry. 5: 1286-1287. DOI: 10.1021/Ic50041A050  0.339
1959 BRINTZINGER H, FALLAB S, ERLENMEYER H. [Metal specificity of hexokinase]. Experientia. 15: 96-7. PMID 13652940 DOI: 10.1007/BF02166692  0.663
1955 Brintzinger H, Fallab S, Erlenmeyer H. Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung. Metallionen und biologische Wirkung, 33. Mitteilung Helvetica Chimica Acta. 38: 557-559. DOI: 10.1002/Hlca.19550380302  0.73
Low-probability matches (unlikely to be authored by this person)
1972 Thomas JL, Brintzinger H. Molybdenocene as an intermediate in reactions with hydroogen, nitrogen, and carbon monoxide Journal of the American Chemical Society. 94: 1386-1387. DOI: 10.1021/Ja00759A075  0.297
1985 Kaminsky W, Külper K, Brintzinger H, Wild FRWP. Polymerisation von Propen und Buten mit einem chiralen Zirconocen und Methylaluminoxan als Cokatalysator Angewandte Chemie. 97: 507-508. DOI: 10.1002/Ange.19850970617  0.296
2001 Tritto I, Marestin C, Boggioni L, Sacchi MC, Brintzinger HH, Ferro DR. Stereoregular and stereoirregular alternating ethylene-norbornene copolymers Macromolecules. 34: 5770-5777. DOI: 10.1021/Ma010122R  0.295
1970 Bell LG, Brintzinger H. Stoichiometric reduction of molecular nitrogen by iron complexes Journal of the American Chemical Society. 92: 4464-4465. DOI: 10.1021/Ja00717A059  0.288
2001 Schweier G, Brintzinger HH. Metallocene catalysts for the polymerization and copolymerization of α-olefins: A research collaboration project report Macromolecular Symposia. 173: 89-103. DOI: 10.1002/1521-3900(200108)173:1<89::Aid-Masy89>3.0.Co;2-O  0.287
2015 Panchenko VN, Babushkin DE, Brintzinger HH. Zirconium-allyl complexes as resting states in zirconocene-catalyzed α-olefin polymerization. Macromolecular Rapid Communications. 36: 249-53. PMID 25358835 DOI: 10.1002/marc.201400444  0.285
2014 Babushkin DE, Panchenko VN, Brintzinger H. Allylzirconiumkomplexe als Reaktionsteilnehmer bei der Zirconocen‐katalysierten α‐Olefinpolymerisation Angewandte Chemie. 126: 9799-9803. DOI: 10.1002/Ange.201403673  0.285
1990 VAN RAAIJ EU, BRINTZINGER HH, ZSOLNAI L, HUTTNER G. ChemInform Abstract: Mono- and Dicarbonyl Complexes of Decamethylchromocene. A CO-Induced η5 → η3 Ring Shift. Cheminform. 21. DOI: 10.1002/chin.199012285  0.283
1988 Christian Strauss R, Keller E, Brintzinger HH. [(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metalmetal bond Journal of Organometallic Chemistry. 340: 249-256. DOI: 10.1016/0022-328X(88)80080-9  0.283
2003 Bryliakov KP, Semikolenova NV, Yudaev DV, Zakharov VA, Brintzinger HH, Ystenes M, Rytter E, Talsi EP. 1H-, 13C-NMR and ethylene polymerization studies of zirconocene/MAO catalysts: Effect of the ligand structure on the formation of active intermediates and polymerization kinetics Journal of Organometallic Chemistry. 683: 92-102. DOI: 10.1016/S0022-328X(03)00443-1  0.278
1990 Röll W, Brintzinger H, Rieger B, Zolk R. Stereo‐ and Regioselectivity of Chiral, Alkyl‐substituted ansa‐Zirconocene Catalysts in Methylalumoxane‐activated Propene Polymerization Angewandte Chemie. 29: 279-280. DOI: 10.1002/Anie.199002791  0.275
1976 Koola JD, Brintzinger HH. Synthesis and reactions of η-cyclopentadienylhydridotris(trimethyl phosphite)chromium(II) Journal of the Chemical Society, Chemical Communications. 388-389. DOI: 10.1039/C39760000388  0.267
1975 Brintzinger H, Lohr LL, Wong KLT. Reactivity patterns of chromocene, molybdenocene, and tungstenocene reaction systems. II. Analysis in terms of molecular orbital and electron-electron repulsion energies Journal of the American Chemical Society. 97: 5146-5155. DOI: 10.1021/Ja00851A021  0.267
1967 Palmer G, Brintzinger H, Estabrook RW. Spectroscopic studies on spinach ferredoxin and adrenodoxin. Biochemistry. 6: 1658-64. PMID 4292055 DOI: 10.1021/Bi00858A012  0.266
1992 Burger P, Diebold J, Gutmann S, Hund HU, Brintzinger HH. ansa-metallocene derivatives. 24. Deviations from C2-axial symmetry in ethano- and etheno-bridged titanocene complexes: Investigation of ansa-metallocene conformations Organometallics. 11: 1319-1327.  0.263
1980 SCHNUTENHAUS H, BRINTZINGER HH. ChemInform Abstract: ANSA-METALLOCENES. 2. 1,1′-TRIMETHYLENE-BIS(η5-3-TERT-BUTYLCYCLOPENTADIENYL)TITANIUM(IV) DICHLORIDE, A CHIRAL ANSA-TITANOCENE DERIVATIVE Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198004308  0.261
1978 Bottomley F, Brintzinger HH. Reactions of nitrogen oxides with di(cyclopentadienyl)titanium complexes Journal of the Chemical Society, Chemical Communications. 234-235. DOI: 10.1039/C39780000234  0.256
2001 Forsyth J, Pereña JM, Benavente R, Pérez E, Tritto I, Boggioni L, Brintzinger HH. Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents Macromolecular Chemistry and Physics. 202: 614-620. DOI: 10.1002/1521-3935(20010301)202:5<614::Aid-Macp614>3.0.Co;2-C  0.254
1990 Röll W, Brintzinger H, Rieger B, Zolk R. Stereo- und Regioselektivität von chiralen, alkylsubstituierten ansa-Zirconocen-Katalysatoren bei der Methylalumoxan-aktivierten Propen-Polymerisation Angewandte Chemie. 102: 339-341. DOI: 10.1002/Ange.19901020336  0.253
1994 Dorer B, Prosenc MH, Rief U, Brintzinger HH. Syntheses and structures of titanocene, zirconocene, and vanadocene dichloride complexes with two ethanediyl bridges Organometallics. 13: 3868-3872.  0.252
1994 Brintzinger H, Beck S, Leclerc M, Stehling U, Röll W. 18. Reaction Mechanisms in Metallocene-Catalyzed Olefin Polymerization Studies in Surface Science and Catalysis. 89: 193-200. DOI: 10.1016/S0167-2991(08)63034-7  0.251
1971 Marvich RH, Brintzinger HH. A metastable form of titanocene. Formation from a hydride complex and reactions with hydrogen, nitrogen, and carbon monoxide [2] Journal of the American Chemical Society. 93: 2046-2048.  0.244
1990 Krauledat H, Brintzinger HH. Isotope effects associated with α-olefin insertion in zirconocene-based polymerisation catalysts: Evidence for an α-agostic transition state Angewandte Chemie (International Edition in English). 29: 1412-1413. DOI: 10.1002/Anie.199014121  0.244
1999 Beck S, Geyer A, Brintzinger HH. Diffusion coefficients of zirconocene-borate ion pairs studied by pulsed field-gradient NMR - Evidence for ion quadruples in benzene solutions Chemical Communications. 2477-2478. DOI: 10.1039/A908203D  0.244
1979 Schnutenhaus H, Brintzinger H. 1, 1′ ‐Trimethylen‐bis(η5‐3‐tert‐butylcyclopentadienyl)–titan(IV)‐dichlorid, ein chirales ansa‐Titanocen‐Derivat Angewandte Chemie. 91: 837-838. DOI: 10.1002/Ange.19790911008  0.243
1973 Pivnichny JV, Brintzinger HH. Iron(II) and iron(III) in the tetrahedral sulfide environment of a gallium sulfide host crystal Inorganic Chemistry. 12: 2839-2844. DOI: 10.1021/Ic50130A020  0.229
1966 Palmer G, Brintzinger H. Nature of the non-haem iron in ferredoxin and rubredoxin [23] Nature. 211: 189-190. PMID 4290604 DOI: 10.1038/211189A0  0.224
1999 Mansel S, Pérez E, Benavente R, Pereña JM, Bello A, Röll W, Kirsten R, Beck S, Brintzinger HH. Synthesis and properties of elastomeric poly(propylene) Macromolecular Chemistry and Physics. 200: 1292-1297. DOI: 10.1002/(Sici)1521-3935(19990601)200:6<1292::Aid-Macp1292>3.0.Co;2-G  0.22
1970 Brintzinger HH, Bartell LS. Extended Hueckel calculations related to the chemistry of titanocene Journal of the American Chemical Society. 92: 1105-1107. DOI: 10.1021/Ja00707A084  0.216
1977 Lee WS, Brintzinger HH. Reaction patterns of cyclopentadienylcobalt(I) carbonyl and acetylene derivatives Journal of Organometallic Chemistry. 127: 93-103. DOI: 10.1016/S0022-328X(00)84199-6  0.216
2010 Ringwald M, Stuermer R, Brintzinger HH. ChemInform Abstract: ansa-Metallocene Derivatives. Part 44. Asymmetric Thermal Transformation, a New Way to Enantiopure Biphenyl-Bridged Titanocene and Zirconocene Complexes: Efficient Catalysts for Asymmetric Imine Hydrogenation. Cheminform. 30: no-no. DOI: 10.1002/chin.199928070  0.203
2010 Babushkin DE, Brintzinger HH. Reactive intermediates formed during olefin polymerization by methylalumoxane-activated ansa-zirconocene catalysts: identification of a chain-carrying intermediate by NMR methods. Journal of the American Chemical Society. 132: 452-3. PMID 20020742 DOI: 10.1021/ja909157r  0.202
1985 Wild FRWP, Wasiucionek M, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. VII. Synthesis and crystal structure of a chiral ansa-zirconocene derivative with ethylene-bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 288: 63-67. DOI: 10.1016/0022-328X(85)80104-2  0.2
1967 Brintzinger H, Plane RA. Raman spectra of bis-diphosphate metal complexes in aqueous solution Inorganic Chemistry. 6: 623-625. DOI: 10.1021/Ic50049A044  0.195
1999 Ringwald M, Stürmer R, Brintzinger HH. Asymmetric Thermal Transformation, a New Way to Enantiopure Biphenyl-Bridged Titanocene and Zirconocene Complexes:  Efficient Catalysts for Asymmetric Imine HydrogenationJ. Am. Chem. Soc.1999,121, 1524−1527 Journal of the American Chemical Society. 121: 7278-7278. DOI: 10.1021/ja9955161  0.192
1979 Schnutenhaus H, Brintzinger HH. 1,1?-Trimethylenebis(?5-3-tert-butylcyclopentadienyl)-titanium(IV)Dichloride, a Chiralansa-Titanocene Derivative Angewandte Chemie International Edition in English. 18: 777-778. DOI: 10.1002/anie.197907771  0.186
1990 Röll W, Brintzinger HH, Rieger B, Zolk R. Stereo- and regioselectivity of chiral, alkyl-substituted ansa-zirconocene catalysts in methylalumoxane-ativated propene polymerization Angewandte Chemie (International Edition in English). 29: 279-280.  0.181
1998 Beck S, Brintzinger HH. Alkyl exchange between aluminum trialkyls and zirconocene dichloride complexes - A measure of electron densities at the Zr center Inorganica Chimica Acta. 270: 376-381.  0.179
1994 Stehling U, Diebold J, Kirsten R, Röll W, Brintzinger HH, Jüngling S, Mülhaupt R, Langhauser F. ansa-zirconocene polymerization catalysts with annelated ring ligands - Effects on catalytic activity and polymer chain length Organometallics. 13: 964-970.  0.169
1965 Brintzinger H. Infrared spectra of adenosine triphosphate complexes in aqueous solution [9] Journal of the American Chemical Society. 87: 1805-1806. PMID 14289345  0.168
1977 Bell LG, Brintzinger HH. Intermediates in the formation of dicyclopentadienyltungsten dicarbonyl: role of a dicyclopentadienyltungsten carbonyl chloride action Journal of Organometallic Chemistry. 135: 173-176. DOI: 10.1016/S0022-328X(00)80857-8  0.163
1985 KAMINSKY W, KUELPER K, BRINTZINGER HH, WILD FRWP. ChemInform Abstract: POLYMERIZATION OF PROPENE AND BUTENE WITH A CHIRAL ZIRCONOCENE AND METHYLALUMINOXANE AS COCATALYST Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198544083  0.163
1997 Sacchi MC, Barsties E, Tritto I, Locatelli P, Brintzinger HH, Stehling U. Stereochemistry of first monomer insertion into a metal-methyl bond: Enantioselectivity and diastereoselectivity in 3-methyl-1-pentene polymerization with metallocene catalysts Macromolecules. 30: 1267-1271.  0.163
1972 Thomas JL, Brintzinger HH. Molybdenocene as an intermediate in reactions with hydrogen, nitrogen, carbon monoxide [28] Journal of the American Chemical Society. 94: 1386-1387.  0.162
1966 Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. III. Considerations on the properties of enzymatic nitrogen-fixing systems and proposal of a general mechanism Biochemistry. 5: 3947-3950.  0.159
1963 Brintzinger H. The structures of adenosine triphosphatemetal ion complexes in aqueous solution Bba - Biochimica Et Biophysica Acta. 77: 343-345. PMID 14090454  0.158
1990 BRINTZINGER HH. ChemInform Abstract: Synthesis and Characterization of Chiral Metallocene Co-catalysts for Stereospecific α-Olefin Polymerizations Cheminform. 21. DOI: 10.1002/chin.199010348  0.156
1992 Huttenloch ME, Diebold J, Rief U, Brintzinger HH, Gilbert AM, Katz TJ. Biphenyl-bridged metallocenes that are chiral, configurationally stable, and free of diastereomers Organometallics. 11: 3600-3607. DOI: 10.1021/Om00059A024  0.155
1966 Brintzinger H, Hester RE. Vibrational analysis of some oxyanion-metal complexes Inorganic Chemistry. 5: 980-985.  0.155
1970 Bell LG, Brintzinger HH. Stoichiometric reduction of molecular nitrogen by iron complexes [9] Journal of the American Chemical Society. 92: 4464-4465.  0.148
1998 Martín S, Brintzinger HH. Cyclomagnesation of dienes catalyzed by a chiral ansa-zirconocene Inorganica Chimica Acta. 280: 189-192.  0.146
1985 Kaminsky W, Külper K, Brintzinger HH, Wild FRWP. Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst Angewandte Chemie International Edition in English. 24: 507-508. DOI: 10.1002/anie.198505071  0.143
2006 Bryliakov KP, Semikolenova NV, Panchenko VN, Zakharov VA, Brintzinger HH, Talsi EP. Activation of rac-Me2Si(ind)2ZrCl2 by methylalumoxane modified by aluminum alkyls: An EPR spin-probe,1H NMR, and polymerization study Macromolecular Chemistry and Physics. 207: 327-335. DOI: 10.1002/macp.200500443  0.138
1995 Brintzinger HH, Fischer D, Mülhaupt R, Rieger B, Waymouth RM. Stereospecific olefin polymerization with chiral metallocene catalysts Angewandte Chemie (International Edition in English). 34: 1143-1170.  0.135
1965 Brintzinger H. Metal ion catalysis of polar reactions | Metallionenkatalyse polarer Reaktionen Zeitschrift Fur Naturwissenschaftlichmedizinische Grundlagenforschung. 2: 188-202. PMID 5866560  0.125
2013 Brintzinger HH, Fischer D. Development of ansa-metallocene catalysts for isotactic olefin polymerization Advances in Polymer Science. 258: 29-42. DOI: 10.1007/12-2013-215  0.122
1970 BRINTZINGER HH, BARTELL LS. ChemInform Abstract: ERWEITERTE HUECKELBERECHNUNGEN HINSICHTLICH DER CHEMIE VON TITANOCEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/chin.197020031  0.12
1971 MARVICH RH, BRINTZINGER HH. ChemInform Abstract: EINE METASTABILE FORM VON TITANOCEN, BLDG. AUS EINEM HYDRIDKOMPLEX UND RK. MIT WASSERSTOFF, STICKSTOFF UND KOHLENMONOXID Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/chin.197128033  0.119
1937 Brintzinger H. Ascorbinsäure und Isoascorbinsäure als Reduktionsmittel zur Herstellung kolloiddisperser Lösungen von Gold, Palladium, Platin, Silber, Selen, Tellur, Molybdänblau und Wolframblau Kolloid-Zeitschrift. 78: 22-23. DOI: 10.1007/BF01502906  0.117
1972 THOMAS JL, BRINTZINGER HH. ChemInform Abstract: MOLYBDAENOCEN ALS ZWISCHENPRODUKT IN RK. MIT WASSERSTOFF, STICKSTOFF UND KOHLENMONOXID Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/chin.197220382  0.111
1966 Brintzinger H, Palmer G, Sands RH. An electron paramagnetic resonance study of metal-aromatic bonding in bis(hexamethylbenzene)iron(I) [17] Journal of the American Chemical Society. 88: 623. DOI: 10.1021/Ja00955A053  0.108
1933 Brintzinger H, Jahn E. Die Anwendung des potentialbildenden Systems Metall/Metall-Anion für die potentiometrisehe Maßanalyse I. Mitteilung: Die fällungsanalytische potentiometrische Titration von Chromat-, Molybdat-und Wolframat-Ionen, sowie einer Reihe von Metall-Ionen unter Anwendung von Chrom, Molybdän und Wolfram als Indikatorelektroden Zeitschrift FüR Analytische Chemie. 94: 396-403. DOI: 10.1007/BF01352722  0.108
2007 Brintzinger HH. Efficient and selective catalysts for olefin polymerizations-insights and challenges Rendiconti Lincei. 18: 257-269.  0.108
1935 Brintzinger H, Schall A. Die Beeinflussung der Löslichkeit schwerlöslicher Säuren und Basen durch salz- bzw. säureartige hydrophile Kolloide - II. Untersuchungen mit Gelatine Kolloid-Zeitschrift. 71: 302-307. DOI: 10.1007/BF01423793  0.096
1970 BELL LG, BRINTZINGER HH. ChemInform Abstract: STOECHIOMETRISCHE RED. VON MOLEKULAREM STICKSTOFF DURCH EISENKOMPLEXE Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/chin.197039073  0.094
1941 Brintzinger H, Hesse B. Zur Bestimmung des Kobalts als Co3O4 Zeitschrift FüR Analytische Chemie. 122: 241-243. DOI: 10.1007/BF01358778  0.093
1935 Brintzinger H, Osswald H. Cellophan und Kuprophan als Membranen fÜr die Dialyse und Elektrodialyse Kolloid-Zeitschrift. 70: 198-200. DOI: 10.1007/BF01422344  0.091
1992 Prosenc MH, Janiak C, Brintzinger HH. Agostic assistance to olefin insertion in alkylzirconocene cations: A molecular orbital study by the extended Hückel method Organometallics. 11: 4036-4041.  0.09
1948 Brintzinger H, Hesse B. Dialkylaminmethylole, Tetraalkylaminmethylendiamine und Alkyloxazolidine als GelatinehÄrtungs- und Gerbmittel Kolloid-Zeitschrift. 111: 156-166. DOI: 10.1007/BF01747542  0.09
1933 Brintzinger H, Beier HG. Die Beeinflussung der Löslichkeit schwerlöslicher Stoffe durch hydrophile Kolloide bzw. adsorbierende Stoffe - II. Löslichkeitsbeeinflussung durch Gummiarabikum Kolloid-Zeitschrift. 64: 300-304. DOI: 10.1007/BF01433941  0.089
1965 Sigel H, Brintzinger H. Inosine-N(1)-oxide nucleotide in complex formation. I. Synthesis of inosine-N(1)-oxide and its 5'-monophosphate from adenosine-N(1)-oxide and its 5'monophosphate by deamination with nitrosyl chloride | Inosin-N(1)-oxid-Nucleotide als Komplexbildner. I. Darstellung von Inosin-N(1)-oxid und dessen 5'-Monophosphat aus Adenosin-N(1)-oxid und dessen 5'-Monophosphat durch Desaminierung mit Nitrosylchlorid Helvetica Chimica Acta. 48: 433-437. PMID 5863920  0.083
1964 Zell R, Brintzinger H, Prijs B, Erlenmeyer H. Zur Biochemie autoxydabler, H2O2-bildender Verbindungen Experientia. 20: 117-119. PMID 5853669 DOI: 10.1007/BF02150683  0.082
1937 Brintzinger H, Beier H. Kautschuk, Gummi, Azetatzellulose, Nitrozellulose, Kunstharze und ähnliche Stoffe als Lösungsmittel - I. Das maximale Lösungsvermögen von Kautschuk und Gummi verschiedenen Vulkanisationsgrades für die isomeren Nitrophenole Kolloid-Zeitschrift. 79: 318-323. DOI: 10.1007/BF01501645  0.082
1929 Brintzinger H, Schieferdecker W. Die potentiometrische Bestimmung des Titans in Gegenwart anderer Metalle, insbesondere von Eisen Zeitschrift FüR Analytische Chemie. 76: 277-280. DOI: 10.1007/BF01376461  0.079
1931 Brintzinger H. Trennung und maßanalytische Bestimmung von Kupfer und Zink Zeitschrift FüR Analytische Chemie. 86: 157-159. DOI: 10.1007/BF01371308  0.065
1970 Brintzinger HH, Bartell LS. Extended hückel calculations related to the chemistry of titanocene [32] Journal of the American Chemical Society. 92: 1105-1107.  0.064
1963 Schneider P, Brintzinger H, Erlenmeyer H. Metallionen-katalysierte hydrolyse von adenosintriphosphat Experientia. 19: 623. PMID 14099854 DOI: 10.1007/BF02151280  0.063
1966 Brintzinger H, Palmer G, Sands RH. On the ligand field of iron in ferredoxin from spinach chloroplasts and related nonheme iron enzymes. Proceedings of the National Academy of Sciences of the United States of America. 55: 397-404. PMID 4287558 DOI: 10.1073/Pnas.55.2.397  0.061
1970 Brintzinger HH, Bercaw JE. The nature of so-called titanocene, (C10H10Ti)2 Journal of the American Chemical Society. 92: 6182-6185.  0.06
1975 Brintzinger HH, Lohr LL, Tang Wong KL. Reactivity patterns of chromocene, molybdenocene, and tungstenocene systems. II. An analysis in terms of molecular orbital electron-electron repulsion energies Journal of the American Chemical Society. 97: 5146-5155.  0.057
1950 Brintzinger H, Wolff H. Untersuchungen Über die Erhöhung der Wasser- und Kochbeständigkeit von Kasein- und anderen Eiweißfasern Kolloid-Zeitschrift. 118: 28-32. DOI: 10.1007/BF01511558  0.055
1934 Brintzinger H, Beier HG. Die Beeinflussung der Löslichkeit schwerlöslicher Säuren und Basen durch salz- bzw. säureartige hydrophile Kolloide - I. Untersuchungen mit Gummiarabikum und dessen freier Säure Kolloid-Zeitschrift. 68: 271-275. DOI: 10.1007/BF01428615  0.055
1941 Brintzinger H. Kaliumsulfat-Zellstoff, ein neuer hochwertiger Zellstoff Kolloid-Zeitschrift. 95: 212. DOI: 10.1007/BF01521462  0.052
1934 Brintzinger H. Ein Elektroschnelldialysator Kolloid-Zeitschrift. 66: 183-188. DOI: 10.1007/BF01434543  0.052
1930 Brintzinger H. Die Verwendung des Dialysenkoeffizienten zur Bestimmung des Molekulargewichts Die Naturwissenschaften. 18: 354-355. DOI: 10.1007/BF01501113  0.052
1933 Beier HG, Brintzinger H. Ein Luftthermostat für Löslichkeitsbestimmungen Kolloid-Zeitschrift. 64: 173-175. DOI: 10.1007/BF01434152  0.052
1940 Brintzinger H, Rost B. Die Bestimmung der Wasserstoff-Ionen-Konzentration mit Wolfram- und Molybdänelektroden Zeitschrift FüR Analytische Chemie. 120: 161-165. DOI: 10.1007/BF01548719  0.05
1933 Brintzinger H, Beier HG. Die Beeinflussung der Löslichkeit schwerlöslicher Stoffe durch hydrophile Kolloide bzw. adsorbierende Stoffe - I. Löslichkeitsbeeinflussung durch Gelatine Kolloid-Zeitschrift. 64: 160-172. DOI: 10.1007/BF01434151  0.049
1939 Brintzinger H. Widerstandsfähigkeit von Frittenfiltern gegen chemische Angriffe beim analytischen Arbeiten mit alkalischen Flüssigkeiten Kolloid-Zeitschrift. 86: 16-18. DOI: 10.1007/BF01511994  0.049
1960 Brintzinger H, Prijs B, Erlenmeyer H. Zur Rolle von Schwermetallionen im Wirkungsmechanismus von Strahlenschädigung und Strahlenschutz Experientia. 16: 468-470. DOI: 10.1007/BF02171161  0.046
1932 Brintzinger H, Beier HG. Die Erhöhung der Löslichkeit schwerlöslicher Stoffe durch die Gegenwart hydrophiler Kolloide bzw. oberflächenaktiver Stoffe Die Naturwissenschaften. 20: 254-255. DOI: 10.1007/BF01503687  0.042
1939 Brintzinger H, Rost B. Die potentiometrisehe Ferrovanadin-Analyse Zeitschrift FüR Analytische Chemie. 117: 4-6. DOI: 10.1007/BF01393172  0.042
1939 Brintzinger H, Rost B. Die potentiometrische Ferrotitan-Analyse Zeitschrift FüR Analytische Chemie. 117: 1-4. DOI: 10.1007/BF01393171  0.042
1938 Brintzinger H, Rost B. Die potentiometrische Ferromolybdän-Analyse Zeitschrift FüR Analytische Chemie. 115: 241-250. DOI: 10.1007/BF01737734  0.042
1942 Brintzinger H, Hesse B. Jodbestimmung mit der Apparatur von Grote-Kreke1er bzw. Wurzschmitt-Zimmermann Zeitschrift FüR Analytische Chemie. 123: 13-15. DOI: 10.1007/BF01735290  0.042
1938 Brintzinger H, Rost B. Die potentiometrische Analyse von Ferrochrom, von Chrom, Eisen und Molybdän in einer Probe sowie von Chrom-Molybdän-Stahl Zeitschrift FüR Analytische Chemie. 115: 250-254. DOI: 10.1007/BF01737735  0.041
1954 Brintzinger H, Orth H. Die katalytische Chlorierung organischer Verbindungen mit Hilfe der Mitführungsmethode Monatshefte FüR Chemie. 85: 1015-1023. DOI: 10.1007/BF00899850  0.041
1933 Brintzinger H, Bubam W. Zementchemische Untersuchungen Kolloid-Zeitschrift. 63: 87-93. DOI: 10.1007/BF01427997  0.041
1965 Erlenmeyer H, Brintzinger H, Sigel H, Curtius HC. Strukturspezifischer oxydativer abbau von peptid-metall-komplexen Experientia. 21: 371-372. PMID 4288352 DOI: 10.1007/BF02139740  0.039
1937 Brintzinger H, Beier H. Die Diasolyse Kolloid-Zeitschrift. 79: 324-331. DOI: 10.1007/BF01501646  0.038
1935 Brintzinger H, Schall A. Die Löslichkeit schwerlöslicher Stoffe in kolloiden Lösungen Kolloid-Zeitschrift. 71: 300-302. DOI: 10.1007/BF01423792  0.038
1935 Brintzinger H, Schlegel H. Die Reinigung von Abwässern durch Hydrogele Kolloid-Zeitschrift. 70: 321-323. DOI: 10.1007/BF01442772  0.037
1948 Brintzinger H, Titzmann R. Quantitative spektralanalytische Bestimmung von Wolfram in Schlacken Fresenius' Zeitschrift FüR Analytische Chemie. 128: 486-488. DOI: 10.1007/BF00445002  0.034
1933 Brintzinger J, Brintzinger H. Ein neuer Weg des Nachweises von Barium, Strontium und Calcium im systematischen Gang der Analyse Zeitschrift FüR Analytische Chemie. 94: 166-170. DOI: 10.1007/BF01498710  0.032
1943 Brintzinger H. Luftfreies Kohlendioxyd aus dem Kippschen Apparat für die Stickstoffbestimmung nach Dumas Zeitschrift FüR Analytische Chemie. 125: 5-6. DOI: 10.1007/BF01358850  0.029
1934 Brintzinger H, Wallach J. Das Verhalten der sekundären Alkalisulfate bei der Diffusion durch eine schwerdurchlässige Membran Kolloid-Zeitschrift. 68: 36-37. DOI: 10.1007/BF01451687  0.017
1929 Brintzinger H, Schieferdecker W. Eine potentiometrische Methode zur Bestimmung von Eisen und Molybdän Zeitschrift FüR Analytische Chemie. 78: 110-112. DOI: 10.1007/BF01361630  0.014
1995 Selg P, Brintzinger HH, Andersen RA, Horváth IT. Koordination von CO an das Erdalkalimetallocen [(Me5C5)2Ca] Angewandte Chemie. 107: 877-879. DOI: 10.1002/Ange.19951070716  0.012
1936 Brintzinger H, Schall A, Beier HG. Die maximale Adsorption - I. Mitteilung: Die maximale Adsorption schwerlöslicher Säuren und Basen an verschiedene Aktivkohlen Kolloid-Zeitschrift. 74: 29-32. DOI: 10.1007/BF01593153  0.01
1934 Brintzinger H, Jahn E. Eine Methode zur Trennung von Phosphorsäure und Calcium, sowie von Phosphorsäure, Calcium und Magnesium Zeitschrift FüR Analytische Chemie. 97: 312-314. DOI: 10.1007/BF01370666  0.01
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