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Alexander T. Radosevich, Ph.D - Publications

Affiliations: 
2011-2016 Chemistry Pennsylvania State University, State College, PA, United States 
 2016- Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
Synthetic methodology, catalysis
Website:
http://web.mit.edu/radosevichlab/index.html
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50 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Hu S, Radosevich AT. Electrophilic C(sp2)-H Cyanation with Inorganic Cyanate (OCN-) by PIII/PV=O-Catalyzed Phase Transfer Activation. Angewandte Chemie (International Ed. in English). e202409854. PMID 38950149 DOI: 10.1002/anie.202409854  0.349
2023 Roth D, Radosevich AT, Greb L. Reversible Oxidative Addition of Nonactivated C-H Bonds to Structurally Constrained Phosphenium Ions. Journal of the American Chemical Society. PMID 37877607 DOI: 10.1021/jacs.3c08456  0.34
2022 Li G, Lavagnino MN, Ali SZ, Hu S, Radosevich AT. Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society. PMID 36562776 DOI: 10.1021/jacs.2c12450  0.317
2022 Bruch QJ, Tanushi A, Müller P, Radosevich AT. Metal-Ligand Role Reversal: Hydride-Transfer Catalysis by a Functional Phosphorus Ligand with a Spectator Metal. Journal of the American Chemical Society. PMID 36378626 DOI: 10.1021/jacs.2c10200  0.303
2022 Drance MJ, Tanushi A, Radosevich AT. Two-Site O-H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand. Journal of the American Chemical Society. 144: 20243-20248. PMID 36301929 DOI: 10.1021/jacs.2c10087  0.365
2022 Hong SY, Radosevich AT. Chemoselective Primary Amination of Aryl Boronic Acids by P/P═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO. Journal of the American Chemical Society. PMID 35549268 DOI: 10.1021/jacs.2c02922  0.316
2022 Li G, Kanda Y, Hong SY, Radosevich AT. Enabling Reductive C-N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)═O Catalysts. Journal of the American Chemical Society. 144: 8242-8248. PMID 35499970 DOI: 10.1021/jacs.2c01487  0.443
2021 Lipshultz JM, Radosevich AT. Uniting Amide Synthesis and Activation by P/P-Catalyzed Serial Condensation: Three-Component Assembly of 2-Amidopyridines. Journal of the American Chemical Society. PMID 34478308 DOI: 10.1021/jacs.1c07608  0.432
2021 Li G, Miller SP, Radosevich AT. P/P═O-Catalyzed Intermolecular N-N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines. Journal of the American Chemical Society. PMID 34473484 DOI: 10.1021/jacs.1c07272  0.409
2021 Li G, Te Grotenhuis C, Radosevich AT. Reductive C-N Coupling by P/P=O-Catalysis. Trends in Chemistry. 3: 72-73. PMID 33681749 DOI: 10.1016/j.trechm.2020.10.001  0.347
2020 Lipshultz JM, Fu Y, Liu P, Radosevich AT. Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C-H borylation of heteroarenes. Chemical Science. 12: 1031-1037. PMID 34163869 DOI: 10.1039/d0sc05620k  0.351
2020 Lim S, Radosevich AT. Round-Trip Oxidative Addition, Ligand Metathesis, and Reductive Elimination in a PIII/PV Synthetic Cycle. Journal of the American Chemical Society. PMID 32909747 DOI: 10.1021/Jacs.0C07580  0.422
2020 Li G, Qin Z, Radosevich AT. P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C-N Coupling with Nitromethane as a Methylamine Surrogate. Journal of the American Chemical Society. PMID 32886500 DOI: 10.1021/Jacs.0C08035  0.526
2020 Bullock RM, Chen JG, Gagliardi L, Chirik PJ, Farha OK, Hendon CH, Jones CW, Keith JA, Klosin J, Minteer SD, Morris RH, Radosevich AT, Rauchfuss TB, Strotman NA, Vojvodic A, et al. Using nature's blueprint to expand catalysis with Earth-abundant metals. Science (New York, N.Y.). 369. PMID 32792370 DOI: 10.1126/Science.Abc3183  0.675
2020 Li G, Nykaza TV, Cooper JC, Ramirez A, Luzung MR, Radosevich AT. An Improved P(III)/P(V)=O-Catalyzed Reductive C-N Coupling of Nitroaromatics and Boronic Acids by Mechanistic Differentiation of Rate- and Product-Determining Steps. Journal of the American Chemical Society. PMID 32178514 DOI: 10.1021/Jacs.0C01666  0.793
2019 Nykaza TV, Cooper JC, Radosevich AT. a-1,2,2,3,4,4-Hexamethylphosphetane 1-oxide. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 96: 418-435. PMID 31902967 DOI: 10.15227/Orgsyn.096.0418  0.304
2019 Nykaza TV, Li G, Yang J, Luzung MR, Radosevich AT. Cascade Synthesis of N-Functionalized Azaheterocycles by P(III)/P(V)=O-Catalyzed Cyclative Coupling. Angewandte Chemie (International Ed. in English). PMID 31869510 DOI: 10.1002/Anie.201914851  0.787
2019 Gilhula JC, Radosevich AT. Tetragonal phosphorus(v) cations as tunable and robust catalytic Lewis acids. Chemical Science. 10: 7177-7182. PMID 31588285 DOI: 10.1039/C9Sc02463H  0.415
2019 Cleveland GT, Radosevich AT. A Nontrigonal Tricoordinate Phosphorus Ligand Exhibiting Reversible "Nonspectator" L/X-Switching. Angewandte Chemie (International Ed. in English). PMID 31469492 DOI: 10.1002/Anie.201909686  0.426
2019 Lecomte M, Lipshultz JM, Kim-Lee SH, Li G, Radosevich AT. Driving Recursive Dehydration by P/P Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C-N and C-C Bond Formation. Journal of the American Chemical Society. PMID 31345031 DOI: 10.1021/Jacs.9B06277  0.487
2019 Nykaza TV, Yang J, Radosevich AT. PEt-Mediated Deoxygenative C-N Coupling of Nitroarenes and Boronic Acids. Tetrahedron. 75: 3248-3252. PMID 31156275 DOI: 10.1016/J.Tet.2019.03.035  0.412
2019 Lee K, Blake A, Tanushi A, McCarthy S, Kim D, Loria S, Donahue C, Spielvogel K, Keith J, Daly S, Radosevich AT. Validating the Biphilic Hypothesis of Nontrigonal P(III) Compounds. Angewandte Chemie (International Ed. in English). PMID 30901511 DOI: 10.1002/Anie.201901779  0.451
2019 Ghosh A, Lecomte M, Kim-Lee SH, Radosevich A. Organophosphorus-Catalyzed Deoxygenation of Sulfonyl Chlorides: Electrophilic (Fluoroalkyl)sulfenylation by PIII/PV=O Redox Cycling. Angewandte Chemie (International Ed. in English). PMID 30632657 DOI: 10.1002/Anie.201813919  0.466
2019 Nykaza TV, Li G, Yang J, Luzung MR, Radosevich AT. Cascade Synthesis of N‐Functionalized Azaheterocycles by P(III)/P(V)=O‐Catalyzed Cyclative Coupling Angewandte Chemie. DOI: 10.1002/Ange.201914851  0.745
2018 Nykaza TV, Cooper JC, Li G, Mahieu N, Ramirez A, Luzung MR, Radosevich AT. Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV=O Catalysis. Journal of the American Chemical Society. PMID 30372615 DOI: 10.1021/Jacs.8B10769  0.764
2018 Tanushi A, Radosevich AT. Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane. Journal of the American Chemical Society. PMID 29923715 DOI: 10.1021/Jacs.8B05156  0.364
2018 Lin YC, Gilhula JC, Radosevich AT. Nontrigonal constraint enhances 1,2-addition reactivity of phosphazenes. Chemical Science. 9: 4338-4347. PMID 29780566 DOI: 10.1039/C8Sc00929E  0.418
2018 Nykaza TV, Ramirez A, Harrison TS, Luzung MR, Radosevich AT. Biphilic Organophosphorus-Catalyzed Intramolecular Csp2-H Amination: Evidence for a Nitrenoid in Catalytic Cadogan Cyclizations. Journal of the American Chemical Society. PMID 29389114 DOI: 10.1021/Jacs.7B13803  0.774
2017 Pistner AJ, Moon HW, Silakov A, Yennawar HP, Radosevich AT. Stable Open-Shell Phosphorane Based on a Redox-Active Amidodiphenoxide Scaffold. Inorganic Chemistry. PMID 28661124 DOI: 10.1021/Acs.Inorgchem.7B00657  0.764
2017 Nykaza TV, Harrison TS, Ghosh A, Putnik RA, Radosevich AT. A Biphilic Phosphetane Catalyzes N-N Bond-Forming Cadogan Heterocyclization via P(III)/P(V)═O Redox Cycling. Journal of the American Chemical Society. PMID 28489354 DOI: 10.1021/Jacs.7B03260  0.542
2017 Lin YC, Hatzakis E, McCarthy SM, Reichl KD, Lai TY, Yennawar HP, Radosevich AT. P-N Cooperative Borane Activation and Catalytic Hydroboration by a Distorted Phosphorous Triamide Platform. Journal of the American Chemical Society. PMID 28398750 DOI: 10.1021/Jacs.7B02512  0.778
2015 Wang SR, Radosevich AT. P(NMe2)3-Mediated Umpolung Alkylation and Nonylidic Olefination of α-Keto Esters. Organic Letters. PMID 26176378 DOI: 10.1021/Acs.Orglett.5B01784  0.453
2015 Reichl KD, Dunn NL, Fastuca NJ, Radosevich AT. Biphilic Organophosphorus Catalysis: Regioselective Reductive Transposition of Allylic Bromides via P(III)/P(V) Redox Cycling. Journal of the American Chemical Society. 137: 5292-5. PMID 25874950 DOI: 10.1021/Jacs.5B01899  0.779
2015 Zhao W, Yan PK, Radosevich AT. A phosphetane catalyzes deoxygenative condensation of α-keto esters and carboxylic acids via P(III)/P(V)═O redox cycling. Journal of the American Chemical Society. 137: 616-9. PMID 25564133 DOI: 10.1021/Ja511889Y  0.493
2014 Zhao W, McCarthy SM, Lai TY, Yennawar HP, Radosevich AT. Reversible intermolecular E-H oxidative addition to a geometrically deformed and structurally dynamic phosphorous triamide. Journal of the American Chemical Society. 136: 17634-44. PMID 25401723 DOI: 10.1021/Ja510558D  0.433
2014 Reichl KD, Radosevich AT. A phosphine-mediated stereocontrolled synthesis of Z-enediynes by a vicinal dialkynylation of ethynylphosphonium salts. Chemical Communications (Cambridge, England). 50: 9302-5. PMID 25000554 DOI: 10.1039/C4Cc03415E  0.755
2014 McCarthy SM, Lin YC, Devarajan D, Chang JW, Yennawar HP, Rioux RM, Ess DH, Radosevich AT. Intermolecular N-H oxidative addition of ammonia, alkylamines, and arylamines to a planar σ(3)-phosphorus compound via an entropy-controlled electrophilic mechanism. Journal of the American Chemical Society. 136: 4640-50. PMID 24597970 DOI: 10.1021/Ja412469E  0.43
2013 Reichl KD, Ess DH, Radosevich AT. Catalyzing pyramidal inversion: configurational lability of P-stereogenic phosphines via single electron oxidation. Journal of the American Chemical Society. 135: 9354-7. PMID 23745778 DOI: 10.1021/Ja404943X  0.776
2013 Zhao W, Fink DM, Labutta CA, Radosevich AT. A C(sp3)-C(sp3) bond forming reductive condensation of α-keto esters and enolizable carbon pronucleophiles. Organic Letters. 15: 3090-3. PMID 23738614 DOI: 10.1021/Ol401276B  0.385
2013 Sathe AA, Hartline DR, Radosevich AT. A synthesis of α-amino acids via direct reductive carboxylation of imines with carbon dioxide. Chemical Communications (Cambridge, England). 49: 5040-2. PMID 23620277 DOI: 10.1039/C3Cc42057D  0.349
2013 Wang SR, Radosevich AT. Reductive homocondensation of benzylidene- and alkylidenepyruvate esters by a P(NMe2)3-mediated tandem reaction. Organic Letters. 15: 1926-9. PMID 23578192 DOI: 10.1021/Ol400576E  0.464
2012 Miller EJ, Zhao W, Herr JD, Radosevich AT. A nonmetal approach to α-heterofunctionalized carbonyl derivatives by formal reductive X-H insertion. Angewandte Chemie (International Ed. in English). 51: 10605-9. PMID 22997095 DOI: 10.1002/Anie.201205604  0.337
2012 Dunn NL, Ha M, Radosevich AT. Main group redox catalysis: reversible P(III)/P(V) redox cycling at a phosphorus platform. Journal of the American Chemical Society. 134: 11330-3. PMID 22746974 DOI: 10.1021/Ja302963P  0.477
2010 Melnick JG, Radosevich AT, Villagrán D, Nocera DG. Decarbonylation of ethanol to methane, carbon monoxide and hydrogen by a [PNP]Ir complex. Chemical Communications (Cambridge, England). 46: 79-81. PMID 20024299 DOI: 10.1039/B914083B  0.49
2009 Radosevich AT, Melnick JG, Stoian SA, Bacciu D, Chen CH, Foxman BM, Ozerov OV, Nocera DG. Ligand reactivity in diarylamido/bis(phosphine) PNP complexes of Mn(CO)3 and Re(CO)3. Inorganic Chemistry. 48: 9214-21. PMID 19736909 DOI: 10.1021/Ic9010218  0.712
2008 Radosevich AT, Chan VS, Shih HW, Toste FD. Synthesis of (-)-octalactin a by a strategic vanadium-catalyzed oxidative kinetic resolution. Angewandte Chemie (International Ed. in English). 47: 3755-8. PMID 18399552 DOI: 10.1002/Anie.200800554  0.665
2005 Ohri RV, Radosevich AT, Hrovat KJ, Musich C, Huang D, Holman TR, Toste FD. A Re(V)-catalyzed C-N bond-forming route to human lipoxygenase inhibitors. Organic Letters. 7: 2501-4. PMID 15932233 DOI: 10.1021/Ol050897A  0.586
2005 Radosevich AT, Musich C, Toste FD. Vanadium-catalyzed asymmetric oxidation of alpha-hydroxy esters using molecular oxygen as stoichiometric oxidant. Journal of the American Chemical Society. 127: 1090-1. PMID 15669834 DOI: 10.1021/Ja0433424  0.588
2003 Sherry BD, Radosevich AT, Toste FD. A mild C-O bond formation catalyzed by a rhenium-oxo complex. Journal of the American Chemical Society. 125: 6076-7. PMID 12785836 DOI: 10.1021/Ja0343050  0.735
2001 Radosevich AT, Wiest O. Quantum mechanical study of the ring-closing reaction of the hexatriene radical cation. The Journal of Organic Chemistry. 66: 5808-13. PMID 11511256 DOI: 10.1021/Jo0103524  0.517
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