Alexander Constantin Filippou, Dr. - Publications

Affiliations: 
Chemistry Rheinische Friedrich-Wilhelms-Universität Bonn, Bonn, Nordrhein-Westfalen, Germany 
Area:
Organometallic Chemistry
Website:
http://www.filippou.chemie.uni-bonn.de/group/members/filippou

122 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2025 Tomer K, Schnakenburg G, Das U, Filippou AC. Metal-silicon triple bonds: reactivity of the silylidyne complexes [Cp*(CO)M[triple bond, length as m-dash]Si-Tbb] (M = Cr - W). Chemical Science. PMID 40201161 DOI: 10.1039/d5sc01063b  0.669
2021 Karwasara S, Maurer LR, Peerless B, Schnakenburg G, Das U, Filippou AC. (NHC)Si═C═N-R: A Two-Coordinated Si-Isocyanide Compound as Si(NHC) Transfer Reagent. Journal of the American Chemical Society. PMID 34469138 DOI: 10.1021/jacs.1c06628  0.332
2020 Ghana P, Rump J, Schnakenburg G, Arz MI, Filippou AC. Planar Tetracoordinated Silicon (ptSi): Room-Temperature Stable Compounds Containing Anti-van't Hoff/Le Bel Silicon. Journal of the American Chemical Society. PMID 33347313 DOI: 10.1021/jacs.0c11628  0.794
2018 Ghana P, Arz MI, Chakraborty U, Schnakenburg G, Filippou AC. Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si-M and M=Si=M. Journal of the American Chemical Society. PMID 29730935 DOI: 10.1021/jacs.8b02902  0.798
2017 Filippou AC, Hoffmann D, Schnakenburg G. Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ-tmps)(CO)Nb 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 E-R] (E = Si, Ge, Sn; tmps = MeSi(CHPMe); R = aryl). Chemical Science. 8: 6290-6299. PMID 29896377 DOI: 10.1039/c7sc02708g  0.467
2017 Ghana P, Arz MI, Schnakenburg G, Straßmann M, Filippou AC. Metal–Silicon Triple Bonds: Access to [Si(η5-C5Me5)]+from SiX2(NHC) and its Conversion to the Silylidyne Complex [TpMe(CO)2MoSi(η3-C5Me5)] (TpMe= κ3-N,N′,N″-hydridotris(3,5-dimethyl-1-pyrazolyl)borate) Organometallics. 37: 772-780. DOI: 10.1021/ACS.ORGANOMET.7B00665  0.436
2016 Arz MI, Schnakenburg G, Meyer A, Schiemann O, Filippou AC. The SiH radical supported by two N-heterocyclic carbenes. Chemical Science. 7: 4973-4979. PMID 30155147 DOI: 10.1039/c6sc01569g  0.386
2016 Arz MI, Straßmann M, Geiß D, Schnakenburg G, Filippou AC. Addition of Small Electrophiles to NHC-stabilized Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon Chemistry. Journal of the American Chemical Society. PMID 26978031 DOI: 10.1021/jacs.6b01018  0.39
2015 Arz MI, Geiß D, Straßmann M, Schnakenburg G, Filippou AC. Silicon(i) chemistry: the NHC-stabilised silicon(i) halides SiX(Idipp) (X = Br, I) and the disilicon(i)-iodido cation [Si(I)(Idipp)]. Chemical Science. 6: 6515-6524. PMID 30090270 DOI: 10.1039/c5sc02681d  0.358
2015 Ghana P, Arz MI, Das U, Schnakenburg G, Filippou AC. Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene. Angewandte Chemie (International Ed. in English). 54: 9980-5. PMID 26136260 DOI: 10.1002/anie.201504494  0.773
2015 Geiß D, Arz MI, Straßmann M, Schnakenburg G, Filippou AC. Si=P double bonds: experimental and theoretical study of an NHC-stabilized phosphasilenylidene. Angewandte Chemie (International Ed. in English). 54: 2739-44. PMID 25600317 DOI: 10.1002/anie.201411264  0.325
2014 Lebedev YN, Das U, Chernov O, Schnakenburg G, Filippou AC. [2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9280-9. PMID 24939862 DOI: 10.1002/chem.201403108  0.325
2014 Filippou AC, Baars B, Chernov O, Lebedev YN, Schnakenburg G. Silicon-oxygen double bonds: a stable silanone with a trigonal-planar coordinated silicon center. Angewandte Chemie (International Ed. in English). 53: 565-70. PMID 24288183 DOI: 10.1002/anie.201308433  0.369
2013 Filippou AC, Ghana P, Chakraborty U, Schnakenburg G. Manganese-tin triple bonds: a new synthetic route to the manganese stannylidyne complex cation trans-[H(dmpe)2Mn≡Sn(C6H3-2,6-Mes2)]+ (dmpe = Me2PCH2CH2PMe2, Mes = 2,4,6-trimethylphenyl). Journal of the American Chemical Society. 135: 11525-8. PMID 23869528 DOI: 10.1021/ja406290t  0.795
2013 Filippou AC, Lebedev YN, Chernov O, Straßmann M, Schnakenburg G. Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+. Angewandte Chemie (International Ed. in English). 52: 6974-8. PMID 23712776 DOI: 10.1002/anie.201301363  0.36
2013 Filippou AC, Chakraborty U, Schnakenburg G. Rhenium-germanium triple bonds: syntheses and reactions of the germylidyne complexes mer-[X2(PMe3)3Re≡Ge-R] (X=Cl, I, H; R=m-terphenyl). Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 5676-86. PMID 23447550 DOI: 10.1002/chem.201300017  0.431
2013 Askevold B, Friedrich A, Buchner MR, Lewall B, Filippou AC, Herdtweck E, Schneider S. Reactivity of iridium(I) PNP amido complexes toward protonation and oxidation Journal of Organometallic Chemistry. 744: 35-40. DOI: 10.1016/J.Jorganchem.2013.04.022  0.502
2013 Filippou AC, Lebedev YN, Chernov O, Straßmann M, Schnakenburg G. Silicon(II) coordination chemistry: N-heterocyclic carbene complexes of Si2+ and SiI+ Angewandte Chemie - International Edition. 52: 6974-6978. DOI: 10.1002/anie.201301363  0.36
2012 Filippou AC, Barandov A, Schnakenburg G, Lewall B, van Gastel M, Marchanka A. Open-shell complexes containing metal-germanium triple bonds. Angewandte Chemie (International Ed. in English). 51: 789-93. PMID 22173926 DOI: 10.1002/anie.201107120  0.332
2012 Filippou AC, Stumpf KW, Chernov O, Schnakenburg G. Metal activation of a germylenoid, a new approach to metalgermanium triple bonds: Synthesis and reactions of the germylidyne complexes [cp(co) 2m=gec(sime3)3] (m = mo, w) Organometallics. 31: 748-755. DOI: 10.1021/om201176n  0.379
2012 Filippou AC, Barandov A, Schnakenburg G, Lewall B, Van Gastel M, Marchanka A. Open-shell complexes containing metal-germanium triple bonds Angewandte Chemie - International Edition. 51: 789-793. DOI: 10.1002/anie.201107120  0.332
2011 Filippou AC, Chernov O, Schnakenburg G. Chromium-silicon multiple bonds: the chemistry of terminal N-heterocyclic-carbene-stabilized halosilylidyne ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 13574-83. PMID 22038596 DOI: 10.1002/chem.201102659  0.466
2011 Filippou AC, Chernov O, Schnakenburg G. Metal-silicon triple bonds: nucleophilic addition and redox reactions of the silylidyne complex [Cp(CO)2 Mo≡Si-R]. Angewandte Chemie (International Ed. in English). 50: 1122-6. PMID 21268209 DOI: 10.1002/anie.201005794  0.36
2011 Filippou AC, Chernov O, Schnakenburg G. Chromium-silicon multiple bonds: The chemistry of terminal N-heterocyclic-carbene-stabilized halosilylidyne ligands Chemistry - a European Journal. 17: 13574-13583. DOI: 10.1002/chem.201102659  0.319
2011 Filippou AC, Chernov O, Schnakenburg G. Metal-silicon triple bonds: Nucleophilic addition and redox reactions of the silylidyne complex [Cp(CO)2MoξSi-R] Angewandte Chemie - International Edition. 50: 1122-1126. DOI: 10.1002/anie.201005794  0.36
2010 Filippou AC, Chernov O, Stumpf KW, Schnakenburg G. Metal-silicon triple bonds: the molybdenum silylidyne complex [Cp(CO)2Mo[triple bond]Si-R]. Angewandte Chemie (International Ed. in English). 49: 3296-300. PMID 20401886 DOI: 10.1002/anie.201000837  0.381
2010 Filippou AC, Chernov O, Blom B, Stumpf KW, Schnakenburg G. Stable N-heterocyclic carbene adducts of arylchlorosilylenes and their germanium homologues. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 2866-72. PMID 20077546 DOI: 10.1002/Chem.200903019  0.618
2010 FILIPPOU AC, GRUENLEITNER W, FISCHER EO. ChemInform Abstract: Transition-Metal Carbyne Complexes. Part 100. Synthesis of Electron- Rich Diethylaminocarbyne Complexes (V) of Tungsten from Cp(Br)2(CO)W. tplbond.CNEt2. Cheminform. 22: no-no. DOI: 10.1002/CHIN.199116224  0.483
2010 Filippou AC, Chernov O, Blom B, Stumpf KW, Schnakenburg G. Stable N-heterocyclic carbene adducts of arylchlorosilylenes and their germanium homologues Chemistry - a European Journal. 16: 2866-2872. DOI: 10.1002/chem.200903019  0.562
2010 Filippou AC, Chernov O, Stumpf KW, Schnakenburg G. Metal-silicon triple bonds: The molybdenum silylidyne complex [Cp(CO) 2Mo = Si-R] Angewandte Chemie - International Edition. 49: 3296-3300. DOI: 10.1002/anie.201000837  0.382
2008 Rohde H, Menzel M, Renz F, Filippou AC. Investigation of Mo- and W-stannylidyne complexes by Mössbauer spectroscopy Hyperfine Interactions. 185: 129-132. DOI: 10.1007/s10751-008-9821-7  0.351
2006 Filippou AC, Weidemann N, Philippopoulos AI, Schnakenburg G. Activation of aryl germanium(II) chlorides by [Mo(PMe3) 6] and [W(η2-CH2PMe2)H(PMe 3)4]: A new route to metal-germanium triple bonds Angewandte Chemie - International Edition. 45: 5987-5991. DOI: 10.1002/anie.200602061  0.307
2005 Filippou AC, Schnakenburg G, Philippopoulos AI, Weidemann N. Ge2 trapped by triple bonds between two metal centers: the germylidyne complexes trans,trans-[Cl(depe)2M[triple chemical bond]Ge--Ge[triple chemical bond]M(depe)2Cl] (M=Mo, W) and bonding analyses of the M[triple chemical bond]Ge--Ge[triple chemical bond]M chain. Angewandte Chemie (International Ed. in English). 44: 5979-85. PMID 16106455 DOI: 10.1002/anie.200501968  0.371
2005 Filippou AC, Schnakenburg G, Philippopoulos AI, Weidemann N. Ge2 trapped by triple bonds between two metal centers: The germylidyne complexes trans,trans-[Cl(depe)2M≡Ge- Ge≡M(depe)2Cl] (M = Mo, W) and bonding analyses of the M≡Ge-Ge≡M chain Angewandte Chemie - International Edition. 44: 5979-5985. DOI: 10.1002/anie.200501968  0.427
2004 Filippou AC, Weidemann N, Schnakenburg G, Rohde H, Philippopoulos AI. Tungsten-lead triple bonds: syntheses, structures, and coordination chemistry of the plumbylidyne complexes trans-[X(PMe3)4W[triple bond]Pb(2,6-Trip2C6H3)]. Angewandte Chemie (International Ed. in English). 43: 6512-6. PMID 15578776 DOI: 10.1002/anie.200461725  0.357
2004 Filippou AC, Rohde H, Schnakenburg G. Triple bond to lead: synthesis and characterization of the plumbylidyne complex trans-[Br(PMe(3))(4)Mo[triple chemical bond]Pb--C(6)H(3)-2,6-Trip(2)]. Angewandte Chemie (International Ed. in English). 43: 2243-7. PMID 15108133 DOI: 10.1002/anie.200353477  0.379
2004 Filippou AC, Weidemann N, Schnakenburg G, Rohde H, Philippopoulos AI. Tungsten-lead triple bonds: Syntheses, structures, and coordination chemistry of the plumbylidyne complexes trans-[X(PMe3) 4W≡Pb(2,6-Trip2C6H3)] Angewandte Chemie - International Edition. 43: 6512-6516. DOI: 10.1002/anie.200461725  0.362
2004 Filippou AC, Rohde H, Schnakenburg G. Triple bond to lead: Synthesis and characterization of the plumbylidyne complex trans-[Br(PMe3)4Mo≡Pb-C6H 3-2,6-Trip2] Angewandte Chemie - International Edition. 43: 2243-2247. DOI: 10.1002/anie.200353477  0.38
2003 Filippou AC, Schneider S, Schnakenburg G. [Na(THF)2Cr(N3N)]: The first trigonal monopyramidal chromium(II) complex. Inorganic Chemistry. 42: 6974-6. PMID 14577759 DOI: 10.1021/Ic0349961  0.472
2003 Filippou AC, Schneider S, Schnakenburg G. A pair of remarkably stable mononuclear chromium(III) and chromium(IV) hydrides. Angewandte Chemie (International Ed. in English). 42: 4486-9. PMID 14520745 DOI: 10.1002/Anie.200352177  0.423
2003 Filippou AC, Portius P, Philippopoulos AI, Rohde H. Triple bonding to tin: synthesis and characterization of the stannylyne complex trans-[Cl(PMe3)4W[triple bond]Sn-C6H3-2,6-Mes2]. Angewandte Chemie (International Ed. in English). 42: 445-7. PMID 12569513 DOI: 10.1002/anie.200390135  0.388
2003 Filippou AC, Philippopoulos AI, Schnakenburg G. Triple bonding to tin: Synthesis and characterization of the square-pyramidal stannylyne complex cation [(dppe)2W≡Sn-C 6H3-2,6-Mes2]+ (dppe = Ph 2PCH2CH2PPh2, Mes = C 6H2-2,4,6-Me3) Organometallics. 22: 3339-3341. DOI: 10.1021/om030303c  0.31
2003 Filippou AC, Schneider S. Unusually stable chromium(IV) alkyls bearing a triamidoamine ligand Organometallics. 22: 3010-3012. DOI: 10.1021/Om030273D  0.508
2003 Filippou AC, Schneider S, Schnakenburg G. [Na(THF)2Cr(N3N)]: The First Trigonal Monopyramidal Chromium(II) Complex Inorganic Chemistry. 42: 6974-6976. DOI: 10.1021/ic0349961  0.455
2003 Filippou AC, Portius P, Philippopoulos AI, Rohde H. Triple bonding to tin: Synthesis and characterization of the stannylyne complex trans-[Cl(PMe3)4W≡Sn-C6 H3-2,6-Mes2] Angewandte Chemie - International Edition. 42: 445-447. DOI: 10.1002/anie.200390135  0.393
2003 Filippou AC, Schneider S, Schnakenburg G. A pair of remarkably stable mononuclear chromium(III) and chromium(IV) hydrides Angewandte Chemie - International Edition. 42: 4486-4489. DOI: 10.1002/anie.200352177  0.423
2002 Filippou AC, Portius P, Philippopoulos AI. Molybdenum and tungsten germylyne complexes of the general formula trans-[X(dppe)2M≡Ge-(η1-Cp*)] (X = Cl, Br, I; dppe = Ph2PCH2CH2PPh2; Cp* = C5Me5): Syntheses, molecular structures, and bonding features of the germylyne ligand Organometallics. 21: 653-661. DOI: 10.1021/om010785x  0.347
2001 Schneider S, Filippou AC. Triamidoamine complexes of chromium(III) and chromium(IV) Inorganic Chemistry. 40: 4674-4677. PMID 11511214 DOI: 10.1021/Ic010361V  0.537
2001 Filippou AC, Portius P, Winter JG, Kociok-Köhn G. Stereoselective insertion of GeCl2 into tungsten-chlorine bonds of aminomethylene and aminocarbyne complexes Journal of Organometallic Chemistry. 628: 11-24. DOI: 10.1016/S0022-328X(01)00748-3  0.363
2001 Filippou AC, Portius P, Winter JG, Kociok-Köhn G. Stereoselective insertion of GeCl2 into tungsten-chlorine bonds of aminomethylene and aminocarbyne complexes Journal of Organometallic Chemistry. 628: 11-24. DOI: 10.1016/S0022-328X(01)00748-3  0.363
2001 Filippou AC, Portius P, Jankowski C. Aminomethylene complexes of molybdenum(IV) and tungsten(IV) bearing 1,2-dithiolato ligands Journal of Organometallic Chemistry. 617: 656-670.  0.328
2001 Filippou AC, Portius P, Jankowski C. Aminomethylene complexes of molybdenum(IV) and tungsten(IV) bearing 1,2-dithiolato ligands Journal of Organometallic Chemistry. 617: 656-670.  0.328
2000 Filippou AC, Philippopoulos AI, Portius P, Neumann DU. Synthesis and structure of the germylyne complexes trans-[X (dppe)2W≡Ge(η1-Cp) ] (X = Cl, Br, I) and comparison of the W≡E bonds (E = C, Ge) by density functional calculations Angewandte Chemie - International Edition. 39: 2778-2781. DOI: 10.1002/1521-3773(20000804)39:15<2778::AID-ANIE2778>3.0.CO;2-2  0.308
2000 Filippou AC, Philippopoulos AI, Portius P, Neumann DU. Synthesis and structure of the germylyne complexes trans-[X (dppe)2W≡Ge(η1-Cp) ] (X = Cl, Br, I) and comparison of the W≡E bonds (E = C, Ge) by density functional calculations Angewandte Chemie - International Edition. 39: 2778-2781. DOI: 10.1002/1521-3773(20000804)39:15<2778::AID-ANIE2778>3.0.CO;2-2  0.308
1998 Filippou AC, Winter JG, Feist M, Kociok-Köhn G, Hinz I. Trichlorogermyl complexes of molybdenum and tungsten bearing cyclopentadienyl ligands: Synthesis, structure and isomerization studies Polyhedron. 17: 1103-1114.  0.314
1997 Filippou AC, Winter JG, Kociok-Köhn G, Hinz I. Insertion of GeCl2 into group VI transition metal-chlorine bonds: Synthesis, spectroscopy and structure of molybdenum and tungsten trichlorogermyl complexes Journal of Organometallic Chemistry. 542: 35-49.  0.317
1997 Filippou AC, Wössner D, Kociok-Köhn G, Hinz I. Metal-carbon multiple bonds: Half-sandwich phenylcarbyne complexes of chromium - Synthesis, structure, electrochemistry and reactions with PMe3 Journal of Organometallic Chemistry. 541: 333-343.  0.309
1997 Filippou AC, Wössner D, Kociok-Köhn G, Hinz I, Gruber L. Metal-carbon multiple bonds: Synthesis, structure, and electrochemistry of chromium aminocarbyne and phenylcarbyne complexes bearing phosphine or alkyl isonitrile ligands Journal of Organometallic Chemistry. 532: 207-218.  0.342
1996 Filippou AC, Lungwitz B, Kociok-Köhn G, Hinz I. Half-sandwich rhenium(III) acyl complexes: Synthesis, structure and conversion to rhenium(I) and rhenium(III) isonitrile complexes 1 Journal of Organometallic Chemistry. 524: 133-146. DOI: 10.1016/S0022-328X(96)06401-7  0.317
1996 Filippou AC, Wössner D, Lungwitz B, Kociok-Köhn G. Carbene Complexes of Divalent Chromium Angewandte Chemie (International Edition in English). 35: 876-878.  0.335
1995 Fischer EO, Apostolidis C, Rebizant J, Dornberger E, Kanellakopulos B, Müller J, Powietzka B, Roth W, Filippou AC, Lungwitz B. Carbene and Carbyne Complexes of Technetium and Rhenium - Synthesis, Structure and Reactions | Carben- und Carbin-Komplexe des Technetiums und Rheniums – Synthese, Struktur und Reaktionen Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 50: 1382-1395. DOI: 10.1515/Znb-1995-0916  0.562
1995 Lungwitz B, Filippou AC. Metal-carbon multiple bonds: novel syntheses and reactions of aminocarbyne complexes of tungsten Journal of Organometallic Chemistry. 498: 91-107. DOI: 10.1016/0022-328X(95)05483-6  0.445
1995 Filippou AC, Mehnert C, Wanninger KMA, Kleine M. Chromium-carbon multiple bonds: aminocarbyne complexes of chromium bearing isocyanide ligands Journal of Organometallic Chemistry. 491: 47-55. DOI: 10.1016/0022-328X(94)05208-S  0.438
1995 Filippou AC, Mehnert C, Wanninger KMA, Kleine M. Chromium-carbon multiple bonds: aminocarbyne complexes of chromium bearing isocyanide ligands Journal of Organometallic Chemistry. 491: 47-55.  0.332
1993 Filippou AC, Hofmann P, Kiprof P, Schmid HR, Wagner C. Mononuclear bis-aminocarbyne complexes of tungsten with Tp′ ligands; theory of metal-centred carbyne-carbyne coupling Journal of Organometallic Chemistry. 459: 233-247. DOI: 10.1016/0022-328X(93)86076-T  0.45
1993 Filippou AC, Völkl C, Rogers RD. Metal-centred CC coupling of nitriles with 1-azaallyl ligands; synthesis and structure of β-diiminato complexes of tungsten Journal of Organometallic Chemistry. 463: 135-142. DOI: 10.1016/0022-328X(93)83410-W  0.403
1993 Filippou AC, Wanninger K, Mehnert C. Half-sandwich aminocarbyne complexes of chromium Journal of Organometallic Chemistry. 461: 99-109. DOI: 10.1016/0022-328X(93)83281-Y  0.448
1993 Filippou AC, Wanninger K, Mehnert C. Half-sandwich aminocarbyne complexes of chromium Journal of Organometallic Chemistry. 461: 99-109. DOI: 10.1016/0022-328X(93)83281-Y  0.319
1992 Filippou AC, Wagner C, Fischer EO, Völkl C. Übergangsmetall-Carbin-Komplexe. CIII. Aktivierung von Ethylisocyanid an elektronenreichen Metallzentren; Synthese von einkernigen Wolfram-Aminocarbin-Komplexen des Typs Tp′(CO)2 WCN(R)Et (R Me, Et) Journal of Organometallic Chemistry. 438: C15-C22. DOI: 10.1016/0022-328X(92)83421-D  0.538
1992 Filippou AC, Völkl C, Grünleitner W, Kiprof P. Carbyne-carbyne coupling at a single metal center. Synthesis structure of bis(diethylamino)acetylene complexes of molybdenum(II) and tungsten(II) Journal of Organometallic Chemistry. 434: 201-223. DOI: 10.1016/0022-328X(92)83306-3  0.525
1992 Martins AM, Calhorda MJ, Romão CC, Völkl C, Kiprof P, Filippou AC. Synthesis and reactivity of molybdenocene isocyanide complexes; crystal structure of (η5-C5H5)2MoCNtBu Journal of Organometallic Chemistry. 423: 367-390. DOI: 10.1016/0022-328X(92)83131-Z  0.538
1992 Filippou AC, Grünleitner W, Fischer EO. Übergangsmetall-carbin-komplexe. CII. Alkylierung von Na[CpMo(CO)2(CNtBu)]; einfluβ des isocyanid-substituenten auf den reaktionsablauf Journal of Organometallic Chemistry. 428: C37-C43. DOI: 10.1016/0022-328X(92)83107-S  0.588
1991 Filippou AC, Grünleitner W. Acid-Induced CC-Coupling of Isocyanide Ligands in Homoleptic Alkylisocyanide Complexes of Mo(0) and W(0) | Säure-induzierte CC-Kupplung von Isocyanid-Liganden in homoleptischen Alkylisocyanid-Komplexen von Mo(0) und W(0) Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 46: 216-230. DOI: 10.1515/Znb-1991-0216  0.402
1991 Filippou AC, Grünleitner W, Fischer EO. Übergangsmetall-Carbin-Komplexe. C. Synthese elektronenreicher Diethylaminocarbin-Komplexe des Wolframs aus Cp(Br)2(CO)WCNEt2 Journal of Organometallic Chemistry. 401: C37-C42. DOI: 10.1016/0022-328X(91)86237-K  0.555
1991 Filippou AC, Grünleitner W. Elektronenreiche isocyanid-substituierte Diethylaminocarbin-Komplexe des Wolframs mit Einem Pentamethylcyclopentadienyl-Liganden Journal of Organometallic Chemistry. 407: 61-79. DOI: 10.1016/0022-328X(91)83140-Y  0.454
1991 Filippou AC, Grünleitner W, Otto Fischer E. Übergangsmetall-Carbin-Komplexe. CI. Gezielter Aufbau eines Diethylaminocarbin-Liganden am Wolfram aus Ethylisocyanid-Vorstufen Journal of Organometallic Chemistry. 411: C21-C26. DOI: 10.1016/0022-328X(91)83053-7  0.38
1991 Filippou AC, Völkl C, Kiprof P. Selective synthesis of four- and five-membered metallaheterocycles via CC bond-forming reactions of η2-iminoacyl and η3-1-azaallyl complexes of tungsten with alkyl isocyanides Journal of Organometallic Chemistry. 415: 375-394. DOI: 10.1016/0022-328X(91)80138-A  0.38
1991 Filippou AC, Völkl C, Kiprof P. Selective synthesis of four- and five-membered metallaheterocycles via CC bond-forming reactions of η2-iminoacyl and η3-1-azaallyl complexes of tungsten with alkyl isocyanides Journal of Organometallic Chemistry. 415: 375-394. DOI: 10.1016/0022-328X(91)80138-A  0.38
1991 Filippou AC, Grünleitner W, Völkl C. CC-coupling reactions at low-valent molybdenum centers. Selective formation of η2-iminoacyl, η3-1-azaallyl and η2-1,4-diazabutadien-2-yl complexes of molybdenum from ethyl isocyanide complexes Journal of Organometallic Chemistry. 413: 181-203. DOI: 10.1016/0022-328X(91)80049-P  0.542
1991 Filippou AC, Grünleitner W, Völkl C. CC-coupling reactions at low-valent molybdenum centers. Selective formation of η2-iminoacyl, η3-1-azaallyl and η2-1,4-diazabutadien-2-yl complexes of molybdenum from ethyl isocyanide complexes Journal of Organometallic Chemistry. 413: 181-203. DOI: 10.1016/0022-328X(91)80049-P  0.374
1991 Filippou AC, Grünleitner W, Fischer EO, Imhof W, Huttner G. Übergangsmetall-Carbin-Komplexe. XCIX. Synthese und röntgenstruktur von (η5-C5Me5)(CO)2MOCNEt2, dem ersten niedervalenten Diethylaminocarbin-Komplex von Molybdän mit einem Pentamethylcyclopentadienyl-Liganden Journal of Organometallic Chemistry. 413: 165-179. DOI: 10.1016/0022-328X(91)80048-O  0.689
1991 Filippou AC, Grünleitner W, Kiprof P. Alkylierungsreaktionen eines anionischen ethylisocyanid-komplexes von W0; Synthese von alkyl-, η2-iminoacyl-, 1-azaallyl- und dialkylaminocarbin-komplexen des wolframs Journal of Organometallic Chemistry. 410: 175-210. DOI: 10.1016/0022-328X(91)80006-6  0.518
1990 Filippou AC, Völkl C, Grünleitner W, Kiprof P. Base-Induced Alkyne Cleavage in W(II) Complexes -a New Way to Low Valent Carbyne Complexes from W(CO)6 | Basen-induzierte Alkin-Spaltung in W(II)-Komplexen -ein neuer Weg zu niedervalenten Carbin-Komplexen aus W(CO)6 Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 45: 351-368. DOI: 10.1515/Znb-1990-0310  0.496
1990 Filippou AC, Grünleitner W. Reduktive CC-kupplung von zwei isocyanid-liganden an Mo(II)- und W(II)-zentren, eine reaktionssequenz über isocyanid- und aminocarbin-komplexe von Mo(0) und W(0) Journal of Organometallic Chemistry. 393: C10-C16. DOI: 10.1016/0022-328X(90)87211-U  0.468
1990 Filippou AC, Grünleitner W. Homoleptic alkylisocyanide complexes of molybdenum(O) and tungsten(O), useful precursors for the synthesis of low-valent dialkylaminocarbyne complexes Journal of Organometallic Chemistry. 398: 99-115. DOI: 10.1016/0022-328X(90)87008-2  0.462
1990 Filippou AC, Fischer EO. Übergangsmetall-carbin-komplexe XCVII. Carbonylhaltige und carbonylfreie diethylaminocarbin-komplexe von wolfram in einer höheren oxidationszahl mit trimethylphosphit- und isonitril-liganden Journal of Organometallic Chemistry. 382: 143-156. DOI: 10.1016/0022-328X(90)85223-L  0.521
1990 Filippou AC, Fischer EO. Übergangsmetall-carbin-komplexe XCVII. Carbonylhaltige und carbonylfreie diethylaminocarbin-komplexe von wolfram in einer höheren oxidationszahl mit trimethylphosphit- und isonitril-liganden Journal of Organometallic Chemistry. 382: 143-156. DOI: 10.1016/0022-328X(90)85223-L  0.521
1990 Filippou AC, Fischer EO. Übergangsmetal-Carbin-Komplexe. XCVI. Erste carbonylfreie, neutrale und kationische Phenylcarbin-Komplex von Wolfram mit Isonitril-Liganden Journal of Organometallic Chemistry. 383: 179-190. DOI: 10.1016/0022-328X(90)85130-Q  0.465
1990 Filippou AC, Fischer EO. Übergangsmetal-Carbin-Komplexe. XCVI. Erste carbonylfreie, neutrale und kationische Phenylcarbin-Komplex von Wolfram mit Isonitril-Liganden Journal of Organometallic Chemistry. 383: 179-190. DOI: 10.1016/0022-328X(90)85130-Q  0.465
1990 Filippou AC, Fischer EO, Grünleitner W. Übergangsmetall-carbin-komplexe XCVIII. N-Alkylierung eines ethylisocyanid-liganden am molybdän(0); Synthese und oxidationsreaktionen erster cyclopentadienyl-substituierter molybdän-diethylaminocarbin-komplexe Journal of Organometallic Chemistry. 386: 333-347. DOI: 10.1016/0022-328X(90)80006-L  0.603
1990 FILIPPOU AC, FISCHER EO, GRUENLEITNER W. ChemInform Abstract: Transition-Metal Carbyne Complexes. Part 98. N-Alkylation of an Ethylisocyanide Ligand at Molybdenum(0); Synthesis and Oxidation Reactions of the First Cyclopentadienyl-Substituted Molybdenum Diethylaminocarbyne Complexes. Cheminform. 21. DOI: 10.1002/CHIN.199029227  0.508
1990 FILIPPOU AC, VOELKL C, GRUENLEITNER W, KIPROF P. ChemInform Abstract: Base-Induced Alkyne Cleavage in W(II) Complexes - A New Way to Low-Valent Carbyne Complexes from W(CO)6. Cheminform. 21. DOI: 10.1002/CHIN.199026273  0.319
1990 FILIPPOU AC, FISCHER EO. ChemInform Abstract: Transition-Metal Carbyne Complexes. Part 96. First Carbonyl-Free, Neutral and Cationic Phenylcarbyne Complexes of Tungsten with Isonitrile Ligands. Cheminform. 21. DOI: 10.1002/CHIN.199020254  0.494
1990 Filippou AC, Völkl C, Grünleitner W, Kiprof P. Alkyne Cleavage as a Novel Route to Low‐Valent Carbyne‐Metal Complexes Angewandte Chemie. 29: 207-209. DOI: 10.1002/Anie.199002071  0.416
1989 Filippou AC, Gränleitner W. A New Route to Cyclopentadienyl-Substituted Diethylaminocarbyne Complexes of Tungsten | Ein neuer Weg zu cyclopentadienyl-substituierten Diethylaminocarbin-Komplexen des Wolframs Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 44: 1572-1580. DOI: 10.1515/Znb-1989-1217  0.446
1989 Filippou AC, Gränleitner W. Proton-Induced Coupling of one tert-Butylisonitrile with one Phenylcarbyne Ligand at Tungsten | Proton-induzierte Kopplung eines tert-Butylisonitrilmit einem Phenylcarbin-Liganden am Wolfram Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 44: 1023-1034. DOI: 10.1515/Znb-1989-0906  0.307
1989 Filippou AC, Grünleitner W. Isonitrile Substituted Half Sandwich Complexes of Wolfram(IV) | Isonnitril-substituierte Halbsandwich-Komplexe von Wolfram(IV) Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 44: 666-672. DOI: 10.1515/Znb-1989-0609  0.437
1989 Filippou AC, Fischer EO. ÜbergangsmetallCarbin-Komplexe. XCV. Auf dem Weg zu den ersten, carbonylfreien, neutralen und kationischen Diethylaminocarbon-Komplexen des Wolframs Journal of Organometallic Chemistry. 365: 317-323. DOI: 10.1016/0022-328X(89)87030-5  0.542
1989 Filippou AC, Grünleitner W. Ein neuer weg zu polyisonitril-substituierten halbsandwhich-komplexen des zweiwertigen molybdäns und wolframs Journal of Organometallic Chemistry. 378: 387-399. DOI: 10.1016/0022-328X(89)85365-3  0.407
1989 Filippou AC, Grünleitner W, Herdtweck E. Cyclopentadienyl-substituierte isonitril-komplexe des vierwertigen molybdäns; synthese und struktur Journal of Organometallic Chemistry. 373: 325-342. DOI: 10.1016/0022-328X(89)85062-4  0.482
1988 Filippou AC, Fischer EO, Alt HG. Transition Metal Carbyne Complexes, XC [1] Synthesis of New, Seven Coordinated, Cationic Tungsten Carbyne Complexes in a Higher Oxidation State | Übergangsmetall-Carbin-Komplexe, XC [1] Synthese neuer, siebenfach-koordinierter, kationischer Carbin-Komplexe des Wolframs in einer höheren Oxidationszahl Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 43: 654-657. DOI: 10.1515/Znb-1988-0603  0.538
1988 Filippou AC, Fischer EO, Okuda J. ÜbergangsmetallCarbin-Komplexe. LXXXVI. Synthese mono-, bis-, und tris-Trimethylphosphan-substituierter Diethylaminocarbin-Komplexe des Wolframs Journal of Organometallic Chemistry. 339: 309-321. DOI: 10.1016/S0022-328X(00)99392-6  0.642
1988 Filippou AC, Herdtweck E, Alt HG. Neue einkernige Triphenylstannyl-substituierte Carben-Komplexe des Kobalts Journal of Organometallic Chemistry. 355: 437-447. DOI: 10.1016/0022-328X(88)89043-0  0.446
1988 Alt HG, Engelhardt HE, Filippou AC. Acetylen als Baustein für Carben- und Vinylidenliganden am Chrom Journal of Organometallic Chemistry. 355: 139-148. DOI: 10.1016/0022-328X(88)89017-X  0.442
1988 Filippou AC, Otto Fischer E. Übergangsmetall-Carbin-Komplexe. XCII. Synthese Pentamethylcyclopentadienyl-substituierter Diethylaminocarbin-Komplexe des Wolframs in niedriger und mittlerer Oxidationszahl Journal of Organometallic Chemistry. 349: 367-374. DOI: 10.1016/0022-328X(88)87029-3  0.403
1988 Filippou AC, Fischer EO. :Ubergangsmetall-carbin-komplexe. XCIV. Reaktionen substituierter diethylaminocarbin-komplexe des wolframs mit elektrophilen Journal of Organometallic Chemistry. 352: 149-155. DOI: 10.1016/0022-328X(88)83029-8  0.556
1988 Filippou AC, Fischer EO. Übergangsmetallcarbin-komplexe. XCIII. Thermodynamisches gleichgewicht zwischen einem neutralen und einem kationischen isonitril-substituierten diethylaminocarbin-komplex des wolframs Journal of Organometallic Chemistry. 352: 141-148. DOI: 10.1016/0022-328X(88)83028-6  0.543
1988 Filippou AC, Otto Fischer E, Alt HG. Übergangsmetall-Carbin-Komplexe. LXXXIX. Ein neuer Weg zu kationischen Carbin-Komplexen durch reduktive Eliminierung zweier Halogen-Liganden aus neutralen Diethylaminocarbin-Komplexen des Wolframs in einer hohen Oxidationszahl mit PMe3 Journal of Organometallic Chemistry. 344: 215-225. DOI: 10.1016/0022-328X(88)80480-7  0.387
1988 Filippou AC, Fischer EO, Paciello R. Übergangsmetall-carbin-komplexe. XCI. Synthese isonitril-substituierter, neutraler und kationaischer diethylaminocarbin-komplexe des wolframs in niedriger und mittlerer oxidationszahl Journal of Organometallic Chemistry. 347: 127-136. DOI: 10.1016/0022-328X(88)80277-8  0.564
1987 Filippou AC, Fischer EO, Müller G, Alt HG. Übergangsmetall-Carben-Komplexe. CXXXX. Einkernige Triphenylstannyl-substituierte Carben-Komplexe des Rheniums Journal of Organometallic Chemistry. 329: 223-239. DOI: 10.1016/S0022-328X(00)99796-1  0.581
1987 Filippou AC, Fischer EO, Alt HG, Thewalt U. Übergangsmetallcarbin-komplexe. LXXXV. Strukturuntersuchungen der reaktionsprodukte von trans-Br(CO)2L2LCNEt2 (L2 = 2,2′-bipyridyl, 1,10-phenanthrolin) mit den organylanionen [(CO)5MEPh2]- (M = Cr, Mo, W; E = P, As, Sb) Journal of Organometallic Chemistry. 326: 59-81. DOI: 10.1016/0022-328X(87)80123-7  0.551
1987 FILIPPOU AC, FISCHER EO, ALT HG, THEWALT U. ChemInform Abstract: Transition Metal Carbyne Complexes. Part 85. Investigations on the Structure of the Products Obtained from the Reaction of trans-Br(CO)2L2WCNEt2 (L2 = 2,2′-Bipyridyl, 1,10-Phenanthroline) with the Organyl Anions ((CO)5MEPh2)- (M = Cr, Cheminform. 18. DOI: 10.1002/CHIN.198750283  0.501
1986 Filippou AC, Fischer EO, Öfele K, Alt HG. Übergangsmetall-carbin-komplexe. LXXXI. trans-Ph2As(CO)2(2,2′-bipy)WCNEt2 (2,2′-bipy = 2,2′-bipyridyl), der erste, neutrale diphenylarsano-carbinokomplex eines übergangsmetalls Journal of Organometallic Chemistry. 308: 11-17. DOI: 10.1016/S0022-328X(00)99516-0  0.561
1986 Filippou AC, Fischer EO, Alt HG. Übergangsmetall-carbin-komplexe. LXXXIII. Neue anionische mer-dihalogeno-tricarbonyl-dialkylamino-carbin-komplexe des wolframs Journal of Organometallic Chemistry. 310: 357-366. DOI: 10.1016/0022-328X(86)80198-X  0.603
1986 Filippou AC, Fischer EO, Alt HG. Uebergangsmetall-carbin-komplexe. LXXXII. [HCN(C6H5)CH2CH2N(C6H5]+[Br2(CO)3WCN(c-C6H11)2]-, darstellung eines neuen anionischen carbin-komplexes des wolframs durch umsetzung eines neutralen carbin-komplexes mit einem elektronenreichen olefin Journal of Organometallic Chemistry. 303: C13-C16. DOI: 10.1016/0022-328X(86)80123-1  0.514
1985 Fischer EO, Filippou AC, Alt HG. Übergangsmetall-carbin-komplexe. LXXIX. Darstellung und dynamisches verhalten von cis- cyanodiethylaminocarbin-komplexen des wolframs mit den zweizähnigen liganden 2,2′-bipyridyl und 1,10- phenanthrolin Journal of Organometallic Chemistry. 296: 69-82. DOI: 10.1016/0022-328X(85)80339-9  0.54
1985 FISCHER EO, FILIPPOU AC, ALT HG, THEWALT U. ChemInform Abstract: TRANSITION METAL-CARBYNE COMPLEXES. PART 78. PREPARATION OF (ET2N-CW(CO)2(μ-PPH2)2MO(CO)4)-, THE FIRST ANIONIC CARBYNEMETAL COMPLEX; ADDITION OF CARBON DIOXIDE TO THE TUNGSTEN-CARBON TRIPLE BOND Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198528303  0.479
1985 Fischer EO, Filippou AC, Alt HG, Thewalt U. Synthesis of [Et2N?C?W(CO)2(?-PPh2)2Mo(CO)4]?, the First Anionic Carbynemetal Complex; Addition of CO2 to the W?C Bond Angewandte Chemie International Edition in English. 24: 203-205. DOI: 10.1002/Anie.198502031  0.564
1985 Fischer EO, Filippou AC, Alt HG, Thewalt U. Darstellung von [Et2NCW(CO)2(μ-PPh2)2Mo(CO)4]⊖, des ersten anionischen Carbinmetall-Komplexes; Addition von CO2 an die WC-Bindung Angewandte Chemie. 97: 215-217. DOI: 10.1002/Ange.19850970314  0.539
1984 Fischer EO, Filippou AC, Alt HG. Übergangsmetall-carbin-komplexe. LXXVI. Neue anionische η2-keten-komplexe des wolframs Journal of Organometallic Chemistry. 276: 377-385. DOI: 10.1016/0022-328X(84)80659-2  0.575
1983 Filippou A, Fischer EO. Transition Metal Carbyne Complexes, LXXIV [1] Synthesis of Thermostable Neutral Carbyne Carbonyl Complexes of Chromium, Molybdenum, and Tungsten with the Bidentate Ligands 2, 2′-Bipyridyl and 1, 10-Phenanthroline | Übergangsmetall-Carbin-Komplexe, LXXTV [1] Synthese thermisch stabiler neutraler Carbin-Carbonyl-Komplexe von Chrom, Molybdan und Wolfram mit den zweizahnigen Liganden 2.2′-Bipyridyl und 1.10-Phenanthrolin Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 38: 587-591. DOI: 10.1515/Znb-1983-0511  0.576
1983 Fischer EO, Filippou AC, Alt HG, Ackermann K. [(C6H5)3P]2 N+ [(ophen)(CO)(CN)2W({A figure is presented})]- (ophen = 1,10-Phenanthrolin), der erste anionische keten-komplex eines übergangsmetalls Journal of Organometallic Chemistry. 254: C21-C23. DOI: 10.1016/0022-328X(83)85131-6  0.559
Show low-probability matches.