Ryan E. Cowley, Ph.D. - Publications

School of Arts and Sciences University of Rochester, Rochester, NY 
transition-metal complexes

25 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Bhadra M, Lee JYC, Cowley RE, Kim S, Siegler MA, Solomon EI, Karlin KD. Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. Journal of the American Chemical Society. PMID 29957998 DOI: 10.1021/Jacs.8B04671  0.458
2018 Bonyhady SJ, DeRosha DE, Vela J, Vinyard DJ, Cowley RE, Mercado BQ, Brennessel WW, Holland PL. Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation. Inorganic Chemistry. PMID 29741884 DOI: 10.1021/Acs.Inorgchem.8B00468  0.762
2017 Garcia-Bosch I, Cowley RE, Díaz DE, Peterson RL, Solomon EI, Karlin KD. Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2Cu(II)2(O2(2-)) Species to Form L2Cu(III)2(O)2 Cores with Enhanced Oxidative Reactivity. Journal of the American Chemical Society. PMID 28195739 DOI: 10.1021/Jacs.6B12990  0.326
2016 Cowley RE, Tian L, Solomon EI. Mechanism of O2 activation and substrate hydroxylation in noncoupled binuclear copper monooxygenases. Proceedings of the National Academy of Sciences of the United States of America. 113: 12035-12040. PMID 27790986 DOI: 10.1073/Pnas.1614807113  0.382
2016 Cowley RE, Cirera J, Qayyum MF, Rokhsana D, Hedman B, Hodgson KO, Dooley DM, Solomon EI. Structure of the Reduced Copper Active Site in Pre-Processed Galactose Oxidase: Ligand Tuning for One-Electron O2 Activation in Cofactor Biogenesis. Journal of the American Chemical Society. PMID 27626829 DOI: 10.1021/Jacs.6B05792  0.319
2016 Tian S, Liu J, Cowley RE, Hosseinzadeh P, Marshall NM, Yu Y, Robinson H, Nilges MJ, Blackburn NJ, Solomon EI, Lu Y. Reversible S-nitrosylation in an engineered azurin. Nature Chemistry. 8: 670-7. PMID 27325093 DOI: 10.1038/Nchem.2489  0.356
2016 Garcia-Bosch I, Cowley RE, Díaz DE, Siegler MA, Nam W, Solomon EI, Karlin KD. Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2 O2 Core with Unexpected Structure and Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26919169 DOI: 10.1002/Chem.201600551  0.39
2015 Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society. 137: 2796-9. PMID 25697226 DOI: 10.1021/Ja511504N  0.42
2013 Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society. 135: 16454-67. PMID 24164682 DOI: 10.1021/Ja4065377  0.43
2013 Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorganic Chemistry. 52: 12872-4. PMID 24164429 DOI: 10.1021/Ic402357U  0.421
2013 Cowley RE, Golder MR, Eckert NA, Al-Afyouni MH, Holland PL. Mechanism of catalytic nitrene transfer using Iron(I)-isocyanide complexes Organometallics. 32: 5289-5298. DOI: 10.1021/Om400379P  0.803
2012 Dugan TR, Bill E, MacLeod KC, Christian GJ, Cowley RE, Brennessel WW, Ye S, Neese F, Holland PL. Reversible C-C bond formation between redox-active pyridine ligands in iron complexes. Journal of the American Chemical Society. 134: 20352-64. PMID 23181620 DOI: 10.1021/Ja305679M  0.805
2012 Cowley RE, Holland PL. Ligand effects on hydrogen atom transfer from hydrocarbons to three-coordinate iron imides. Inorganic Chemistry. 51: 8352-61. PMID 22800175 DOI: 10.1021/Ic300870Y  0.739
2012 Edelbach BL, Pharoah BM, Bellows SM, Thayer PR, Fennie CN, Cowley RE, Holland PL. An expedient synthesis of 2,4,6-tris(trifluoromethyl)aniline Synthesis (Germany). 44: 3595-3597. DOI: 10.1055/S-0032-1316809  0.564
2012 Cowley RE, Christian GJ, Brennessel WW, Neese F, Holland PL. A reduced (β-diketiminato)iron complex with end-on and side-on nitriles: Strong backbonding or ligand non-innocence? European Journal of Inorganic Chemistry. 479-483. DOI: 10.1002/Ejic.201100787  0.736
2011 Cowley RE, Eckert NA, Vaddadi S, Figg TM, Cundari TR, Holland PL. Selectivity and mechanism of hydrogen atom transfer by an isolable imidoiron(III) complex. Journal of the American Chemical Society. 133: 9796-811. PMID 21563763 DOI: 10.1021/Ja2005303  0.804
2011 Dible BR, Cowley RE, Holland PL. Remote substitution on N-heterocyclic carbenes heightens the catalytic reactivity of their palladium complexes Organometallics. 30: 5123-5132. DOI: 10.1021/Om200349Y  0.636
2011 Cowley RE, Holland PL. C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product Inorganica Chimica Acta. 369: 40-44. DOI: 10.1016/J.Ica.2010.11.031  0.674
2010 Cowley RE, DeYonker NJ, Eckert NA, Cundari TR, DeBeer S, Bill E, Ottenwaelder X, Flaschenriem C, Holland PL. Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation. Inorganic Chemistry. 49: 6172-87. PMID 20524625 DOI: 10.1021/Ic100846B  0.816
2009 Cowley RE, Bill E, Neese F, Brennessel WW, Holland PL. Iron(II) complexes with redox-active tetrazene (RNNNNR) ligands. Inorganic Chemistry. 48: 4828-36. PMID 19397284 DOI: 10.1021/Ic900001Y  0.753
2009 Cowley RE, Eckert NA, Elhaïk J, Holland PL. Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates. Chemical Communications (Cambridge, England). 1760-2. PMID 19294287 DOI: 10.1039/B820620A  0.783
2008 Yu Y, Sadique AR, Smith JM, Dugan TR, Cowley RE, Brennessel WW, Flaschenriem CJ, Bill E, Cundari TR, Holland PL. The reactivity patterns of low-coordinate iron-hydride complexes. Journal of the American Chemical Society. 130: 6624-38. PMID 18444648 DOI: 10.1021/Ja710669W  0.792
2008 Cowley RE, Elhaïk J, Eckert NA, Brennessel WW, Bill E, Holland PL. A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides. Journal of the American Chemical Society. 130: 6074-5. PMID 18419120 DOI: 10.1021/Ja801375G  0.777
2007 Cowley RE, Bontchev RP, Sorrell J, Sarracino O, Feng Y, Wang H, Smith JM. Formation of a cobalt(III) imido from a cobalt(II) amido complex. Evidence for proton-coupled electron transfer. Journal of the American Chemical Society. 129: 2424-5. PMID 17288417 DOI: 10.1021/Ja066899N  0.633
2006 Cowley RE, Bontchev RP, Duesler EN, Smith JM. Removing the sting from the tail: reversible protonation of scorpionate ligands in cobalt(II) tris(carbene)borate complexes. Inorganic Chemistry. 45: 9771-9. PMID 17112274 DOI: 10.1021/Ic061299A  0.694
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