Russell P. Hughes - Publications

Affiliations: 
Chemistry Dartmouth College, Hanover, NH, United States 
Area:
Organometallic mechanism and synthesis, CF bond activation, catalysis, computational chemistry
Website:
http://www.dartmouth.edu/~chem/faculty/rph.html

247 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Zhou DY, Miura-Akagi PM, McCarty SM, Guiles CH, O'Donnell TJ, Yoshida WY, Krause CE, Rheingold AL, Hughes RP, Cain MF. P-Alkynyl functionalized benzazaphospholes as transmetalating agents. Dalton Transactions (Cambridge, England : 2003). PMID 33403375 DOI: 10.1039/d0dt01367f  1
2020 Zimmerman A, Xu R, Reynolds SC, Shipp C, Marshall D, Wang G, Blank NF, Gibbons S, Hughes RP, Glueck DS, Balaich GJ, Rheingold AL. Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles. The Journal of Organic Chemistry. PMID 32627554 DOI: 10.1021/acs.joc.0c00974  1
2020 Shreiber ST, Kaplan PT, Hughes RP, Vasiliu M, Dixon DA, Cramer RE, Vicic DA. Syntheses, solution behavior, and computational bond length analyses of trifluoromethyl and perfluoroethyl cuprate salts Journal of Fluorine Chemistry. 234: 109518. DOI: 10.1016/j.jfluchem.2020.109518  0.01
2019 Nakashige ML, Loristo JIP, Wong LS, Gurr JR, O'Donnell TJ, Yoshida WY, Rheingold AL, Hughes RP, Cain MF. -Selective Synthesis and Coordination Chemistry of Pyridine-Phosphaalkenes: Five Ligands Produce Four Distinct Types of Ru(II) Complexes. Organometallics. 38: 3338-3348. PMID 33299263 DOI: 10.1021/acs.organomet.9b00425  1
2019 Landis CR, Hughes RP, Weinhold F. Comment on "Observation of alkaline earth complexes M(CO) (M = Ca, Sr, or Ba) that mimic transition metals". Science (New York, N.Y.). 365. PMID 31395757 DOI: 10.1126/science.aay2355  1
2019 Gibbons SK, D Valleau CR, Peltier JL, Cain MF, Hughes RP, Glueck DS, Golen JA, Rheingold AL. Diastereoselective Coordination of P-Stereogenic Secondary Phosphines in Copper(I) Chiral Bis(phosphine) Complexes: Structure, Dynamics, and Generation of Phosphido Complexes. Inorganic Chemistry. 58: 8854-8865. PMID 31247872 DOI: 10.1021/acs.inorgchem.9b01263  1
2019 Jiang X, Cui X, Duncan AJE, Li L, Hughes RP, Staples RJ, Alexandrov EV, Proserpio DM, Wu Y, Ke C. Topochemical Synthesis of Single-Crystalline Hydrogen-Bonded Cross-Linked Organic Frameworks and Their Guest-Induced Elastic Expansion. Journal of the American Chemical Society. PMID 31246447 DOI: 10.1021/jacs.9b05232  0.36
2019 Nakashige ML, Loristo JIP, Wong LS, Gurr JR, O’Donnell TJ, Yoshida WY, Rheingold AL, Hughes RP, Cain MF. E-Selective Synthesis and Coordination Chemistry of Pyridine-Phosphaalkenes: Five Ligands Produce Four Distinct Types of Ru(II) Complexes Organometallics. 38: 3338-3348. DOI: 10.1021/acs.organomet.9b00425  0.01
2019 Hughes RP, Lemal DM. Competing (4+2) and (2+2) cycloaddition reactions of tetrafluorothiophene-S,S-dioxide with phenylacetylene: A computational study Journal of Fluorine Chemistry. 221: 42-47. DOI: 10.1016/j.jfluchem.2019.03.006  0.01
2018 Li Q, Qian H, Shao B, Hughes RP, Aprahamian I. Building Strain with Large Macrocycles and using it to Tune the Thermal Half-Lives of Hydrazone Photochromes. Journal of the American Chemical Society. PMID 30133273 DOI: 10.1021/jacs.8b07612  1
2018 Muldoon J, Varga B, Deegan M, Chapp T, Eordogh A, Hughes R, Glueck DS, Moore C, Rheingold A. Inversion of Configuration at the Phosphorus Nucleophile in Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides. Angewandte Chemie (International Ed. in English). PMID 29484790 DOI: 10.1002/anie.201801427  1
2018 Kim WS, Du K, Eastman A, Hughes RP, Micalizio GC. Synthetic nat- or ent-steroids in as few as five chemical steps from epichlorohydrin. Nature Chemistry. 10: 70-77. PMID 29256503 DOI: 10.1038/nchem.2865  0.08
2018 Kremláček V, Hyvl J, Yoshida WY, Růžička A, Rheingold AL, Turek J, Hughes RP, Dostál L, Cain MF. Heterocycles Derived from Generating Monovalent Pnictogens within NCN Pincers and Bidentate NC Chelates: Hypervalency versus Bell-Clappers versus Static Aromatics Organometallics. 37: 2481-2490. DOI: 10.1021/acs.organomet.8b00290  0.01
2018 Gibbons SK, Xu Z, Hughes RP, Glueck DS, Rheingold AL. Chiral Bis(Phospholane) PCP Pincer Complexes: Synthesis, Structure, and Nickel-Catalyzed Asymmetric Phosphine Alkylation Organometallics. 37: 2159-2166. DOI: 10.1021/acs.organomet.8b00284  0.01
2018 Deegan MM, Muldoon JA, Hughes RP, Glueck DS, Rheingold AL. Synthesis and Structure of Metal Complexes of P-Stereogenic Chiral Phosphiranes: An EDA-NOCV Analysis of the Donor–Acceptor Properties of Phosphirane Ligands Organometallics. 37: 1473-1482. DOI: 10.1021/acs.organomet.8b00123  0.01
2017 Gibbons SK, Hughes RP, Glueck DS, Royappa AT, Rheingold AL, Arthur RB, Nicholas AD, Patterson HH. Synthesis, Structure, and Luminescence of Copper(I) Halide Complexes of Chiral Bis(phosphines). Inorganic Chemistry. PMID 29064687 DOI: 10.1021/acs.inorgchem.7b01562  1
2017 Pell CJ, Zhu Y, Huacuja R, Herbert DE, Hughes RP, Ozerov OV. Fluorocarbene, fluoroolefin, and fluorocarbyne complexes of Rh. Chemical Science. 8: 3178-3186. PMID 28507693 DOI: 10.1039/c6sc05391b  0.04
2017 Giffin KA, Pua LA, Piotrkowski S, Gabidullin BM, Korobkov I, Hughes RP, Baker RT. Generation of Hydrofluoronickelacycles from Trifluoroethylene and Ni(0): Ligand Effects on Regio-/Stereoselectivity and Reactivity. Journal of the American Chemical Society. PMID 28287263 DOI: 10.1021/jacs.6b12607  1
2017 Lee GM, Leung ASC, Harrison DJ, Korobkov I, Hughes RP, Baker RT. Experimental and Computational Evidence for 1,4-Diradical Intermediates in Reactions of Cobalt Fluorocarbene Complexes with Terminal Aryl-alkynes to give Metallacyclobutenes Organometallics. 36: 2853-2860. DOI: 10.1021/acs.organomet.7b00344  0.01
2017 Gansle KM, Gash AE, Chambliss CK, Clapsaddle BJ, Newell BS, Miller SM, Anderson OP, Hughes RP, Strauss SH. X-ray structures and electronic properties of the 1,1′,2,2′- and 1,1′,3,3′-tetra-t-butylferrocenium(1+) cations Polyhedron. 121: 88-94. DOI: 10.1016/j.poly.2016.09.027  0.01
2016 Hyvl J, Yoshida WY, Rheingold AL, Hughes RP, Cain MF. A Masked Phosphinidene Trapped in a Fluxional NCN Pincer. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27654835 DOI: 10.1002/chem.201604415  1
2016 Lisi GP, Hughes RP, Wilcox DE. Coordination contributions to protein stability in metal-substituted carbonic anhydrase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27350155 DOI: 10.1007/s00775-016-1375-6  0.01
2016 Miura-Akagi PM, Nakashige ML, Maile CK, Oshiro SM, Gurr JR, Yoshida WY, Royappa AT, Krause CE, Rheingold AL, Hughes RP, Cain MF. Synthesis of a Tris(phosphaalkene)phosphine Ligand and Fundamental Organometallic Reactions on Its Sterically Shielded Metal Complexes Organometallics. 35: 2224-2231. DOI: 10.1021/acs.organomet.6b00250  0.01
2016 Magnuson KW, Oshiro SM, Gurr JR, Yoshida WY, Gembicky M, Rheingold AL, Hughes RP, Cain MF. Streamlined Preparation and Coordination Chemistry of Hybrid Phosphine-Phosphaalkene Ligands Organometallics. 35: 855-859. DOI: 10.1021/acs.organomet.6b00101  1
2016 MacInnis MC, DeMott JC, Zolnhofer EM, Zhou J, Meyer K, Hughes RP, Ozerov OV. Cationic Two-Coordinate Complexes of Pd(I) and Pt(I) Have Longer Metal-Ligand Bonds Than Their Neutral Counterparts Chem. 1: 902-920. DOI: 10.1016/j.chempr.2016.11.007  0.01
2015 DiPoto MC, Hughes RP, Wu J. Dearomative Indole (3+2) Reactions with Azaoxyallyl Cations - New Method for the Synthesis of Pyrroloindolines. Journal of the American Chemical Society. PMID 26562355 DOI: 10.1021/jacs.5b10221  1
2015 Yuan J, Bourgeois CJ, Rheingold AL, Hughes RP. Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond. Dalton Transactions (Cambridge, England : 2003). PMID 26211437 DOI: 10.1039/c5dt02275d  1
2015 Yuan J, Hughes RP, Rheingold AL. A (pentafluoroethyl)(trifluoromethyl)carbene complex of iridium and reductive activation of its sp(3) α, β, and γ carbon-fluorine bonds to give perfluoro-2-butyne, perfluoro-1,2,3-butatriene and perfluoro-1-irida-2-methyl-2-cyclobutene) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 26158776 DOI: 10.1039/c5dt02075a  1
2015 Fuller JT, Harrison DJ, Leclerc MC, Baker RT, Ess DH, Hughes RP. A New Stepwise Mechanism for Formation of a Metallacyclobutane via a Singlet Diradical Intermediate Organometallics. 34: 5210-5213. DOI: 10.1021/acs.organomet.5b00863  1
2015 Landis CR, Hughes RP, Weinhold F. Bonding Analysis of TM(cAAC)2 (TM = Cu, Ag, and Au) and the Importance of Reference State Organometallics. 34: 3442-3449. DOI: 10.1021/acs.organomet.5b00429  1
2015 Braun T, Hughes RP. Organometallic Fluorine Chemistry Organometallic Fluorine Chemistry. 1-243. DOI: 10.1007/978-3-319-22096-3  1
2014 Yang Y, Hughes RP, Aprahamian I. Near-infrared light activated azo-BF2 switches. Journal of the American Chemical Society. 136: 13190-3. PMID 25222380 DOI: 10.1021/ja508125n  1
2014 Li H, Hughes RP, Wu J. Dearomative indole (3 + 2) cycloaddition reactions. Journal of the American Chemical Society. 136: 6288-96. PMID 24739089 DOI: 10.1021/ja412435b  1
2013 Lopchuk JM, Hughes RP, Gribble GW. What controls regiochemistry in 1,3-dipolar cycloadditions of münchnones with nitrostyrenes? Organic Letters. 15: 5218-21. PMID 24073889 DOI: 10.1021/ol402385v  1
2013 Su X, Voskian S, Hughes RP, Aprahamian I. Manipulating liquid-crystal properties using a pH activated hydrazone switch. Angewandte Chemie (International Ed. in English). 52: 10734-9. PMID 24038673 DOI: 10.1002/anie.201305514  1
2013 Robbins TF, Qian H, Su X, Hughes RP, Aprahamian I. Cyanide detection using a triazolopyridinium salt. Organic Letters. 15: 2386-9. PMID 23627279 DOI: 10.1021/ol4008298  1
2012 Han X, Li H, Hughes RP, Wu J. Gallium(III)-catalyzed three-component (4+3) cycloaddition reactions. Angewandte Chemie (International Ed. in English). 51: 10390-3. PMID 22969063 DOI: 10.1002/anie.201205238  1
2012 Yang Y, Hughes RP, Aprahamian I. Visible light switching of a BF2-coordinated azo compound. Journal of the American Chemical Society. 134: 15221-4. PMID 22954379 DOI: 10.1021/ja306030d  1
2012 Ray D, Foy JT, Hughes RP, Aprahamian I. A switching cascade of hydrazone-based rotary switches through coordination-coupled proton relays. Nature Chemistry. 4: 757-62. PMID 22914198 DOI: 10.1038/nchem.1408  1
2012 Reynolds SC, Hughes RP, Glueck DS, Rheingold AL. Synthesis, reactivity, and resolution of a C2-symmetric, P-stereogenic benzodiphosphetane, a building block for chiral bis(phosphines). Organic Letters. 14: 4238-41. PMID 22870878 DOI: 10.1021/ol301935q  1
2012 Taw FL, Clark AE, Mueller AH, Janicke MT, Cantat T, Scott BL, Hay PJ, Hughes RP, Kiplinger JL. Titanium(IV) trifluoromethyl complexes: New perspectives on bonding from organometallic fluorocarbon chemistry Organometallics. 31: 1484-1499. DOI: 10.1021/om201055e  1
2011 Huang H, Hughes RP, Rheingold AL. Synthesis and structural characterization of group 6 transition metal complexes with terminal fluoromethylidyne (CF) ligands; a DFT/NBO/NRT comparison of bonding characteristics of terminal NO, CF and CH ligands. Dalton Transactions (Cambridge, England : 2003). 40: 47-55. PMID 21082118 DOI: 10.1039/c0dt01006e  1
2011 Wilson EE, Oliver AG, Hughes RP, Ashfeld BL. Synthesis of phosphine-ligated zinc acetylide dimers: Enhanced reactivity in carbonyl additions Organometallics. 30: 5214-5221. DOI: 10.1021/om200581f  1
2011 Yuan J, Hughes RP, Rheingold AL. Unexpected synthesis of a perfluoroacyl complex, Cp*Ir(CO)(COC 6F 11)Br, by direct fluoroalkylation of a CO ligand, and elimination of perfluorocyclohexene by activation of a γ-C-F bond Organometallics. 30: 1744-1746. DOI: 10.1021/om200019d  1
2010 Cain MF, Hughes RP, Glueck DS, Golen JA, Moore CE, Rheingold AL. Synthesis and structure of intermediates in copper-catalyzed alkylation of diphenylphosphine. Inorganic Chemistry. 49: 7650-62. PMID 20617815 DOI: 10.1021/ic100816u  1
2010 Lane EM, Chapp TW, Hughes RP, Glueck DS, Feland BC, Bernard GM, Wasylishen RE, Rheingold AL. Synthesis of gold phosphido complexes derived from bis(secondary) phosphines. structure of tetrameric [Au(MesP(CH(2))(3)PMes)Au](4). Inorganic Chemistry. 49: 3950-7. PMID 20232831 DOI: 10.1021/ic100219j  1
2010 Huang H, Rheingold AL, Hughes RP. Synthesis and X-ray structure of a diamagnetic oxo-bridged trifluoromethyl-chromium(V) complex: Structural and computational comparisons between CF3 and CH3 ligands in two different oxidation states of chromium Organometallics. 29: 3672-3675. DOI: 10.1021/om100543t  1
2010 Huang H, Hughes RP, Rheingold AL. Synthesis and structural characterization of new perfluoroacyl and perfluoroalkyl group 6 transition metal compounds Organometallics. 29: 1948-1955. DOI: 10.1021/om1001183  1
2010 Yuan J, Hughes RP, Golen JA, Rheingold AL. Synthesis and structural and computational studies of a conformationally locked (η1-Perfluoroalkylidene)(η2-alkene) transition metal complex: Ir(Cp*)(CFCF3)(C2H 4) Organometallics. 29: 1942-1947. DOI: 10.1021/om1000343  1
2010 Hughes RP. Fluorine as a ligand substituent in organometallic chemistry: A second chance and a second research career Journal of Fluorine Chemistry. 131: 1059-1070. DOI: 10.1016/j.jfluchem.2010.06.014  1
2010 Yuan J, Hughes RP, Rheingold AL. Synthesis and crystallographic characterization of dimeric perfluoroalkyl iridium complexes: [Cp*Ir(X)(RF)]2 (X = I, R F = CF3, CF2CF3, CF 2CF2CF3, CF(CF3)2, CF(CF3)(CF2CF3); X = Cl and Br, RF = CF2CF3) Inorganica Chimica Acta. 364: 96-101. DOI: 10.1016/j.ica.2010.06.006  1
2010 CURNOW OJ, HUGHES RP. ChemInform Abstract: (Ru(η5-C5Me5)(η5-C5F5)) (IV): The First Transition-Metal Complex Containing a Perfluorocyclopentadienyl Ligand. Cheminform. 23: no-no. DOI: 10.1002/chin.199244263  0.01
2009 Huang H, Hurubeanu NR, Bourgeois CJ, Cheah SM, Yuan J, Rheingold AL, Hughes RP. Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)2 Canadian Journal of Chemistry. 87: 151-160. DOI: 10.1139/V08-114  1
2009 Yuan J, Hughes RP, Rheingold AL. A monomeric perfluoroalkyl iridium(III) amido complex with an Ir=N double bond and its reactions to activate sp 3 carbon - Hydrogen bonds at room temperature Organometallics. 28: 4646-4648. DOI: 10.1021/om900657f  1
2009 Hui H, Rheingold AL, Hughes RP. Serendipitous discovery of a simple compound with an unsupported Ir - Ir bond Organometallics. 28: 1575-1578. DOI: 10.1021/om801110x  1
2009 Pet MA, Cain MF, Hughes RP, Glueck DS, Golen JA, Rheingold AL. Synthesis and structure of ferrocenylmethylphosphines, their borane adducts, and some related derivatives Journal of Organometallic Chemistry. 694: 2279-2289. DOI: 10.1016/j.jorganchem.2009.03.015  1
2009 Hughes RP. Conversion of carbon-fluorine bonds a to transition metal centers to carbon-hydrogen, carbon-carbon, and carbon-heteroatom bonds European Journal of Inorganic Chemistry. 4591-4606. DOI: 10.1002/ejic.200900816  1
2008 Huang H, Hughes RP, Rheingold AL. Synthesis and structural characterization of a coordinatively unsaturated ruthenium complex, Cp*Ru(Ph2nacnac), and its CO adduct Polyhedron. 27: 734-738. DOI: 10.1016/j.poly.2007.11.002  1
2007 Leontyeva L, Hughes RP, Rheingold AL. An unusual migratory insertion of CO into a pentamethylcyclopentadienyl- platinum bond Organometallics. 26: 5735-5736. DOI: 10.1021/om700777p  1
2007 Bourgeois CJ, Huang H, Larichev RB, Zakharov LN, Rheingold AL, Hughes RP. Variable-temperature NMR determination of the barriers to rotation about the Ir-C σ-bond in a series of primary perfluoroalkyl iridium complexes [IrCp*{(CF2)nCF3}(PMe3) 2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OT f] Organometallics. 26: 264-271. DOI: 10.1021/om060822q  1
2007 Yuan J, Hughes RP, Rheingold AL. The first example of a bis(trifluoromethyl)carbene transition-metal complex and its reduction to a perfluoroallene complex European Journal of Inorganic Chemistry. 4723-4725. DOI: 10.1002/ejic.200700814  1
2006 Huang H, Hughes RP, Landis CR, Rheingold AL. The simplest binary fluorocarbon as a ligand. Synthetic, spectroscopic, crystallographic, and computational studies of a molybdenum complex of terminally ligated carbon monofluoride (fluoromethylidyne). Journal of the American Chemical Society. 128: 7454-5. PMID 16756295 DOI: 10.1021/ja062510k  1
2006 Hughes RP, Larichev RB, Zakharov LN, Rheingold AL. Carbon-fluorine bond activation coupled with alkynyl migration to give fluorinated allenyl complexes of iridium Organometallics. 25: 3943-3947. DOI: 10.1021/om0602916  1
2006 Bourgeois CJ, Garratt SA, Hughes RP, Larichev RB, Smith JM, Ward AJ, Willemsen S, Zhang D, DiPasquale AG, Zakharov LN, Rheingold AL. Synthesis and structural characterization of (perfluoroalkyl) fluoroiridium(III) and (perfluoroalkyl)methyliridium(III) compounds Organometallics. 25: 3474-3480. DOI: 10.1021/om060267s  1
2006 Bourgeois CJ, Hughes RP, Yuan J, DiPasquale AG, Rheingold AL. α- and β-fluorine elimination reactions induced by reduction of iridium - Fluoroalkyl complexes. Selective formation of fluoroalkylidene and hydrofluoroalkene ligands Organometallics. 25: 2908-2910. DOI: 10.1021/om060243l  1
2006 Hughes RP. Rhodium Comprehensive Organometallic Chemistry. 5: 277-540. DOI: 10.1016/B978-008046518-0.00064-7  1
2005 Garratt SA, Hughes RP, Kovacik I, Ward AJ, Willemsen S, Zhang D. Carbon-fluorine bond activation coupled with carbon-hydrogen bond formation alpha to iridium: kinetics, mechanism, and diastereoselectivity. Journal of the American Chemical Society. 127: 15585-94. PMID 16262424 DOI: 10.1021/ja0545012  1
2005 Hughes RP, Laritchev RB, Yuan J, Golen JA, Rucker AN, Rheingold AL. A simple route to difluorocarbene and perfluoroalkylidene complexes of iridium. Journal of the American Chemical Society. 127: 15020-1. PMID 16248629 DOI: 10.1021/ja055166k  1
2005 Hughes RP, Laritchev RB, Zakharov LN, Rheingold AL. Carbon-fluorine bond activation coupled with carbon-carbon bond formation at iridium. Confirmation of complete kinetic diastereoselectivity at the new carbon stereocenter by intramolecular trapping using vinyl as the migrating group. Journal of the American Chemical Society. 127: 6325-34. PMID 15853339 DOI: 10.1021/ja042345d  1
2005 Bourgeois CJ, Hughes RP, Husebo TL, Smith JM, Guzei IM, Liable-Sands LM, Zakharov LN, Rheingold AL. Reactions of perfluoroalkyl iodides with M(C 5H 5)(CO)(PMe 3) [M = Rh, Ir]; evidence for direct fluoroalkylation at a CO ligand Organometallics. 24: 6431-6439. DOI: 10.1021/om050714o  1
2005 Hughes RP, Laritchev RB, Zakharov LN, Rheingold AL. Unexpected formation of an organoplatinum(IV) fluoride complex in the reaction of Pt(TMEDA)(CH 3) 2 with perfluoro-sec-butyl Iodide Organometallics. 24: 4845-4848. DOI: 10.1021/om0504654  1
2004 Hughes RP, Ward AJ, Golen JA, Incarvito CD, Rheingold AL, Zakharov LN. Synthesis, molecular structures, and chemistry of some new palladium(II) and platinum(II) complexes with pentafluorophenyl ligands. Dalton Transactions (Cambridge, England : 2003). 2720-7. PMID 15514757 DOI: 10.1039/B406602B  1
2004 Hughes RP, Zhang D, Ward AJ, Zakharov LN, Rheingold AL. Conformational analysis and assignments of relative stereocenter configurations in fluoroalkyl-iridium complexes using 19F[1H] HOESY experiments. Comparison with solid-state X-ray structural results. Journal of the American Chemical Society. 126: 6169-78. PMID 15137782 DOI: 10.1021/ja049225q  1
2004 Hughes RP, Laritchev RB, Zakharov LN, Rheingold AL. Reductive activation of carbon-fluorine bonds in perfluoroalkyl ligands: an unexpected route to the only known tetrafluorobutatriene transition metal complex: Ir(eta 5-C5Me5)(PMe3)(2,3-eta 2 -CF2[double bond]C[double bond]C[double bond]CF2). Journal of the American Chemical Society. 126: 2308-9. PMID 14982426 DOI: 10.1021/ja031598o  1
2004 Hughes RP, Meyer MA, Tawa MD, Ward AJ, Williamson A, Rheingold AL, Zakharov LN. Does alpha-fluorination affect the structural trans-influence and kinetic trans-effect of an alkyl ligand? Molecular structures of Pd(TMEDA)(CH(3))(R(F)) and a kinetic study of the trans to cis isomerization of Pt(TMEDA)(CH(3))(2)I(R(F)) [R(F) = CF(2)CF(3), CFHCF(3), CH(2)CF(3)]. Inorganic Chemistry. 43: 747-56. PMID 14731039 DOI: 10.1021/ic030251j  1
2003 Hughes RP, Ward AJ, Rheingold AL, Zakharov LN. Synthesis and molecular structures of platinum(II) and platinum(IV) diimine complexes possessing fluoroalkyl ligands Canadian Journal of Chemistry. 81: 1270-1279. DOI: 10.1139/v03-117  1
2003 Hughes RP, Laritchev RB, Williamson A, Incarvito CD, Zakharov LN, Rheingold AL. Reactions of iridium and rhodium complexes containing η2-benzyne, η2-tetrafluorobenzyne, and η2-trifluorobenzyne ligands. Differential rates of arene elimination by protonation of isomeric fluoroaryl complexes and restricted rotation of PMe3 ligands in ortho-iodo and ortho-bromoaryl complexes Organometallics. 22: 2134-2141. DOI: 10.1021/om030048w  1
2002 Hughes RP, Zhang D, Zakharov LN, Rheingold AL. Selective protonation at a C-F bond in the presence of an iridium-methyl bond gives diastereoselective carbon-fluorine bond activation and carbon-carbon bond formation. A new path to carbon stereocenters bearing fluorine atoms Organometallics. 21: 4902-4904. DOI: 10.1021/om020718i  1
2002 Johnston BF, Rankin DWH, Robertson HE, Hughes RP, Lomprey JR. Molecular structure of Ru(η-C5Me5)(η-C5F5) by gas-phase electron diffraction and density functional theory Organometallics. 21: 4840-4846. DOI: 10.1021/om0205501  1
2002 Hughes RP, Laritchev RB, Williamson A, Incarvito CD, Zakharov LN, Rheingold AL. Iridium and rhodium complexes containing fluorinated phenyl ligands and their transformation to η2-Benzyne complexes, including the parent benzyne complex IrCp*(PMe3)(C6H4) Organometallics. 21: 4873-4885. DOI: 10.1021/om0204787  1
2002 Hughes RP, Willemsen S, Williamson A, Zhang D. Carbon-fluorine bond hydrogenolysis in perfluoroethyl-iridium complexes to give HFC-134a involves heterolytic activation of H2 Organometallics. 21: 3085-3087. DOI: 10.1021/om020225d  1
2002 Hughes RP, Smith JM, Incarvito CD, Lam KC, Rhatigan B, Rheingold AL. Cationic iridium-perfluoroalkyl complexes with NH3 and PH3 ligands. Activation of carbon-fluorine bonds by H2S to give bis(trifluoromethyl)dithiametallacyclobutane and bis(trifluoromethyl)trithiametallacyclohexane complexes Organometallics. 21: 2136-2144. DOI: 10.1021/om0200407  1
2002 Hughes RP, Husebo TL, Maddock SM, Liable-Sands LM, Rheingold AL. Reactions of Perfluoroisopropyl Iodide with Cyclopentadienyl−Rhodium Complexes in Methanol. An Unexpected Route to a Rhodium−Fulvalene Complex. Organometallics. 21: 1004-1004. DOI: 10.1021/om011050v  0.01
2002 Hughes RP, Overby JS, Lam KC, Incarvito CD, Rheingold AL. Oxidative addition reaction of perfluoro-n-butyl iodide to (COD)PtMe2 to give (COD)PtMe(nC4F 9). The molecular structure of (COD)PtMe2 Polyhedron. 21: 2357-2360.  1
2002 Bowden AA, Hughes RP, Lindner DC, Incarvito CD, Liable-Sands LM, Rheingold AL. Synthesis and structural studies of perfluoroalkyl-rhodium and iridium(III) compounds containing tris(pyrazolyl)borate ligands Journal of the Chemical Society, Dalton Transactions. 3245-3252.  1
2001 Hughes RP, Williamson A, Sommer RD, Rheingold AL. The first transition metal complex of tetrafluorobenzyne: Ir(eta(5)-C(5)Me(5))(PMe(3))(eta(2)-C(6)F(4)). Journal of the American Chemical Society. 123: 7443-4. PMID 11472184 DOI: 10.1021/ja010992o  1
2001 Hughes RP, Maddock SM, Guzei IA, Liable-Sands LM, Rheingold AL. Reactions of halofluorocarbons with group 6 complexes M(C(5)H(5))(2)L (M = Mo, W; L = C(2)H(4), CO). Fluoroalkylation at molybdenum and tungsten, and at cyclopentadienyl or ethylene ligands. Journal of the American Chemical Society. 123: 3279-88. PMID 11457063 DOI: 10.1021/ja003339u  1
2001 Hughes RP, Williamson A, Incarvito CD, Rheingold AL. Synthesis and molecular structure of a perfluoroalkyl complex of platinum containing a PCP pincer ligand Organometallics. 20: 4741-4744. DOI: 10.1021/om010569o  1
2001 Hughes RP, Sweetser JT, Tawa MD, Williamson A, Incarvito CD, Rhatigan B, Rheingold AL, Rossi G. Synthesis and molecular structures of perfluoro-n-alkyl complexes of platinum(II) and platinum(IV) containing tetramethylethylenediamine (TMEDA) or 1,2-bis(diphenylphosphino)ethane (DPPE) ligands Organometallics. 20: 3800-3810. DOI: 10.1021/om010424h  1
2001 Hughes RP, Kovacik I, Lindner DC, Smith JM, Willemsen S, Zhang D, Guzei IA, Rheingold AL. Unusual reactivity of "Proton Sponge" as a hydride donor to transition metals: Synthesis and structural characterization of fluoroalkyl(hydrido) complexes of iridium(III) and rhodium(III) Organometallics. 20: 3190-3197. DOI: 10.1021/om0102347  1
2001 Hughes RP, Lindner DC, Smith JM, Zhang D, Incarvito CD, Lam KC, Liable-Sands LM, Sommer RD, Rheingold AL. Water, water, everywhere. Synthesis and structures of perfluoroalkyl rhodium and iridium(III) compounds containing water ligands Journal of the Chemical Society, Dalton Transactions. 2270-2278.  1
2001 Hughes RP, Lindner DC, Liable-Sands LM, Rheingold AL. Conversion of perfluorobenzyl complexes of rhodium to fluorinated oxarhodacycles Organometallics. 20: 363-366.  1
2000 Hughes RP, Smith JM, Liable-Sands LM, Concolino TE, Lam KC, Incarvito C, Rheingold AL. Syntheses and crystallographic studies of [Ir(η5-C5Me5)(L)(RF)I] (L = CO, PMe3; RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes. Cone and solid angle steric parameters for perfluoroalkyl ligands Journal of the Chemical Society, Dalton Transactions. 873-879. DOI: 10.1039/a907057e  1
2000 Hughes RP, Trujillo HA, Egan JW, Rheingold AL. Iridium-promoted reactions of carbon-carbon bonds. Skeletal rearrangement of a vinylcyclopropene during iridacyclohexadiene formation and subsequent isomerization of iridacyclohexadienes via α,α'-substituent migrations Journal of the American Chemical Society. 122: 2261-2271. DOI: 10.1021/ja992407d  1
2000 Blanchard MD, Hughes RP, Concolino TE, Rheingold AL. π-Stacking between pentafluorophenyl and phenyl groups as a controlling feature of intra- and intermolecular crystal structure motifs in substituted ferrocenes. Observation of unexpected face-to-face stacking between pentafluorophenyl rings Chemistry of Materials. 12: 1604-1610. DOI: 10.1021/cm000093j  1
2000 Hughes RP, Overby JS, Williamson A, Lam KC, Concolino TE, Rheingold AL. Synthesis, molecular structures, and dynamics of primary and secondary fluoroalkyl complexes of palladium(II) with tetramethylethylenediamine (TMEDA) ligands. Evaluation of the structural trans-influences of methyl and fluoroalkyl groups as ligands within the same coordination sphere Organometallics. 19: 5190-5201.  1
1999 Hughes RP, Smith JM. Hydrogenolysis of aliphatic carbon-fluorine bonds in fluoroalkyl- iridium complexes to give hydrofluorocarbons Journal of the American Chemical Society. 121: 6084-6085. DOI: 10.1021/ja990490z  1
1999 Hughes RP, Trujillo HA, Egan JW, Rheingold AL. Skeletal rearrangement during rhodium-promoted ring opening of 1,2-diphenyl-3-vinyl-1-cyclopropene. Preparation and characterization of 1,2- and 2,3-diphenyl-3,4-pentadienediyl rhodium complexes and their ring closure to a 1,2-diphenylcyclopentadienyl complex Organometallics. 18: 2766-2772.  1
1998 Hughes RP, Zheng X, Morse CA, Curnow OJ, Lomprey JR, Rheingold AL, Yap GPA. Syntheses of the Complete Set of Isomerically Pure, Partially Fluorinated Cyclopentadienyl Ligands (C5F5-nHn) [n= 1−4] by Flash Vacuum Thermolysis of (η5-Oxocyclohexadienyl)ruthenium Complexes. Molecular Structures of [Ru(η5-C5Me5)(η5-C5-1,2-F2H3)] and [Ru(η5-C5Me5)(η5-C5H4F)] Organometallics. 17: 457-465. DOI: 10.1021/om970775p  0.01
1998 Hughes RP, Kowalski AS. Flash Vacuum Thermolysis of η5-Oxocyclohexadienyl Complexes of Ruthenium To Give η5-Cyclopentadienyl Ligands Organometallics. 17: 270-273. DOI: 10.1021/om970770s  0.01
1998 Herrera V, de Rege PJ, Horváth IT, Husebo TL, Hughes RP. Tuning the fluorous partition coefficients of organometallic complexes. The synthesis and characterization of [η5-C5H4CH2CH2(CF2)9CF3]Rh(CO)L (L = CO or P[CH2CH2(CF2)5CF3]3) and Cl2Ni{P[CH2CH2(CF2)5CF3]3}2 Inorganic Chemistry Communications. 1: 197-199. DOI: 10.1016/S1387-7003(98)00053-7  0.01
1998 Hughes RP, Maddock SM, Rheingold AL, Guzei IA. Selective conversion of an ethylene to an ethylidene ligand in reactions of a hydrido(ethylene) complex of tantalum with iodofluorocarbons. Molecular structure of [Ta(η5-C5H5)2(η t-CHCH3)I] Polyhedron. 17: 1037-1043.  1
1998 Herrera V, De Rege PJF, Horváth IT, Le Husebo T, Hughes RP. Tuning the fluorous partition coefficients of organometallic complexes. The synthesis and characterization of [η5-C5H4CH2CH 2(CF2)9CF3]Rh(CO)L (L=CO. Inorganic Chemistry Communications. 1: 197-199.  1
1998 Hughes RP, Zheng X, Morse CA, Curnow OJ, Lomprey JR, Rheingold AL, Yap GPA. Syntheses of the complete set of isomerically pure, partially fluorinated cyclopentadienyl ligands (C5F5-nHn) [n = 1-4] by flash vacuum thermolysis of (η5-Oxocyclohexadienyl)ruthenium complexes. Molecular structures of [Ru(η5-C5Me5) (η5-C5-1,2-F2H3)] Organometallics. 17: 457-465.  1
1998 Hughes RP, Trujillo HA. Selective solubility of organometallic complexes in saturated fluorocarbons. Synthesis of cyclopentadienyl ligands with fluorinated ponytails Chemtracts. 11: 141-142.  1
1997 Hughes RP, Lindner DC, Rheingold AL, Yap GP. Synthesis and Structure of the Thallium(I) Salt of the Tetrakis{3,5-bis(trifluoromethyl)phenyl}borate Anion. Inorganic Chemistry. 36: 1726-1727. PMID 11669768  1
1997 Hughes RP, Le Husebo T, Maddock SM. Thallium(I) selectively abstracts fluoride from a tertiary carbon-fluorine bond under conditions where silver(I) selectively abstracts iodide from rhodium Journal of the American Chemical Society. 119: 10231-10232. DOI: 10.1021/ja972398d  1
1997 Hughes RP, Lindner DC. Facile activation of carbon-fluorine bonds in saturated fluoroalkyl ligands by coordinated water in fluoroalkyl aqua complexes of rhodium [6] Journal of the American Chemical Society. 119: 11544-11545. DOI: 10.1021/ja9723388  1
1997 Hughes RP, Maddock SM, Rheingold AL, Liable-Sands LM. Selective Fluoroalkylation of Cyclopentadienyl and Ethylene Ligands in Reactions of Perfluoroalkyl Iodides with Low-Valent Complexes of Molybdenum and Tungsten:  Evidence for a Fluorocarbanion Mechanism Journal of the American Chemical Society. 119: 5988-5989. DOI: 10.1021/ja970452k  0.01
1997 Hughes RP, Le Husebo T, Holliday BJ, Rheingold AL, Liable-Sands LM. Fluoroalkylation of cobalt complexes: Selective reactions at the metal or the cyclopentadienyl ring Journal of Organometallic Chemistry. 548: 109-112.  1
1997 Lichtenberger DL, Elkadi Y, Gruhn NE, Hughes RP, Curnow OJ, Zheng X. Electronic structure perturbations of substituted ruthenocenes: The first photoelectron spectra of perchloro- and perfluorocyclopentadienyl complexes Organometallics. 16: 5209-5217.  1
1997 Richardson DE, Lang L, Eyler JR, Kircus SR, Zheng X, Morse CA, Hughes RP. Additivity of fluorine substituent effects in ruthenocene ionization energetics Organometallics. 16: 149-150.  1
1997 Hughes RP, Le Husebo T, Rheingold AL, Liable-Sands LM, Yap GPA. Ancillary ligand-controlled selectivity for metal or cyclopentadienyl ring fluoroalkylation in reactions of fluoroalkyl iodides with cyclopentadienylrhodium complexes Organometallics. 16: 5-7.  1
1996 Hughes RP, Lindner DC, Rheingold AL, Yap GPA. Perfluorobenzyl complexes of cobalt and rhodium. Unusual coupling between pentafluorophenyl and pentamethylcyclopentadienyl rings Organometallics. 15: 5678-5686.  1
1996 Hughes RP, Lomprey JR, Rheingold AL, Haggerty BS, Yap GPA. Synthesis and molecular structures of titanocene, zirconocene, and uranocene dichlorides containing 1,2-di-tert-butylcyclopentadienyl ligands Journal of Organometallic Chemistry. 517: 89-99.  1
1996 Hughes RP, Lomprey JR, Rheingold AL, Yap GPA. Molybdenum and tungsten complexes containing the 1,2-di-tert-butylcyclopentadienyl ligand Journal of Organometallic Chemistry. 517: 63-70.  1
1996 Hughes RP, Kowalski AS, Lomprey JR, Neithamer DR. A new synthesis of 1,5-di-tert-butyl-1,3-cyclopentadiene by dehydration of an epoxide and characterization of its Diels-Alder dimer Journal of Organic Chemistry. 61: 401-404.  1
1995 Hughes RP, Rose PR, Zheng X, Rheingold AL. Synthesis and Molecular Structure of the First Example of an .eta.4-Complex of Hexafluorobutadiene: [RuCl(.eta.5-C5Me5)(.eta.4-C4F6)]. Structural Comparison of Coordinated Butadiene and Its Perfluorinated Analog Organometallics. 14: 2407-2414. DOI: 10.1021/om00005a043  0.01
1995 Donovan BT, Hughes RP, Spara PP, Rheingold AL. Unusual chloropalladation of 1,2,3-tri-tert-butyl-3-vinyl-1-cyclopropene to give an η3-(chloromethyl)cyclobutenyl ligand. Crystal and molecular structures of Di-μ-chlorobis-[(1-3η)-4-endo-(chloromethyl)-1,2,3-tri-tert- butylcyclobutenyl]dipalladium and tetra-μ-chlorobis[(1-3η)-4-endo-(chloromethyl)-1,2,3-tri-tert- butylcyclobutenyl]tripalladium Organometallics. 14: 489-494. DOI: 10.1021/om00001a066  1
1995 Hughes RP, Lomprey JR. Tin and thallium reagents for transfer of the 1,2-di-tert-butylcyclopentadienyl ligand to transition metals Inorganica Chimica Acta. 240: 653-656. DOI: 10.1016/0020-1693(95)04517-1  1
1995 Hughes RP, Trujillo HA, Gauri AJ. Stereoselective ring expansion of 3-vinyl-1-cyclopropenes to give (η5-cyclopentadienyl)ruthenium and (η4-cyclohexadienone)iron complexes. Exclusion of planar metallacyclohexadiene intermediates and relevance to the Dötz reaction Organometallics. 14: 4319-4324.  1
1995 Hughes RP, Rose PR, Zheng X, Rheingold AL. Synthesis and molecular structure of the first example of an η4-complex of hexafluorobutadiene: [RuCl(η5-C5Me5)(η4-C 4F6)]. Structural comparison of coordinated butadiene and its perfluorinated analogue Organometallics. 14: 2407-2414.  1
1994 Hughes RP, Zheng X, Ostrander RL, Rheingold AL. Synthesis and Molecular Structure of [Ru(.eta.5-C5H5)(.eta.5-C5F5)]. Intramolecular Structural Comparison of the Cyclopentadienyl Ligand with its Perfluorinated Analog Organometallics. 13: 1567-1568. DOI: 10.1021/om00017a011  0.01
1994 Hughes RP, Kowalski AS, Donovan BT. Unusual rhodium promoted reaction of a vinylcyclopropene to give a cyclobutadiene ligand. Formation of (η5-pentamethylcyclopentadienyl)- [η4-tri-t-butyl(methyl) cyclobutadiene]rhodium Journal of Organometallic Chemistry. 472: c18-c20. DOI: 10.1016/0022-328X(94)80231-9  1
1994 Hughes RP, Tucker DS, Rheingold AL. Reversible insertion of iridium into a cyclopropenyl carbon-carbon bond Organometallics. 13: 4664-4666.  1
1994 Hughes RP, Zheng X, Ostrander RL, Rheingold AL. Synthesis and molecular structure of [Ru(η5-C5H5)(η5-C 5F5)]. Intramolecular structural comparison of the cyclopentadienyl ligand with its perfluorinated analogue Organometallics. 13: 1567-1568.  1
1994 Hughes RP, Kowalski AS, Lomprey JR, Rheingold AL. Preparation of the 1,2-di-tert-butylcyclopentadienyl anion and a transition metal derivative. Crystal structure of 1,1′,2,2′-tetra-tert-butylferrocene Organometallics. 13: 2691-2695.  1
1993 Hughes RP, Tucker DS. .eta.3-Cyclopropenyl is isolobal with nitrosyl, but not with .eta.3-propenyl (allyl): evidence from conformational preferences and rotational barriers in alkene and alkyne complexes of iridium Organometallics. 12: 4736-4738. DOI: 10.1021/om00036a009  0.01
1993 Ditchfield R, Hughes RP, Tucker DS, Bierwagen EP, Robbins J, Robinson DJ, Zakutansky JA. Synthesis and dynamic NMR studies of .eta.3-triphenyl- and .eta.3-trimethylcyclopropenyl complexes of ruthenium, [Ru(.eta.5-C5R5)(.eta.3-C3R'3)X2] (R = H, Me; R' = Me, Ph; X = Cl, Br, I). Extended Hueckel molecular orbital study of barriers to rotation of .eta.3-cyclopropenyl ligands in isoelectronic ruthenium and molybdenum complexes Organometallics. 12: 2258-2267. DOI: 10.1021/om00030a041  0.01
1993 Donovan BT, Hughes RP, Kowalski AS, Trujillo HA, Rheingold AL. Stereoselective rhodium-promoted ring closure of an .eta.4-1,3-pentadienediyl ligand to an .eta.4-1,3-cyclopentadiene, with subsequent regiospecific endo-H migration: molecular structure of [Rh(.eta.5-C5H5)(1-4-.eta.)-C5H3-1,2-exo-5-Bu-tert3)] Organometallics. 12: 1038-1043. DOI: 10.1021/om00028a018  0.01
1993 Richardson DE, Ryan MF, Geiger WE, Chin TT, Hughes RP, Curnow OJ. Gas-phase and solution studies of the oxidation of the first perfluorocyclopentadienyl complex, [Ru(.eta.5-C5Me5)(.eta.5-C5F5)] Organometallics. 12: 613-615. DOI: 10.1021/om00027a007  0.01
1993 Hughes RP, Trujillo HA, Rheingold AL. .alpha.-Carbon-hydrogen and .alpha.'-carbon-carbon bond cleavage in an iridacyclohexadiene. Interchange of .alpha.-hydrogen and .alpha.'-phenyl substituents without accompanying skeletal rearrangement Journal of the American Chemical Society. 115: 1583-1585. DOI: 10.1021/ja00057a058  0.01
1993 Lichtenberger DL, Hoppe ML, Subramanian L, Kober EM, Hughes RP, Hubbard JL, Tucker DS. Electron distribution and bonding in η3-cyclopropenyl-metal complexes Organometallics. 12: 2025-2031.  1
1993 Ditchfield R, Hughes RP, Tucker DS, Bierwagen EP, Robbins J, Robinson DJ, Zakutansky JA. Synthesis and dynamic NMR studies of η3-triphenyl- and η3-trimethylcyclopropenyl complexes of ruthenium, [Ru(η5-C5R5)(η3-C 3R′3)X2] (R = H, Me; R′ = Me, Ph; X = Cl, Br, I). Extended Huckel molecular orbital study of barriers to rotation of η .. Organometallics. 12: 2258-2267.  1
1993 Donovan BT, Hughes RP, Kowalski AS, Trujillo HA, Rheingold AL. Stereoselective rhodium-promoted ring closure of an η4-1,3-pentadienediyl ligand to an η4-1,3-cyclopentadiene, with subsequent regiospecific endo-H migration: Molecular structure of [Rh(η5-C5H5)((1-4-η)-C 5H3-1,2,exo-5-tBu3)] Organometallics. 12: 1038-1043.  1
1993 Hughes RP, Tucker DS. η3-Cyclopropenyl is isolobal with NO, but not with η3-propenyl (allyl): Evidence from conformational preferences and rotational barriers in alkene and alkyne complexes of iridium Organometallics. 12: 4736-4738.  1
1993 Shen JK, Tucker DS, Basolo F, Hughes RP. Kinetics of CO substitution in reactions of η3-cyclopropenyl complexes of iron, cobalt, rhodium, and iridium with phosphorus ligands. first examples of a dissociative mechanism for CO substitution in the cobalt triad carbonyl complexes Journal of the American Chemical Society. 115: 11312-11318.  1
1993 Hughes RP, Tucker DS, Rheingold AL. Preparation and dynamic behavior of η3-cyclopropenyl complexes of cobalt, rhodium, and iridium. Crystal and molecular structure of [Ir(η3-C3 tBu3)(CO)3] Organometallics. 12: 3069-3074.  1
1993 Richardson DE, Ryan MF, Geiger WE, Chin TT, Hughes RP, Curnow OJ. Gas-phase and solution studies of the oxidation of the first perfluorocyclopentadienyl complex, [Ru(η5-C5Me5)(η5-C 5F5)] Organometallics. 12: 613-615.  1
1993 Hughes RP, Trujillo HA, Rheingold AL. α-C-H and α′-C-C bond cleavage in an iridacyclohexadiene. interchange of α-hydrogen and α′-phenyl substituents without accompanying skeletal rearrangement Journal of the American Chemical Society. 115: 1583-1585.  1
1993 Curnow OJ, Hughes RP, Mairs EN, Rheingold AL. Facile propeller rotation in metallacyclopropanes. Synthesis and dynamic behavior of new tetrafluoroethylene-ruthenium complexes. Crystal and molecular structure of [Ru(η5-C5Me5)Cl(η2-C 2F4)]2 Organometallics. 12: 3102-3108.  1
1993 Hughes RP, Rose PR, Rheingold AL. Transition-metal chemistry of hexafluorobutadiene. Facile hydrolysis of (hexafluoro-1-metalla-3-cyclopentene)rhodium complexes to give tetrafluoro-1-metalla-3-cyclopenten-2-one and tetrafluoro-1-metalla-2-cyclopenten-4-one complexes. Crystal and molecular structures of trans-[(Rh-CF2CF=CF-CO)Cl(PPh3)2], mer-[(Rh-CF2 .. Organometallics. 12: 3109-3117.  1
1992 Curnow OJ, Hughes RP. [Ru(.eta.5-C5Me5)(.eta.5-C5F5)]: the first transition-metal complex containing a perfluorocyclopentadienyl ligand Journal of the American Chemical Society. 114: 5895-5897. DOI: 10.1021/ja00040a083  0.01
1992 Curnow OJ, Hughes RP. [Ru(η5-C5Me5)(η5-C 5F5)]: The first transition-metal complex containing a perfluorocyclopentadienyl ligand Journal of the American Chemical Society. 114: 5895-5897.  1
1992 Curnow OJ, Hughes RP, Rheingold AL. An (η2-tetrafluoroethylene)ruthenium complex with a metallacyclopropane structure but with a low barrier to propellor rotation Journal of the American Chemical Society. 114: 3153-3155.  1
1992 Donovan BT, Hughes RP, Trujillo HA, Rheingold AL. Steric congestion in a cyclopentadienyl ligand bearing tert-butyl groups on three contiguous carbon atoms: Crystal and molecular structure of (η5-1,2,3-Tri-tert-butylcyclopentadienyl)(η 5-indenyl)rhodium(III) hexafluorophosphate Organometallics. 11: 64-69.  1
1990 Carl RT, Corcoran EW, Hughes RP, Samkoff DE. Nickel, palladium, and platinum complexes derived from octafluorocyclooctatetraene. Synthesis of 1-2:5-6-.eta.-octafluorocyclooctatetraene complexes of nickel(0) and .eta.2-octafluorobicyclo[3.3.0]octa-2,7-diene-4,6-diyl complexes of nickel(II), palladium(II), and platinum(II) Organometallics. 9: 838-844. DOI: 10.1021/om00117a046  0.01
1990 Hughes RP. Organo-Transition Metal Compounds Containing Perfluorinated Ligands Advances in Organometallic Chemistry. 31: 183-267. DOI: 10.1016/S0065-3055(08)60511-0  1
1990 Donovan BT, Egan JW, Hughes RP, Spara PP, Trujillo HA, Rheingold AL. Reversible Carbon-Carbon Bond Cleavage of a 3-Vinyl-1-Cyclopropene by Rh(I). Molecular Structures of Two Sterically Crowded 1,2,3,5-η-Pentadienediyl Complexes of Rh(III) Israel Journal of Chemistry. 30: 351-360. DOI: 10.1002/ijch.199000037  0.01
1990 Hughes RP, Doig SJ, Hemond RC, Smith WL, Davis RE, Gadol SM, Holland KD. Synthesis, structures, and conformational dynamics of dicobalt complexes containing the hexafluorodidehydrocyclooctatetraene (hexafluorocycloocta-3,5,7-trien-1-yne) ligand. Crystal and molecular structures of [(Co(L)(CO)2)2(μ2-(1η,2η)-C 8F6)] (L = CO, PPh3, PPhMe2, PMe3) Organometallics. 9: 2745-2753.  1
1990 Hughes RP, Carl RT, Doig SJ, Hemond RC, Samkoff DE, Smith WL, Stewart LC, Davis RE, Holland KD, Dickens P, Kashyap RP. Effect of polyfluorination on ring inversion barriers for cyclooctatetraenes. Synthesis of heptafluorocycloocta-1,3,5,7-tetraenyl, hexafluorocycloocta-1,3,5,7-tetraenediyl, heptafluorotricyclo[4.2.0.02,5]octa-3,7-dienyl, and hexafluorotricyclo[4.2.0.02,5]octa-3,7-dienediyl transition-metal compounds. Crystal and molecular structures of [Fe(η-C .. Organometallics. 9: 2732-2745.  1
1990 Donovan BT, Hughes RP, Trujillo HA. Mechanism of rhodium-promoted conversion of 3-vinyl-1-cyclopropenes to 1,3-cyclopentadienes. Stereochemistry of the carbon-carbon bond-forming step Journal of the American Chemical Society. 112: 7076-7077.  1
1989 Hemond RC, Hughes RP, Rheingold AL. Synthesis of .eta.6-octafluorocyclooctatetraene and .eta.6-cyclooctatetraene complexes of manganese(I). Molecular structures of [Mn(.eta.5-C5R5)(.eta.6-C8X8)] (R = H, Me, X = F; R = Me, X = H) Organometallics. 8: 1261-1269. DOI: 10.1021/om00107a021  0.01
1989 HEMOND RC, HUGHES RP, RHEINGOLD AL. ChemInform Abstract: Synthesis of η6-Octafluorocyclooctatetraene and η6-Cyclooctatetraene Complexes of Manganese(I). Molecular Structures of (Mn(η5-C5R5)(η6-C8X8)) (R: H, Me, X: F; R: Me, X: H). Cheminform. 20. DOI: 10.1002/chin.198934283  0.01
1989 Hughes RP, Robinson DJ. Transition-metal-promoted activation of carbon-carbon bonds. A new synthetic route to substituted ruthenocene derivatives via ring expansion reactions of 3-vinyl-1-cyclopropenes Organometallics. 8: 1015-1019.  1
1989 Hughes RP, King ME, Robinson DJ, Spotts JM. Stereoselective oxidative additions of a carbon-carbon σ-bond in tetrafluorocyclopropene to iridium(I) complexes Journal of the American Chemical Society. 111: 8919-8920.  1
1989 Hemond RC, Hughes RP, Rheingold AL. Synthesis of η6-octafluorocyclooctatetraene and η6-cyclooctatetraene complexes of manganese(I). Molecular structures of [Mn(η5-C5R5)(η6-C 8X8)] (R = H, Me, X = F; R = Me, X = H) Organometallics. 8: 1261-1269.  1
1988 Hemond RC, Hughes RP. The first transition metal complex containing a co-ordinated vinylcyclopropene and its photochemical ring expansion to give an η4-cyclobutadiene ligand Journal of the Chemical Society, Chemical Communications. 319-320. DOI: 10.1039/C39880000319  1
1988 Hughes RP, Robbins J, Robinson DJ, Rheingold AL. Conformationally rigid .eta.3-cyclopropenyl complexes of ruthenium(IV). Crystal and molecular structure of [Ru(.eta.5-C5H5)(.eta.3-C3Ph3)Br2] Organometallics. 7: 2413-2415. DOI: 10.1021/om00101a024  0.01
1988 BelBruno JJ, Greenfield SR, Carl RT, Hughes RP. Competition among collisional deactivation, ionization, and dissociation in the multiphoton excitation of octafluorocyclooctatetraene The Journal of Physical Chemistry. 92: 2480-2484. DOI: 10.1021/j100320a018  0.01
1988 Hemond RC, Hughes RP, Robinson DJ, Rheingold AL. Activation of a fluorinated carbon-carbon bond by oxidative addition of tetrafluorocyclopropene to platinum(0). The first example of a perfluorometallacyclobutene Organometallics. 7: 2239-2241.  1
1988 BelBruno JJ, Greenfield SR, Carl RT, Hughes RP. Competition among collisional deactivation, ionization, and dissociation in the multiphoton excitation of octafluorocyclooctatetraene Journal of Physical Chemistry. 92: 2480-2484.  1
1988 Hughes RP, Bobbins J, Robinson DJ, Rheingold AL. Conformationally rigid η3-cyclopropenyl complexes of ruthenium(IV). Crystal and molecular structure of [Ru(η5-C5H5)(η3-C 3Ph3)Br2] Organometallics. 7: 2413-2415.  1
1988 Carl RT, Hughes RP, Rheingold AL, Marder TB, Taylor NJ. Synthesis, structures, and solution dynamics of mononuclear and dinuclear (η5-indenyl)rhodium complexes of octafluorocyclooctatetraene. Crystal and molecular structures of [Rh(η5-C9H7)(1,2,5,6-η-C 8F8)], {[Rh(η5-C9H7)] 2 .. Organometallics. 7: 1613-1624.  1
1988 Carl RT, Hughes RP, Samkoff DE. Transannular ring-closure reactions of octafluorocyclooctatetraene coordinated to cobalt and rhodium centers. Ligand-induced formation of η2-octafluorocycloocta-2,5,7-triene-1,4-diyl and η2-octafluorobicyclo[3.3.0]octa-2,7-diene-4,6-diyl complexes of cobalt(III) and rhodium(III) Organometallics. 7: 1625-1631.  1
1987 BelBruno JJ, Kobsa PH, Carl RT, Hughes RP. Competition between radiative pumping and nonradiative processes in the multiphoton dissociation of organometallic iron complexes The Journal of Physical Chemistry. 91: 6168-6172. DOI: 10.1021/j100308a022  0.01
1987 Carl RT, Hughes RP, Johnson JA, Davis RE, Kashyap RP. Unprecedented bonding of a coordinated polyenyl ligand. Synthesis and molecular structures of fac-trialkyltricarbonyliron compounds containing the η3-nonafluorocycloocta-2,5-diene-1,4,7-triyl ligand and its derivatives Journal of the American Chemical Society. 109: 6875-6876.  1
1987 Carl RT, Doig SJ, Geiger WE, Hemond RC, Hughes RP, Kelly RS, Samkoff DE. Pentamethylcyclopentadienyl cobalt and rhodium complexes of octafluorocyclooctatetraene. Photochemical and thermal interconversion of 1,2,5,6-μ- and 1,2,3,6-η-C8F8 isomers. Electrochemical and ESR characterization of the 19-electron radical anion [Co(η-C5Me5)(1,2,5,6-η-C8F 8)]- Organometallics. 6: 611-616.  1
1987 Egan JW, Hughes RP, Rheingold AL. Transition-metal-promoted ring-opening reactions of vinylcyclopropenes. 1,2,3,5-η-Penta-2,4-dienediyl and 1,5-η-penta-2,4-dienediyl (1-metallacyclohexa-2,4-diene) complexes of rhodium(III) and iridium(III) and their conversion to (η5-cyclopentadienyl)hydridometal compounds Organometallics. 6: 1578-1581.  1
1987 Belbruno JJ, Kobsa PH, Carl RT, Hughes RP. Competition between radiative pumping and nonradiative processes in the multiphoton dissociation of organometallic iron complexes Journal of Physical Chemistry. 91: 6168-6172.  1
1986 Henry WP, Hughes RP. Organic synthesis using carbon monoxide. Regiospecific cobalt mediated synthesis of 2H-pyran-2-ones. Journal of the American Chemical Society. 108: 7862-4. PMID 22283315 DOI: 10.1021/ja00284a077  1
1986 Hughes RP, Carl RT, Hemond RC, Samkoff DE, Rheingold AL. Unprecedented co-ordination of a cyclo-octatetraene ligand. Synthesis and crystal and molecular structure of (η-pentamethylcyclopentadienyl)(1,4- η-octafluorocyclooctatetraene)(trimethylphosphine)rhodium(III) Journal of the Chemical Society, Chemical Communications. 306-308. DOI: 10.1039/C39860000306  1
1986 Hughes RP, Lambert JMJ, Whitman DW, Hubbard JL, Henry WP, Rheingold AL. Reactions of cyclopropenyl cations with tricarbonylnitrosylferrate(1-), tetracarbonylcobaltate(1-), and octacarbonyldicobalt. Synthesis and conformational and configurational stabilities of η3-cyclopropenyl and η3-oxocyclobutenyl complexes of iron and cobalt. Crystal and molecular structure of Fe(η-C3Ph2-t-Bu)(CO)2(NO) Organometallics. 5: 789-797. DOI: 10.1021/om00135a029  1
1986 Hughes RP. Book Review: Metallo-organic Chemistry Organometallics. 5: 606-606. DOI: 10.1021/om00134a601  0.01
1986 Henry WP, Hughes RP. Organic synthesis using carbon monoxide. Regiospecific cobalt-mediated synthesis of 2H-pyran-2-ones Journal of the American Chemical Society. 108: 7862-7864.  1
1986 Hughes RP, Carl RT, Samkoff DE, Davis RE, Holland KD. Transition-metal chemistry of octafluorocyclooctatetraene. Synthesis and X-ray structure of a novel five-coordinate cis-dialkyl nickel complex Organometallics. 5: 1053-1055.  1
1986 Hughes RP, Lambert JMJ, Hubbard JL. Reactions of (η3-Cyclopropenyl)iron complexes with tertiary phosphorus ligands. Competition between ligand substitution and cyclopropenyl migration to carbon monoxide followed by ring expansion to give oxocyclobutenyl ligands Organometallics. 5: 797-804.  1
1986 Grabowski NA, Hughes RP, Jaynes BS, Rheingold AL. Stepwise transition metal promoted ring expansion reactions of vinylcyclopropenes to give cyclopentadienes and cyclohexa-2,4-dienones. The first example of a 1-metallacyclohexa-2,4-diene complex, {[Pt-CH 2-CH=C(Ph)-C(Ph)=C(Ph)](PPh3)2} Journal of the Chemical Society, Chemical Communications. 1694-1695.  1
1986 Hemond RC, Hughes RP, Locker HB. Competitive C-H and C-C activation in the reaction of pentamethylcyclopentadiene with decacarbonyldimanganese Organometallics. 5: 2391-2392.  1
1985 Hughes RP, Reisch JW, Rheingold AL. Oxidative addition of cyclopropenyl cations to zerovalent molybdenum and tungsten centers. Synthesis of .eta.3-cyclopropenyl and .eta.3-oxocyclobutenyl complexes of molybdenum(II) and tungsten(II). Crystal and molecular structures of [Mo(.eta.5-C5H5)(.eta.3-C3Ph2R)(CO)2] (R = Ph, tert-Bu) Organometallics. 4: 1754-1761. DOI: 10.1021/om00129a012  0.01
1985 Hughes RP, Rheingold AL, Herrmann WA, Hubbard JL. Syntheses of metal carbonyls. XVII. Formation of a heteronuclear organometallic cluster containing ruthenium and rhodium; crystal and molecular structure of {[Rh(η-C5Me5)]3Ru(CO)3](μ3-CO)2} Journal of Organometallic Chemistry. 286: 361-368. DOI: 10.1016/0022-328X(85)80051-6  1
1985 Hughes RP, Kläui W, Reisch JW, Müller A. Reactions of cyclopropenyl cations with group 6 metal carbonyl anions. Synthesis of η3-oxocyclobutenyl complexes of chromium, molybdenum, and tungsten Organometallics. 4: 1761-1766.  1
1985 Doherty NM, Ewels BE, Hughes RP, Samkoff DE, Saunders WD, Davis RE, Laird BB. Cyclopentadienylcobalt and -rhodium complexes containing monocyclic and bicyclic valence isomers of octafluorocyclooctatetraene: Crystal and molecular structures of the exo and endo isomers of (η-cyclopentadienyl)-(2-5-η-octafluorobicyclo[4.2.0]octa-2,4,7-triene) rhodium(I) Organometallics. 4: 1606-1611.  1
1985 Hughes RP, Reisch JW, Rheingold AL. Synthesis and crystal and molecular structure of an η-cyclopropene complex of molybdenum Organometallics. 4: 241-244.  1
1985 Hughes RP, Reisch JW, Rheingold AL. Oxidative addition of cyclopropenyl cations to zerovalent molybdenum and tungsten centers. Synthesis of η3-cyclopropenyl and η3-oxocyclobutenyl complexes of molybdenum(II) and tungsten(II). Crystal and molecular structures of [Mo(η5-C5H5)(η3-C 3Ph2R)(CO)2] (R = Ph, t-Bu) Organometallics. 4: 1754-1761.  1
1985 Hughes RP, Lambert JMJ, Rheingold AL. A novel transition-metal-promoted rearrangement of a cyclopropenyl cation. Synthesis and crystal and molecular structure of a 1-3-η-butadienyl complex of platinum Organometallics. 4: 2055-2057.  1
1984 Hughes RP, Reisch JW, Rheingold AL. A novel synthetic route to cyclobutadiene complexes of molybdenum and tungsten. Crystal and molecular structure of Mo(η-C5H5)(η-C4Ph 3Me)(CO)(Cl) Organometallics. 3: 1761-1763.  1
1984 Dolg SJ, Hughes RP, Davis RE, Gadol SM, Holland KD. Cobalt complexes of hexafluorodehydrocyclooctatetraene: Synthesis and crystal and molecular structures of [Co(CO)3]2(C8F6) and [Co(CO)2(PPh3)]2(C8F6) Organometallics. 3: 1921-1922.  1
1983 Hughes R. Advances in Organometallic Chemistry. Volume 20 Organometallics. 2: 479-479. DOI: 10.1021/om00075a900  0.01
1983 Doig SJ, Hughes RP, Patt SL, Samkoff DE, Smith WL. Octafluorocyclooctatetraene transition metal compounds: displacement of fluoride by metal carbonyl anions Journal of Organometallic Chemistry. 250: c1-c4. DOI: 10.1016/0022-328X(83)85083-9  1
1983 Hughes RP, Samkoff DE, Davis RE, Laird BB. Octafluorocyclooctatetraene transition-metal compounds. Novel transannular ring closures and a formal intramolecular redox equilibrium between 1,2,5,6-η and 1,2,3,6-η ligands Organometallics. 2: 195-197.  1
1982 Hughes RP, Lambert JMJ, Reisch JW, Smith WL. Reinvestigations of some reactions of metal carbonyl anions with cyclopropenium cations. Conversion of .eta.3-cyclopropenyl to .eta.3-cyclobutenonyl ligands Organometallics. 1: 1403-1405. DOI: 10.1021/om00070a027  0.01
1982 Hughes RP, Day CS. Steric blocking of .eta.3 .fwdarw. .eta.1 .fwdarw. .eta.3 isomerizations of an .eta.3-allylic ligand. Crystal and molecular structures of 1,3-chloropalladation products of cis-9-methylenebicyclo[6.1.0]nonane and cis-7-methylenebicyclo[4.1.0]heptane Organometallics. 1: 1221-1225. DOI: 10.1021/om00069a021  0.01
1982 Donaldson WA, Hughes RP, Davis RE, Gadol SM. Syntheses of cationic and zwitterionic cyclobutadiene compounds of cobalt(I). Crystal and molecular structure of tricarbonyl(.eta.-1-methoxy-3-methyl-2-phenylcyclobutadiene)cobalt(1+) hexafluorophosphate Organometallics. 1: 812-819. DOI: 10.1021/om00066a009  0.01
1982 Boland-Lussier BE, Churchill MR, Hughes RP, Rheingold AL. Synthesis and characterization of cationic iron vinylidene compounds: formation of carbon-hydrogen, carbon-nitrogen and carbon-phosphorus bonds and the x-ray crystal structure of [Fe(.eta.-C5H5)(CO)(PPh3) {C(PPh3):CH2}]+BF4- Organometallics. 1: 628-634. DOI: 10.1021/om00064a010  0.01
1982 Albright TA, Clemens PR, Hughes RP, Hunton DE, Margerum LD. Chloropalladation of alkyl-substituted methylenecyclopropanes Journal of the American Chemical Society. 104: 5369-5379. DOI: 10.1021/ja00384a021  0.01
1982 Donaldson WA, Hughes RP. Mechanism of formation of (.eta.3-oxocyclobutenyl)cobalt compounds from [Co(CO)4]- and cyclopropenium cations Journal of the American Chemical Society. 104: 4846-4859. DOI: 10.1021/ja00382a019  0.01
1982 DeSimone DM, Desrosiers PJ, Hughes RP. 2-Cyclopropene-1-carbonyl compounds of rhenium, manganese, and iron. A facile route to nonfluxional 3-.eta.1-cyclopropenyl compounds of rhenium Journal of the American Chemical Society. 104: 4842-4846. DOI: 10.1021/ja00382a018  0.01
1982 Hughes RP, McGrady ND, Samkoff DE. Transition metal chemistry of octafluorocyclooctatetraene Journal of Fluorine Chemistry. 21: 20. DOI: 10.1016/S0022-1139(00)85351-8  0.01
1982 DONALDSON WA, HUGHES RP. ChemInform Abstract: MECHANISM OF FORMATION OF (η3-OXOCYCLOBUTENYL)COBALT COMPOUNDS FROM (CO(CO)4)- AND CYCLOPROPENIUM CATIONS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198249288  0.01
1982 DESIMONE DM, DESROSIERS PJ, HUGHES RP. ChemInform Abstract: 2-CYCLOPROPENE-1-CARBONYL COMPOUNDS OF RHENIUM, MANGANESE, AND IRON. A FACILE ROUTE TO NONFLUXIONAL 3-η1-CYCLOPROPENYL COMPOUNDS OF RHENIUM Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198249283  0.01
1982 DONALDSON WA, HUGHES RP. ChemInform Abstract: A CONVENIENT SYNTHESIS OF 2-ALKYL-3-DEUTERO-2-CYCLOPROPENE-1-CARBOXYLIC ACIDS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198235149  0.01
1982 BOLAND-LUSSIER BE, HUGHES RP. ChemInform Abstract: REACTIONS OF THE CATIONIC IRON VINYLIDENE COMPOUNDS (FE(η-C5H5)(CO)(PPH3)(C:CH2))+ BF4- WITH OXYGEN-HYDROGEN, NITROGEN-HYDROGEN, SULFUR-HYDROGEN, AND CHLORINE-HYDROGEN BONDS AND CARBON-CARBON TRIPLE BONDS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198229256  0.01
1982 BOLAND-LUSSIER BE, CHURCHILL MR, HUGHES RP, RHEINGOLD AL. ChemInform Abstract: SYNTHESIS AND CHARACTERIZATION OF CATIONIC IRON VINYLIDENE COMPOUNDS: FORMATION OF CARBON-HYDROGEN, CARBON-NITROGEN AND CARBON-PHOSPHORUS BONDS AND THE X-RAY CRYSTAL STRUCTURE OF (FE(η-C5H5)(CO)(PPH3) (C(PPH3):CH2))+BF4- Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198229255  0.01
1982 Hughes RP. Reinvestigations of some reactions of metal carbonyl anions with cyclopropenium cations. conversion of η3-cyclopropenyl to η3-oxoeyclobulenyl ligands Organometallics. 1: 1403-1405.  1
1981 Donaldson WA, Hughes RP. A Convenient Synthesis of 2-Alkyl-3-Deutero-2-Cyclopropene-1-Carboxylic Acids Synthetic Communications. 11: 999-1004. DOI: 10.1080/00397918108065761  0.01
1981 Clemens PR, Hughes RP, Margerum LD. Stereochemical features of the 1,3-chloropalladation of bicyclic methylenecyclopropanes Journal of the American Chemical Society. 103: 2428-2430. DOI: 10.1021/ja00399a058  0.01
1981 Barefoot AC, Corcoran EW, Hughes RP, Lemal DM, Saunders WD, Laird BB, Davis RE. Octafluorocyclooctatetraene transition-metal chemistry: 1,2-.eta. and 1,2,3,6-.eta. complexes of iron and platinum Journal of the American Chemical Society. 103: 970-972. DOI: 10.1021/ja00394a057  0.01
1981 Donaldson WA, Hughes RP. The direct measurement of in a coordinated cyclobutadiene ligand Journal of Magnetic Resonance (1969). 43: 170-172. DOI: 10.1016/0022-2364(81)90092-5  0.01
1981 BAREFOOT ACI, CORCORAN EWJ, HUGHES RP, LEMAL DM, SAUNDERS WD, LAIRD BB, DAVIS RE. ChemInform Abstract: OCTAFLUOROCYCLOOCTATETRAENE TRANSITION-METAL CHEMISTRY: 1,2-η AND 1,2,3,6-η COMPLEXES OF IRON AND PLATINUM Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198122323  0.01
1980 Dallas BK, Hughes RP. The chloropalladation of 2,2-diphenylmethylenecyclopropanes Journal of Organometallic Chemistry. 184: C67-C69. DOI: 10.1016/S0022-328X(00)93775-6  0.01
1979 Chidsey CE, Donaldson WA, Hughes RP, Sherwin PF. Interactions of small organic rings with transition metals. Formation of .eta.3-cyclobutenonyl complexes by the ring expansion of 2-cyclopropene-1-carbonyl metal species Journal of the American Chemical Society. 101: 233-235. DOI: 10.1021/ja00495a046  0.01
1979 Chidsey CE, Donaldson WA, Hughes RP. Cationic cobalt(I) carbonyl compounds containing complexed cyclobutadienes Journal of Organometallic Chemistry. 169: C12-C14. DOI: 10.1016/S0022-328X(00)81466-7  1
1979 Boland BE, Fam SA, Hughes RP. Activation of metal-acyl oxygen atoms by triflic anhydride: a simple synthetic route to reactive cationic vinylidene complexes Journal of Organometallic Chemistry. 172: C29-C32. DOI: 10.1016/S0022-328X(00)81057-8  0.01
1979 BOLAND BE, FAM SA, HUGHES RP. ChemInform Abstract: ACTIVATION OF METAL-ACYL OXYGEN ATOMS BY TRIFLIC ANHYDRIDE: A SIMPLE SYNTHETIC ROUTE TO REACTIVE CATIONIC VINYLIDENE COMPLEXES Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197939249  0.01
1979 CHIDSEY CE, DONALDSON WA, HUGHES RP. ChemInform Abstract: CATIONIC COBALT(I) CARBONYL COMPOUNDS CONTAINING COMPLEXED CYCLOBUTADIENES Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197927314  0.01
1979 Chidsey CE, Donaldson WA, Hughes RP, Sherwin PF. Interactions of small organic rings with transition metals. Formation of η3-cyclobutenonyl complexes by the ring expansion of 2-cyclopropene-1-carbonyl metal species [13] Journal of the American Chemical Society. 101: 233-235.  1
1978 HUGHES RP. ChemInform Abstract: REACTIONS OF DIIRON ENNEACARBONYL WITH PYRYLIUM IODIDES Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197811297  0.01
1977 Hughes RP, Krishnamachari N, Lock CJL, Powell J, Turner G. Crystal and molecular structure of a five-coordinate rhodium(I)-diene complex and the correlation of structural parameters with carbon-13 nuclear magnetic resonance shifts Inorganic Chemistry. 16: 314-319. DOI: 10.1021/ic50168a018  0.04
1977 Hughes RP. Reactions of diiron enneacarbonyl with pyrylium iodides Journal of Organometallic Chemistry. 141: C29-C32. DOI: 10.1016/S0022-328X(00)90862-3  0.01
1977 BOTTRILL M, DAVIES R, GODDARD R, GREEN M, HUGHES RP, LEWIS B, WOODWARD P. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 1 Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197740320  0.01
1977 HUGHES RP, KRISHNAMACHARI N, LOCK CJL, POWELL J, TURNER G. ChemInform Abstract: CRYSTAL AND MOLECULAR STRUCTURE OF A FIVE-COORDINATE RHODIUM(I)-DIENE COMPLEX AND THE CORRELATION OF STRUCTURAL PARAMETERS WITH CARBON-13 NUCLEAR MAGNETIC RESONANCE SHIFTS Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197716077  0.01
1977 GODDARD R, GREEN M, HUGHES RP, WOODWARD P. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 12. The Preparation and Themal Rearrangement of η′-But-3-enyl Complexes of Palladium(II): the Crystal and Molecular Structure of trans-Chloro-η′-[3-chloro-cis-1,2-bis(methoxycarbonyl)but-3-enyl] Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197703333  0.01
1977 GREEN M, HUGHES RP. ChemInform Abstract: REACTIONS OF CO-ORDINATED LIGANDS. PART XI. THE RING OPENING OF METHYLENECYCLOPROPANES BY PALLADIUM(II)-NUCLEOPHILE SYSTEMS, FORMATION OF SUBSTITUTED η3-BUT-3-ENYL COMPLEXES OF PALLADIUM(II) Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197703332  0.04
1977 CHISNALL BM, GREEN M, HUGHES RP, WELCH AJ. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. XIII. Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197703078  0.01
1976 GREEN M, HUGHES RP. ChemInform Abstract: REACTIONS OF CYCLOPENTADIENYL METAL CARBONYL ANIONS WITH THE 1,2,3-TRI-TERT-BUTYLCYCLOPROPENIUM CATION. ELECTROPHILIC ATTACK AT PERIPHERAL LIGANDS Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/chin.197605292  0.04
1976 GREEN M, HOWARD JAK, HUGHES RP, KELLETT SC, WOODWARD P. ChemInform Abstract: η2-BONDED METHYLENECYCLOPROPANE COMPLEXES OF RHODIUM(I), IRIDIUM(I), PLATINUM(0), AND PLATINUM(II). CRYSTAL AND MOLECULAR STRUCTURE OF ACETYLACETONATOBIS(η2-METHYLENECYCLOPROPANE)RHODIUM(I) Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/chin.197602316  0.04
1975 BOTTRILL M, GODDARD R, GREEN M, HUGHES RP, LLOYD MK, TAYLOR SH, WOODWARD P. ChemInform Abstract: REACTIONS OF CO-ORDINATED LIGANDS PART 10, REACTIONS OF TRIFLUOROACETONITRILE WITH PI-ALLYLIC COMPLEXES OF IRIDIUM(I) AND WITH DICARBONYL(CYCLOPENTADIENYL)METHYLIRON, THE MOLECULAR AND CRYSTAL STRUCTURE OF CARBONYL(ETA-CYCLOPENTADIENY Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197540323  0.04
1975 GREEN M, HUGHES RP, WELCH AJ. ChemInform Abstract: RING OPENING OF 2,3-BIS(HYDROXYMETHYL)METHYLENECYCLOPROPANES WITH (FE2(CO)9), THE MOLECULAR STRUCTURE OF A 1,4-DIENE COMPLEX OF IRON(0), TRICARBONYL-ETA(4)-(3-METHYLENE-4-VINYLDIHYDROFURAN-2(3H)-ONE)IRON Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197538393  0.01
1975 DAVIS R, GREEN M, HUGHES RP. ChemInform Abstract: STEPWISE DIELS-ALDER ADDITION OF HEXAFLUOROBUT-2-YNE TO CO-ORDINATED 1,3-DIENES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197537360  0.01
1975 BOTTRILL M, GODDARD R, GREEN M, HUGHES RP, LLOYD MK, LEWIS B, WOODWARD P. ChemInform Abstract: ADDITION OF HEXAFLUOROBUT-2-YNE TO CO-ORDINATED 1,3-DIENES, CRYSTAL STRUCTURES OF THE ADDUCTS (RU(CO)2(P(OCH2)3CME)(C6H8)(C4F6)2) AND (FE(CO)2(P(OCH2)3CME)(C7H8)(C4F6)2) Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197527394  0.01
1974 Ban E, Hughes RP, Powell J. Transition metal-promoted reactions of unsaturated hydrocarbons Journal of Organometallic Chemistry. 69: 455-472. DOI: 10.1016/S0022-328X(00)89751-X  0.08
1974 GREEN M, HUGHES RP. ChemInform Abstract: TRANSITION-METAL COMPLEXES OF METHYLENECYCLOPROPANES, RING-OPENING REACTIONS PROMOTED BY PALLADIUM(II) Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197449439  0.01
1974 BAN E, HUGHES RP, POWELL J. ChemInform Abstract: TRANSITION METAL-PROMOTED REACTIONS OF UNSATURATED HYDROCARBONS PART 4, REACTIONS OF NORBORNENYL COMPLEXES OF PALLADIUM(II) WITH GROUP V DONOR LIGANDS, OLEFINS, 1,3-DIENES AND 1,2-DIENES Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197431426  0.01
1974 HUGHES RP, JACK T, POWELL J. ChemInform Abstract: A STUDY OF TRIHAPTO-PENTAHAPTO EQUILIBRIA IN HEPTADIENYLPALLADIUM(II) COMPLEXES AND THE POSSIBLE ROLE OF SUCH COMPLEXES IN METAL COMPLEX CATALYSED 1,4-POLYMERIZATIONS OF 1,3-BUTADIENE Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197417442  0.01
1974 HUGHES RP, POWELL J. ChemInform Abstract: TRANSITION METAL PROMOTED REACTIONS OF UNSATURATED HYDROCARBONS PART 3, INSERTION OF 1,2-DIENS INTO ALLYLIC PALLADIUM BONDS Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197408453  0.01
1974 HUGHES RP, POWELL J. ChemInform Abstract: TRANSITION METAL PROMOTED REACTIONS OF UNSATURATED HYDROCARBONS PART 2, INSERTION OF BICYCLIC OLEFINS INTO ALLYLIC-PALLADIUM AND -PLATINUM BONDS Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197408452  0.08
1974 HUGHES RP, POWELL J. ChemInform Abstract: A (13)C AND (1)H NMR INVESTIGATION OF THE BONDING IN NORBORNENYL COMPLEXES OF PALLADIUM(II) AND PLATINUM(II) Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197408062  0.01
1973 Hughes R, Jack T, Powell J. A study of trihapto-pentahapto equilibria in heptadienylpalladium(ii) complexes and the possible role of such complexes in metal complex catalysed 1,4-polymerizations of 1,3-butadiene Journal of Organometallic Chemistry. 63: 451-459. DOI: 10.1016/S0022-328X(73)80058-0  1
1973 Hughes R, Powell J. The dynamic stereochemistry of the allylic ligand in a μ-allylic complex of platinum(II) Journal of Organometallic Chemistry. 55: C45-C48. DOI: 10.1016/S0022-328X(00)84029-2  1
1973 Hughes RP, Powell J. A 13C and 1H NMR investigation of the bonding in norbornenyl complexes of palladium(II) and platinum(II) Journal of Organometallic Chemistry. 60: 427-441. DOI: 10.1016/S0022-328X(00)80661-0  0.08
1973 Hughes RP, Powell J. Transition metal promoted reactions of unsaturated hydrocarbons Journal of Organometallic Chemistry. 60: 409-425. DOI: 10.1016/S0022-328X(00)80660-9  1
1973 Hughes RP, Powell J. Transition metal promoted reactions of unsaturated hydrocarbons Journal of Organometallic Chemistry. 60: 387-407. DOI: 10.1016/S0022-328X(00)80659-2  1
1973 HUGHES RP, POWELL J. ChemInform Abstract: THE DYNAMIC STEREOCHEMISTRY OF THE ALLYLIC LIGAND IN A MU-ALLYLIC COMPLEX OF PLATINUM(II) Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/chin.197343419  0.04
1972 Cooper DG, Hughes RP, Powell J. Carbon-13 shielding effects in metal-alkyl, metal-olefin, and metal-allyl bonds Journal of the American Chemical Society. 94: 9244-9246. DOI: 10.1021/ja00781a054  0.04
1972 Hughes R, Powell J. Insertion of 1,2-dienes into π-homoallylic complexes of palladium(II) Journal of Organometallic Chemistry. 34: C51-C54. DOI: 10.1016/S0022-328X(00)88275-3  1
1969 Hughes R, Powell J. The reaction of allene with acetylacetonato-π-allylpalladium(II): formation of 2,2′-bi-π-allyl complexes of palladium(II) Journal of Organometallic Chemistry. 20: P17-P19. DOI: 10.1016/S0022-328X(00)80073-X  1
Show low-probability matches.