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Steven H. Bertz, Ph.D. - Publications

Affiliations: 
1973-1977 Chemisty Harvard University, Cambridge, MA, United States 
 1978-1991 Bell Laboratories, Murray Hill, NJ, United States 
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34 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2013 Bertz SH, Hardin RA, Heavey TJ, Ogle CA. The X-ray crystal structure of a cuprate-carbonyl π-complex. Angewandte Chemie (International Ed. in English). 52: 10250-2. PMID 23943548 DOI: 10.1002/Anie.201303783  0.686
2013 Bertz SH, Hardin RA, Heavey TJ, Jones DS, Monroe TB, Murphy MD, Ogle CA, Whaley TN. First X-ray crystal structure and internal reference diffusion-ordered NMR spectroscopy study of the prototypical Posner reagent, MeCu(SPh)Li(THF)3. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 10138-41. PMID 23780906 DOI: 10.1002/Chem.201301415  0.586
2013 Bertz SH, Hardin RA, Ogle CA. Aldehydes and ketones form intermediate π complexes with the Gilman reagent, Me2CuLi, at low temperatures in tetrahydrofuran. Journal of the American Chemical Society. 135: 9656-8. PMID 23777294 DOI: 10.1021/Ja404105U  0.658
2013 Bertz SH, Hardin RA, Murphy MD, Ogle CA. π-Complexes from acyl cyanides and lithium dimethylcuprate(I). Chemical Communications (Cambridge, England). 49: 3010-2. PMID 23459603 DOI: 10.1039/C3Cc40602D  0.631
2012 Bertz SH, Hardin RA, Murphy MD, Ogle CA, Richter JD, Thomas AA. Rapid injection NMR reveals η3 'π-allyl' Cu(III) intermediates in addition reactions of organocuprate reagents. Journal of the American Chemical Society. 134: 9557-60. PMID 22631600 DOI: 10.1021/Ja3022363  0.687
2012 Bertz SH, Hardin RA, Murphy MD, Ogle CA, Richter JD, Thomas AA. Minimization of organocuprate complexity through self-organization: remarkable orientation effect in mixed cuprate π complexes. Angewandte Chemie (International Ed. in English). 51: 2681-5. PMID 22298492 DOI: 10.1002/Anie.201107060  0.608
2012 Bertz SH, Browder KL, Hardin RA, Murphy MD, Ogle CA, Thomas AA. Ligand exchange in mixed organocuprate(I) π-complexes Organometallics. 31: 7809-7811. DOI: 10.1021/Om3006646  0.655
2012 Bertz SH, Cope SK, Hardin RA, Murphy MD, Ogle CA, Smith DT, Thomas AA, Whaley TN. Complexes of the gilman reagent with double bonds across the π-σ Continuum Organometallics. 31: 7827-7838. DOI: 10.1021/Om300622C  0.647
2010 Bertz SH, Moazami Y, Murphy MD, Ogle CA, Richter JD, Thomas AA. Complexes of Gilman reagents with C-S and C-N double bonds: sigma or pi bonding? Journal of the American Chemical Society. 132: 9549-51. PMID 20540520 DOI: 10.1021/Ja103068H  0.653
2010 Bertz SH, Murphy MD, Ogle CA, Thomas AA. Organocuprate(III) chemistry: synthesis and reactivity of amido, cyano, phosphido and thiolato ate complexes of copper(III). Chemical Communications (Cambridge, England). 46: 1255-6. PMID 20449268 DOI: 10.1039/B921412G  0.655
2010 Bartholomew ER, Bertz SH, Cope SK, Murphy MD, Ogle CA, Thomas AA. Serendipity strikes again--efficient preparation of lithium tetramethylcuprate(III) via rapid injection NMR. Chemical Communications (Cambridge, England). 46: 1253-4. PMID 20449267 DOI: 10.1039/B924000D  0.627
2008 Bartholomew ER, Bertz SH, Cope S, Murphy M, Ogle CA. Preparation of sigma- and pi-allylcopper(III) intermediates in SN2 and SN2' reactions of organocuprate(I) reagents with allylic substrates. Journal of the American Chemical Society. 130: 11244-5. PMID 18671398 DOI: 10.1021/Ja801186C  0.687
2008 Bartholomew ER, Bertz SH, Cope S, Dorton DC, Murphy M, Ogle CA. Neutral organocopper(III) complexes. Chemical Communications (Cambridge, England). 1176-7. PMID 18309408 DOI: 10.1039/B717290G  0.634
2007 Bertz SH, Cope S, Dorton D, Murphy M, Ogle CA. Organocuprate cross-coupling: the central role of the copper(III) intermediate and the importance of the copper(I) precursor. Angewandte Chemie (International Ed. in English). 46: 7082-5. PMID 17712868 DOI: 10.1002/Anie.200703035  0.582
2007 Bertz SH, Cope S, Murphy M, Ogle CA, Taylor BJ. Rapid injection NMR in mechanistic organocopper chemistry. Preparation of the elusive copper(III) intermediate. Journal of the American Chemical Society. 129: 7208-9. PMID 17506552 DOI: 10.1021/Ja067533D  0.671
2005 Murphy MD, Ogle CA, Bertz SH. Opening the 'black box': oscillations in organocuprate conjugate addition reactions. Chemical Communications (Cambridge, England). 854-6. PMID 15700059 DOI: 10.1039/B412514B  0.652
2005 Bertz SH, Ogle CA, Rastogi A. Remarkable effect of silyl groups on asymmetric induction in a conjugate addition reaction with O-methylnorephedrine-based N-silylamidocuprates. Journal of the American Chemical Society. 127: 1372-3. PMID 15686359 DOI: 10.1021/Ja0455805  0.634
2005 Bertz SH, Human J, Ogle CA, Seagle P. Subtle factors are important: radical formation and transmetallation in reactions of butyl cuprates with cyclohexyl iodide. Organic & Biomolecular Chemistry. 3: 392-4. PMID 15678172 DOI: 10.1039/B416612D  0.64
2005 Bertz SH, Ogle CA, Rastogi A. New Copper Chemistry. Part 31. Remarkable Effect of Silyl Groups on Asymmetric Induction in a Conjugate Addition Reaction with O-Methylnorephedrine-Based N-Silylamidocuprates. Cheminform. 36. DOI: 10.1002/chin.200524042  0.624
2003 Bertz SH. Complexity of synthetic reactions. The use of complexity indices to evaluate reactions, transforms and disconnections New Journal of Chemistry. 27: 860-869. DOI: 10.1039/b210843g  0.375
2002 Bertz SH, Carlin CM, Deadwyler DA, Murphy MD, Ogle CA, Seagle PH. Rapid-injection NMR study of iodo- and cyano-Gilman reagents with 2-cyclohexenone: observation of pi-complexes and their rates of formation. Journal of the American Chemical Society. 124: 13650-1. PMID 12431075 DOI: 10.1021/Ja027744S  0.656
1999 Bertz SH, Chopra A, Eriksson M, Ogle CA, Seagle P. Re-evaluation of Organocuprate Reactivity: Logarithmic Reactivity Profiles for Iodo- versus Cyano-Gilman Reagents in the Reactions of Organocuprates with 2-Cyclohexenone and Iodocyclohexane Chemistry - a European Journal. 5: 2680-2691. DOI: 10.1002/(Sici)1521-3765(19990903)5:9<2680::Aid-Chem2680>3.0.Co;2-T  0.633
1999 Bertz SH, Chopra A, Eriksson M, Ogle CA, Seagle P. New copper chemistry, part 29: Re-evaluation of organocuprate reactivity: Logarithmic reactivity profiles for iodo- versus cyano-Gilman reagents in the reactions of organocuprates with 2-cyclohexenone and iodocyclohexane Chemistry - a European Journal. 5: 2680-2691.  0.636
1989 Bertz SH, Smith RAJ. New copper chemistry. 16. Mechanism of organocuprate conjugate addition: observation of cuprate-olefin complexes and lithium-coordinated intermediates in the reaction of lithium dimethylcuprate(I) with 10-methyl-.DELTA.1,9-2-octalone Journal of the American Chemical Society. 111: 8276-8277. DOI: 10.1021/ja00203a038  0.433
1989 Bertz SH, Smith RAJ. Mechanism of organocuprate conjugate addition: Observation of cuprate-olefin complexes and Li-coordinated intermediates in the reaction of lithium dimethylcuprate(I) with 10-methyl-Δ1,9-2-octalone Journal of the American Chemical Society. 111: 8276-8277.  0.403
1988 Gibson CP, Dabbagh G, Bertz SH. Titanium enolates from epoxides and bis(pentamethylcyclopentadienyl) dimethyltitanium(IV) Journal of the Chemical Society, Chemical Communications. 603-605. DOI: 10.1039/C39880000603  0.301
1986 BERTZ SH, DABBAGH G, WILLIAMS LM. ChemInform Abstract: New Copper Chemistry. Part 9. Reaction of Organocuprates with Dithio Esters: Double-Barrelled Carbophilic Addition and a New Synthetic Route to Tertiary Thiols. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198621141  0.334
1985 Bertz SH, Lannoye G, Cook JM. The synthesis of triquinacene via the weiss reaction. Tetrahedron Letters. 26: 4695-4698. DOI: 10.1016/S0040-4039(00)94926-8  0.347
1985 Bertz SH, Dabbagh G, Williams LM. Reaction of organocuprates with dithio esters: Double-barrelled carbophilic addition and a new synthetic route to tertiary thiols [2] Journal of Organic Chemistry. 50: 4414-4415.  0.327
1982 Bertz SH, Rihs G, Woodward RB. Reaction of dimethyl sodio-3-ketoglutarate with glyoxal and substituted glyoxals. First expeditious preparation of bicyclo[3.3.0]octane-3,7-dione; synthesis and crystal structure of 5,7-dihydroxy-4-methoxycarbonyl-3-phenyl-1-indanone Tetrahedron. 38: 63-70. DOI: 10.1016/0040-4020(82)85046-1  0.615
1981 Aharon-Shalom E, Wudl F, Bertz SH, Walsh WM, Rupp LW, Chaikin PM, Burns MJ, Andres K, Schwenk H. TETRAKIS (DEUTERIOMETHYL) TETRASELENAFULVALENE. Molecular Crystals and Liquid Crystals. 86: 35-41. DOI: 10.1080/00268948208073666  0.371
1981 Bertz SH, Adams WO, Silverton JV. 2,5-Bis(methoxycarbonyl)-4-hydroxycyclopent-2-en-1-one as an intermediate in Weiss' glyoxal reaction. Analogous chemistry of malondialdehyde Journal of Organic Chemistry. 46: 2828-2830.  0.362
1973 Casey CP, Bertz SH, Burkhardt TJ. Reaction of metal-carbene complexes with diazoalkanes. A versatile vinyl ether synthesis. Tetrahedron Letters. 14: 1421-1424. DOI: 10.1016/S0040-4039(01)95959-3  0.562
1973 CASEY CP, BERTZ SH, BURKHARDT TJ. ChemInform Abstract: RK. VON METALL-CARBEN-KOMPLEXEN MIT DIAZOALKANEN, EINE EINFACHE SYNTHESE FUER VINYLAETHER Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197329217  0.404
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