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Leo A. Paquette - Publications

Affiliations: 
Ohio State University, Columbus, Columbus, OH 
Area:
organic synthesis
Website:
http://chemistry.osu.edu/faculty/paquette

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Year Citation  Score
2012 Paquette LA, Ross RJ, Springer JP. Stereocontrolled construction of an ingenol prototype having a complete array of oxygenated and unsaturated centers. Journal of the American Chemical Society. 110: 6192-204. PMID 22148799 DOI: 10.1021/Ja00226A039  0.505
2010 Paquette LA. Silicon-mediated organic synthesis. Science (New York, N.Y.). 217: 793-800. PMID 17778295 DOI: 10.1126/Science.217.4562.793  0.301
2010 Pettigrew JD, Paquette LA. Efforts toward the synthesis of pseudolaric acid a: Intramolecular bromoetherification as a multipurpose synthetic tool Heterocycles. 80: 99-102. DOI: 10.3987/Com-09-S(S)7  0.359
2010 Hartung R, Paquette L. ChemInform Abstract: New Synthetic Tactics Designed to Access Diynes and Polyynes Cheminform. 33: no-no. DOI: 10.1002/chin.200251241  0.751
2010 Paquette LA, Owen DR, Bibart RT, Seekamp CK, Kahane AL, Lanter JC, Alvarez Corral M. ChemInform Abstract: 1-Oxaspiro[4.4]nonan-6-ones. Synthetic Access via Oxonium Ion Technology, Optical Resolution, and Conversion into Enantiopure Spirocyclic α,β-Butenolides. Cheminform. 32: no-no. DOI: 10.1002/chin.200136107  0.761
2010 MITZEL TM, PAQUETTE LA. ChemInform Abstract: Linear and Cyclic Carbon Systems. Cheminform. 28: no-no. DOI: 10.1002/chin.199725282  0.729
2010 PAQUETTE LA, HORMUTH S, LOVELY CJ. ChemInform Abstract: Studies Directed Toward the Total Synthesis of Cerorubenic Acid-III. Part 4. Exploration of an Organometallic Approach to Construction of the Eastern Sector. Cheminform. 26: no-no. DOI: 10.1002/chin.199549227  0.579
2010 PAQUETTE LA, COMBRINK KD, ELMORE SW, ROGERS RD. ChemInform Abstract: Impact of Substituent Modifications on the Atropselectivity Characteristics of an Anionic Oxy-Cope Ring Expansion. Cheminform. 22: no-no. DOI: 10.1002/chin.199126107  0.681
2009 Wang X, Butler SC, Gallucci JC, Paquette LA. Enolization regioselectivity involving stereoisomeric 4a-methyl-5-methoxyperhydrobenzo[7]annulen-2-ones. The Journal of Organic Chemistry. 74: 6825-30. PMID 19642628 DOI: 10.1021/Jo901391D  0.367
2009 Paquette LA, Dura RD, Modolo I. Contrasting responses of pyrido[2,1-a]isoindol-6-ones and their sultam counterparts to photochemical activation. The Journal of Organic Chemistry. 74: 1982-7. PMID 19199670 DOI: 10.1021/Jo802476C  0.375
2009 Paquette LA, Moura-Letts G, Wang GP. From D-glucose to enantiomerically pure cycloctanoses. The glycosidase inhibitory capacity of medium-ring carbasugars. The Journal of Organic Chemistry. 74: 2099-107. PMID 19173597 DOI: 10.1021/Jo802620H  0.321
2009 Proust N, Preston AJ, Paquette LA. Workable synthetic routes to functionalized 1,6-benzodiazocines Heterocycles. 77: 163-166. DOI: 10.3987/Com-08-S(F)10  0.329
2009 Paquette LA, Lai KW. Claisen ring expansion approach toward the CDEF ring system of lancifodilactone G Heterocycles. 79: 299-302. DOI: 10.3987/Com-08-S(D)2  0.353
2009 Braun A, Cho IH, Ciblat S, Clyne D, Forgione P, Hart AC, Huang G, Kim J, Modolo I, Paquette LA, Peng X, Pichlmair S, Stewart CA, Wang J, Zuev D. Enantioselective synthesis of structurally intricate and complementary polyoxygenated building blocks of spongistatin 1 (altohyrtin a) Collection of Czechoslovak Chemical Communications. 74: 651-769. DOI: 10.1135/Cccc2008181  0.819
2008 Gallucci JC, Dura RD, Paquette LA. 7-Bromo-4b-methyl-7,8-dihydro-4bH-9-thia-8a-aza-fluorene 9,9-dioxide. Acta Crystallographica. Section E, Structure Reports Online. 64: o1303. PMID 21202932 DOI: 10.1107/S1600536808017972  0.372
2008 Moura-Letts G, Paquette LA. Contiguously substituted cyclooctane polyols. configurational assignments via (1)H NMR correlations and symmetry considerations. The Journal of Organic Chemistry. 73: 7663-70. PMID 18761439 DOI: 10.1021/Jo801443D  0.336
2008 Paquette LA, Wah Lai K. Pinacol macrocyclization-based route to the polyfused medium-sized CDE ring system of lancifodilactone G. Organic Letters. 10: 3781-4. PMID 18683932 DOI: 10.1021/Ol8014607  0.315
2008 Proust N, Gallucci JC, Paquette LA. Neighboring group participation by sulfonamido nitrogen. The Journal of Organic Chemistry. 73: 6279-82. PMID 18630964 DOI: 10.1021/Jo800952M  0.306
2008 Paquette LA, Peng X, Yang J, Kang HJ. The carbohydrate-sesquiterpene interface. directed synthetic routes to both (+)- and (-)-fomannosin from D-glucose. The Journal of Organic Chemistry. 73: 4548-58. PMID 18489155 DOI: 10.1021/Jo8004233  0.682
2008 Lai KW, Paquette LA. Stereocontrolled synthesis of the sterically encumbered F ring of lancifodilactone G. Organic Letters. 10: 2115-8. PMID 18454538 DOI: 10.1021/Ol800419V  0.333
2008 Paquette LA, Lai KW. Studies directed toward the total synthesis of lancifodilactone G: an expeditious route to the ABC subunit. Organic Letters. 10: 2111-3. PMID 18454534 DOI: 10.1021/Ol800418M  0.357
2008 Paquette LA, Dura RD, Gallucci JC. Photodimerization of pyrido[2,1-a]isoindol-6(4H)-one Heterocycles. 76: 129-132. DOI: 10.3987/Com-07-S(N)2  0.32
2008 Stewart CA, Peng X, Paquette LA. An efficient means for generating p-methoxybenzyl (PMB) ethers under mildly acidic conditions Synthesis. 0433-0437. DOI: 10.1055/S-2008-1032132  0.469
2007 Gallucci JC, Inomata K, Dura RD, Paquette LA. (+)-(1S,5R,10S)-11,11-Dimeth-yl-4-oxa-tricyclo-[8.4.0.0]tetra-deca-ne-3,12-dione. Acta Crystallographica. Section E, Structure Reports Online. 64: o287. PMID 21200853 DOI: 10.1107/S1600536807066159  0.348
2007 Hilmey DG, Davis BD, Gallucci JC, Brodbelt JS, Paquette LA. X-ray crystallographic and mass spectrometric probing of the conformational and ionophoric properties of stereoisomeric hexatetrahydrofuranylhexane segments. The Journal of Organic Chemistry. 72: 9088-101. PMID 17958448 DOI: 10.1021/Jo7016229  0.313
2007 Paquette LA, Peng X, Yang J. Asymmetric synthesis of the phytopathogen (+)-fomannosin. Angewandte Chemie (International Ed. in English). 46: 7817-9. PMID 17823900 DOI: 10.1002/Anie.200702056  0.626
2007 Adaligil E, Davis BD, Hilmey DG, Shen Y, Spruell JM, Brodbelt JS, Houk KN, Paquette LA. Synthesis of, and structural assignments to the stereoisomers of bis (2,2')- and tris (2,2',2")-tetrahydrofurans: conformational features and ionic binding capacities of these gateway polycyclic networks. The Journal of Organic Chemistry. 72: 6215-23. PMID 17629342 DOI: 10.1021/Jo0708238  0.326
2007 Ciblat S, Kim J, Stewart CA, Wang J, Forgione P, Clyne D, Paquette LA. A modular approach to marine macrolide construction. 4. Assembly of C36-C51 and C29-C44 building blocks and evaluation of key coupling reactions targeting spongistatin 1 (altohyrtin A). Organic Letters. 9: 719-22. PMID 17286379 DOI: 10.1021/Ol063083I  0.703
2007 O'Connor PD, Knight CK, Friedrich D, Peng X, Paquette LA. Pectenotoxin-2 synthetic studies. 3. Assessment of the capacity for stereocontrolled cyclization to form the entire C1-C26 subunit based upon the double bond geometry across C15-C16. The Journal of Organic Chemistry. 72: 1747-54. PMID 17269830 DOI: 10.1021/Jo062513F  0.574
2007 Bedore MW, Chang SK, Paquette LA. Development of an access route to the c31-c52 central core of amphidinol 3. Organic Letters. 9: 513-6. PMID 17249800 DOI: 10.1021/Ol062875+  0.351
2007 Paquette LA, Hu Y, Luxenburger A, Bishop RL. Studies toward the total synthesis of dumsin. 2. A second generation approach resulting in enantioselective construction of a functionalized ABC subunit of the tetranortriterpenoid insect antifeedant. The Journal of Organic Chemistry. 72: 209-22. PMID 17194102 DOI: 10.1021/Jo062068O  0.427
2007 Nagamine T, Inomata K, Endo Y, Paquette LA. Amino acid mediated intramolecular asymmetric aldol reaction to construct a new chiral bicyclic enedione containing a seven-membered ring: remarkable inversion of enantioselectivity compared to the six-membered ring example. The Journal of Organic Chemistry. 72: 123-31. PMID 17194090 DOI: 10.1021/Jo061824N  0.395
2007 Dura RD, Modolo I, Paquette LA. Effective synthetic routes to 4H- and 10bH- pyrido[2,1-α]isoindol-6-ones Heterocycles. 74: 145-148. DOI: 10.3987/Com-07-S(W)19  0.318
2007 Selvaraj PR, Paquette LA. Do upper limits to the multiple spiro acetalization of the cyclohexane ring exist? Heterocycles. 73: 165-168. DOI: 10.3987/Com-07-S(U)4  0.8
2007 Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. Ethene/norbornene copolymerization with (isodicyclopentadienyl)titanium complex-MAO catalyst Collection of Czechoslovak Chemical Communications. 72: 697-702. DOI: 10.1135/Cccc20070697  0.578
2007 Gallucci JC, Dura RD, Paquette LA. (11SR,13RS)-12-Oxa-9-aza-tetra-cyclo[7.4.1.02,7.0 11,13]tetra-deca-2(7),3,5-trien-8-one Acta Crystallographica Section E: Structure Reports Online. 63: o3417. DOI: 10.1107/S160053680703228X  0.34
2007 Adaligil E, Davis BD, Hilmey DG, Shen Y, Spruell JM, Brodbelt JS, Houk KN, Paquette LA. Erratum: Synthesis of, and structural assignments to the stereoisomers of bis (2,2′)- and tris (2,2′,2″)-tetrahydrofurans: Conformational features and ionic binding capacities of these gateway polycyclic networks (Journal of Organic Chemistry (2007) 72 (6216)) Journal of Organic Chemistry. 72. DOI: 10.1021/Jo702007W  0.311
2007 Hilmey DG, Paquette LA. 1,3‐Dichloroacetone as a Cyclopropanone Equivalent: 5‐Oxaspiro[3.4]Octan‐1‐One Organic Syntheses. 156-162. DOI: 10.1002/0471264229.Os084.16  0.391
2006 Paquette LA, Dura RD, Fosnaugh N, Stepanian M. Direct comparison of the response of bicyclic sultam and lactam dienes to photoexcitation. Concerning the propensity of differing bond types to bridgehead nitrogen for homolytic cleavage. The Journal of Organic Chemistry. 71: 8438-45. PMID 17064017 DOI: 10.1021/Jo061404Y  0.392
2006 Kreilein MM, Hofferberth JE, Hart AC, Paquette LA. Diosphenol-based approach to the a-ring functionalization of advanced Taxol precursors. The Journal of Organic Chemistry. 71: 7329-36. PMID 16958527 DOI: 10.1021/Jo061115+  0.807
2006 Preston AJ, Gallucci JC, Paquette LA. Synthesis and selected reactions of a bicyclic sultam having sulfur at the apex position. The Journal of Organic Chemistry. 71: 6573-8. PMID 16901145 DOI: 10.1021/Jo0611162  0.433
2006 Hu Y, Bishop RL, Luxenburger A, Dong S, Paquette LA. Alkali metal counterion control of enolate protonation stereoselectivity. Organic Letters. 8: 2735-7. PMID 16774244 DOI: 10.1021/Ol060761S  0.323
2006 Paquette LA, Zhang Y. From common carbohydrates to enantiopure cyclooctane polyols and glycomimetics via deoxygenative zirconocene ring contraction. The Journal of Organic Chemistry. 71: 4353-63. PMID 16749762 DOI: 10.1021/Jo051989G  0.353
2006 Paquette LA, Hilmey DG, Gallucci JC. Practical designed syntheses of all stereoisomeric bis(2,2')- and tris(2,2',2' ')-tetrahydrofurans. Organic Letters. 8: 2635-7. PMID 16737332 DOI: 10.1021/Ol0608350  0.357
2006 Dong S, Parker GD, Tei T, Paquette LA. In pursuit of pestalotiopsin a via zirconocene-mediated ring contraction. Organic Letters. 8: 2429-31. PMID 16706543 DOI: 10.1021/Ol060827J  0.401
2006 Dura RD, Paquette LA. Ring contraction of bridgehead sultams by photoinduced di-pi-methane rearrangement. The Journal of Organic Chemistry. 71: 2456-9. PMID 16526797 DOI: 10.1021/Jo0526587  0.365
2006 Hartung RE, Paquette LA. Direct comparison of SN2 mesylate displacement versus the mitsunobu protocol for 2′,3′-dideoxyspirocarbanucleoside construction Heterocycles. 67: 75-78. DOI: 10.3987/Com-04-S(T)2  0.798
2006 Hilmey DG, Selvaraj PR, Paquette LA. Synthesis and Lewis acid induced isomerization of mono-, di-, and tri-spiro α-keto tetrahydro-furans and -pyrans Canadian Journal of Chemistry. 84: 1388-1396. DOI: 10.1139/V06-103  0.816
2006 Dura RD, Paquette LA. Tetrabutylammonium fluoride in dimethyl sulfoxide: A reagent combination for the twofold dehydrobromination of vicinal dibromides Synthesis. 2837-2840. DOI: 10.1055/S-2006-942527  0.318
2006 Pichlmair S, de Lera Ruiz M, Vilotijevic I, Paquette LA. Exploration of conjugate addition routes to advanced tricyclic components of mangicol A Tetrahedron. 62: 5791-5802. DOI: 10.1016/J.Tet.2006.03.066  0.397
2006 Pichlmair S, de Lera Ruiz M, Basu K, Paquette LA. Evaluation of possible intramolecular [4+2] cycloaddition routes for assembling the central tetracyclic core of the potent marine antiinflammatory agent mangicol A Tetrahedron. 62: 5178-5194. DOI: 10.1016/J.Tet.2005.11.096  0.651
2005 Paquette LA, Liu Z, Ramsey C, Gallucci JC. Competitive stereochemical control operative during conrotatory electrocyclization of helically equilibrating diquinanyl-substituted 1,3,5,7-octatetraenyl bisenolates. The Journal of Organic Chemistry. 70: 8154-61. PMID 16277342 DOI: 10.1021/Jo0513919  0.332
2005 Paquette LA, Kreilein MM, Bedore MW, Friedrich D. Oxidative cleavage of p-methoxybenzyl ethers with methyl(trifluoromethyl)dioxirane. Organic Letters. 7: 4665-7. PMID 16209505 DOI: 10.1021/Ol051856H  0.799
2005 Paquette LA, Dong S. Stereoselective synthesis of beta-anomeric 4'-thiaspirocyclic ribonucleosides carrying the full complement of RNA-level hydroxyl substitution. The Journal of Organic Chemistry. 70: 5655-64. PMID 15989350 DOI: 10.1021/Jo0506985  0.387
2005 Paquette LA, Chang SK. The polyol domain of amphidinol 3. A stereoselective synthesis of the entire C(1)-C(30) sector. Organic Letters. 7: 3111-4. PMID 15987218 DOI: 10.1021/Ol0511833  0.332
2005 Hilmey DG, Paquette LA. Promoter-dependent course of the Beckmann rearrangement of stereoisomeric spiro[4.4]nonane-1,6-dione monoximes. Organic Letters. 7: 2067-9. PMID 15876056 DOI: 10.1021/Ol050669G  0.305
2005 Bondar D, Liu J, Müller T, Paquette LA. Pectenotoxin-2 synthetic studies. 2. Construction and conjoining of ABC and DE Eastern hemisphere subtargets. Organic Letters. 7: 1813-6. PMID 15844913 DOI: 10.1021/Ol0504291  0.804
2005 Hartung R, Paquette LA. Practical synthesis of enantiopure spiro[4.4]nonane C-(2'-deoxy)ribonucleosides. The Journal of Organic Chemistry. 70: 1597-604. PMID 15730277 DOI: 10.1021/Jo0480601  0.803
2005 Paquette LA, Zhang Y. Enantioselective route from carbohydrates to cyclooctane polyols. Organic Letters. 7: 511-3. PMID 15673277 DOI: 10.1021/Ol0474296  0.359
2005 Brennan NK, Guo X, Paquette LA. Second-generation, highly abbreviated route for elaboration of the oxetane D-ring in a fully functionalized taxane. The Journal of Organic Chemistry. 70: 732-4. PMID 15651832 DOI: 10.1021/Jo0482965  0.815
2005 Inomata K, Barragué M, Paquette LA. Diastereoselectivities realized in the amino acid catalyzed aldol cyclizations of triketo acetonides of differing ring size. The Journal of Organic Chemistry. 70: 533-9. PMID 15651798 DOI: 10.1021/Jo0486084  0.379
2005 Paquette LA, Liu Z, Efremov I. Exploratory studies aimed at a synthesis of vinigrol. 4. Probe of possible means for direct connection of the side arms and of ring-contraction alternatives. The Journal of Organic Chemistry. 70: 514-8. PMID 15651795 DOI: 10.1021/Jo048456C  0.778
2005 Paquette LA, Efremov I. Exploratory studies aimed at a synthesis of vinigrol. 3. Evaluation of a lactone bridge as a conformational lock. The Journal of Organic Chemistry. 70: 510-3. PMID 15651794 DOI: 10.1021/Jo0484575  0.757
2005 Paquette LA, Efremov I, Liu Z. Exploratory studies aimed at a synthesis of vinigrol. 2. Attempts to exploit ring-closing metathesis for construction of the central cyclooctane belt. The Journal of Organic Chemistry. 70: 505-9. PMID 15651793 DOI: 10.1021/Jo048458X  0.784
2005 Guo X, Paquette LA. Concise means for accessing an advanced precursor to 1-deoxypaclitaxel. The Journal of Organic Chemistry. 70: 315-20. PMID 15624939 DOI: 10.1021/Jo048289G  0.41
2005 Paquette LA, Hilmey DG, Selvaraj PR. Direct access to heteropolycyclic spiroketones. 1,3-dichloroacetone as a cyclopropanone equivalent Heterocycles. 66: 57-60. DOI: 10.3987/Com-05-S(K)14  0.808
2005 Chang SK, Paquette LA. Synthesis of the skipped polyene chain and its neighboring highly oxygenated pyran ring en route to delivering the C(43)-C(67) subsector of amphidinol 3 Synlett. 2915-2918. DOI: 10.1055/S-2005-918960  0.397
2005 Hartung RE, Paquette LA. Development of a generic stereocontrolled pathway to fully hydroxylated spirocarbocyclic nucleosides as a prelude to RNA targeting Synthesis. 3209-3218. DOI: 10.1055/S-2005-918472  0.775
2005 Hilmey DG, Gallucci JC, Paquette LA. Neighboring effect of the lactam functionality in select reactions of 6-azaspiro[4.5]decane-1,7-dione Tetrahedron. 61: 11000-11009. DOI: 10.1016/J.Tet.2005.08.091  0.368
2005 Paquette LA, Selvaraj PR, Keller KM, Brodbelt JS. Is potential coordination of alkali metal ions to stereodefined polyoxygenated cyclohexanes an adequate driving force for fostering the adoption of axial conformers? Tetrahedron. 61: 231-240. DOI: 10.1016/J.Tet.2004.10.011  0.762
2005 Paquette LA, Tian Z, Seekamp CK, Wang T. Synthesis of the cyclopentyl nucleoside (-)-neplanocin A from D-glucose via zirconocene-mediated ring contraction Helvetica Chimica Acta. 88: 1185-1198. DOI: 10.1002/Hlca.200590099  0.798
2005 Paquette LA. The Ramberg‐Bäcklund Rearrangement Organic Reactions. 1-71. DOI: 10.1002/0471264180.Or025.01  0.404
2005 Kreilein MM, Eppich JC, Paquette LA. 1,4-Dioxene Organic Syntheses. 82: 99-107.  0.768
2004 Paquette LA, Seekamp CK, Kahane AL, Hilmey DG, Gallucci J. Stereochemical features of Lewis acid-promoted glycosidations involving 4'-spiroannulated DNA building blocks. The Journal of Organic Chemistry. 69: 7442-7. PMID 15497968 DOI: 10.1021/Jo048904G  0.798
2004 Paquette LA, Chang J, Liu Z. Synthetic studies aimed at (-)-cochleamycin A. Evaluation of late-stage macrocyclization alternatives. The Journal of Organic Chemistry. 69: 6441-8. PMID 15357606 DOI: 10.1021/Jo049084A  0.586
2004 Paquette LA, Kahane AL, Seekamp CK. Conformationally constrained purine mimics. Incorporation of adenine and guanine into spirocyclic nucleosides. The Journal of Organic Chemistry. 69: 5555-62. PMID 15307723 DOI: 10.1021/Jo049413Z  0.785
2004 Paquette LA, Barton WR, Gallucci JC. Synthesis of 1-Aza-8-thiabicyclo[4.2.1]nona-2,4-diene 8,8-dioxide and its conversion to a strained spirocycle via photoinduced SO2-N bond cleavage. Organic Letters. 6: 1313-5. PMID 15070325 DOI: 10.1021/Ol049679S  0.402
2004 Paquette LA, Hartung RE, Hofferberth JE, Vilotijevic I, Yang J. Synthesis of stereoisomeric medium-ring alpha,alpha'-dihydroxy cycloalkanones. The Journal of Organic Chemistry. 69: 2454-60. PMID 15049645 DOI: 10.1021/Jo0358675  0.797
2004 Paquette LA, Hartung RE, Hofferberth JE, Gallucci JC. Reactions of alpha,alpha'-dihydroxy ketones with phosgene. Structural requirements for spiro epoxy carbonate formation. Organic Letters. 6: 969-71. PMID 15012077 DOI: 10.1021/Ol036497+  0.8
2004 Hartung RE, Paquette LA. Homologation of vicinal polyketone networks to epoxy ketones with diazomethane Heterocycles. 64: 23-26. DOI: 10.3987/Com-04-S(P)9  0.787
2004 Paquette LA. Spirocyclic Restriction of Nucleosides Australian Journal of Chemistry. 57: 7-17. DOI: 10.1071/Ch03267  0.353
2004 Basu K, Richards J, Paquette LA. Mono- and bis-acrolein derivatives by reliable and efficient one-step methylenation of aldehyde precursors Synthesis. 2841-2844. DOI: 10.1055/S-2004-834866  0.605
2004 Peng X, Bondar D, Paquette LA. Alkoxide precoordination to rhodium enables stereodirected catalytic hydrogenation of a dihydrofuranol precursor of the C29-40 F/G sector of pectenotoxin-2 Tetrahedron. 60: 9589-9598. DOI: 10.1016/J.Tet.2004.06.142  0.799
2004 Paquette LA, Kang HJ. Synthesis of an enantiomerically pure 2,2,4-trisubstituted cyclobutanone building block by zirconocene-promoted deoxygenative ring contraction of structurally modified 4-vinylfuranosides Tetrahedron. 60: 1353-1358. DOI: 10.1016/J.Tet.2003.07.012  0.357
2004 Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. Titanium isodicyclopentadienide hemimetallocenes for ethylene/styrene copolymerization European Polymer Journal. 40: 2241-2246. DOI: 10.1016/J.Eurpolymj.2004.01.024  0.578
2004 Hartung RE, Hilmey DG, Paquette LA. Fluoride ion-promoted α-ketol rearrangement during unmasking of silyl-protected medium-ring dihydroxy ketones Advanced Synthesis and Catalysis. 346: 713-716. DOI: 10.1002/Adsc.200404002  0.799
2004 Hofferberth JE, Paquette LA. The α‐Hydroxy Ketone (α‐Ketol) and Related Rearrangements † Organic Reactions. 62: 477-567. DOI: 10.1002/0471264180.Or062.03  0.769
2003 Paquette LA, Fabris F, Gallou F, Dong S. C4'-spiroalkylated nucleosides having sulfur incorporated at the apex position. The Journal of Organic Chemistry. 68: 8625-34. PMID 14575495 DOI: 10.1021/jo030196w  0.623
2003 Paquette LA, Seekamp CK, Kahane AL. Conformational restriction of nucleosides by spirocyclic annulation at C4' including synthesis of the complementary dideoxy and didehydrodideoxy analogues. The Journal of Organic Chemistry. 68: 8614-24. PMID 14575494 DOI: 10.1021/Jo0301954  0.813
2003 Paquette LA, Hong FT. Total synthesis of dumsin. 1. Retrosynthetic strategy and the elaboration of key intermediates from (--)-bornyl acetate. The Journal of Organic Chemistry. 68: 6905-18. PMID 12946130 DOI: 10.1021/Jo0301346  0.391
2003 Paquette LA, Guevel R, Sakamoto S, Kim IH, Crawford J. Convergent enantioselective synthesis of vinigrol, an architecturally novel diterpenoid with potent platelet aggregation inhibitory and antihypertensive properties. 1. Application of anionic sigmatropy to construction of the octalin substructure. The Journal of Organic Chemistry. 68: 6096-107. PMID 12895037 DOI: 10.1021/Jo0301301  0.394
2003 Paquette LA, Shetuni BB, Gallucci JC. pi-Facial stereoselectivity in Diels-Alder cycloadditions to 1-oxaspiro[4.5]deca-6,9-dien-8-one. The strong directive effect of ether oxygen in a cross-conjugated ketone setting. Organic Letters. 5: 2639-42. PMID 12868878 DOI: 10.1021/Ol0347895  0.397
2003 Gallucci JC, Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. ansa-[(tert-Butylamino)(isodicyclopentadienyl)dimethylsilane]Zr(NMe2)2 prepared by an amine-elimination reaction. Acta Crystallographica. Section C, Crystal Structure Communications. 59: M109-11. PMID 12682383 DOI: 10.1107/S0108270103003172  0.614
2003 Paquette LA, Lo HY. Chemical modification of a highly functionalized taxane. The consequences of an absent bridgehead double bond on oxetane D-ring construction. The Journal of Organic Chemistry. 68: 2282-9. PMID 12636392 DOI: 10.1021/jo0206566  0.325
2003 Paquette LA, Lo HY, Hofferberth JE, Gallucci JC. A delicate balance of energetics. Subtleties associated with alpha-ketol-based bridge migration to afford 9-keto-10beta-p-methoxybenzyloxytaxanes. The Journal of Organic Chemistry. 68: 2276-81. PMID 12636391 DOI: 10.1002/CHIN.200326194  0.749
2003 Paquette LA, Hofferberth JE. Effect of 9,10-cyclic acetal stereochemistry on feasible operation of the alpha-ketol rearrangement in highly functionalized paclitaxel (Taxol) precursors. The Journal of Organic Chemistry. 68: 2266-75. PMID 12636390 DOI: 10.1021/jo020627v  0.734
2003 Paquette LA, Hartung RE, France DJ. Conversion of the enantiomers of spiro[4.4]nonane-1,6-diol into both epimeric carbaspironucleosides having natural C1' absolute configuration. Organic Letters. 5: 869-71. PMID 12633093 DOI: 10.1021/Ol0340033  0.804
2003 Guo X, Basu K, Cabral JA, Paquette LA. Relative rate profile for ring-closing metathesis of a series of 1-substituted 1,7-octadienes as promoted by a 4,5-dihydroimidazol-2-ylidene-coordinated ruthenium catalyst. Organic Letters. 5: 789-92. PMID 12633072 DOI: 10.1021/Ol0272794  0.612
2003 Paquette LA, Vilotijevic I, Hilmey D, Yang J. Divergent regioselectivity in the base-promoted reactions of cyclic eight-membered alpha-ketols with activated halides. Organic Letters. 5: 463-6. PMID 12583744 DOI: 10.1021/Ol027315Z  0.543
2003 Gallucci JC, Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. A doubly bridged isodicyclopentadienyl zirconium complex: bis[N-(3,5-dimethylphenyl)-N-[(eta5-isodicyclopentadien-2-yl)dimethylsilyl]amido-kappaN]zirconium(II) diethyl ether solvate. Acta Crystallographica. Section C, Crystal Structure Communications. 59: m67-9. PMID 12574651 DOI: 10.1107/S0108270103000751  0.597
2003 Yang J, Long YO, Paquette LA. Concise total syntheses of the bioactive mesotricyclic diterpenoids jatrophatrione and citlalitrione. Journal of the American Chemical Society. 125: 1567-74. PMID 12568617 DOI: 10.1021/Ja021177R  0.683
2003 Paquette LA, Kim IH, Cunière N. Zirconocene-mediated route to enantiopure 9-oxabicyclononanes functionalized on both carbon bridges. Organic Letters. 5: 221-3. PMID 12529145 DOI: 10.1021/Ol027336T  0.805
2003 Paquette LA, Webber P, Simpson I. Contrasting diastereofacial selectivity associated with N-phenyltriazolinedione cycloadditions to oxaspirocycloheptatrienes. Organic Letters. 5: 177-80. PMID 12529134 DOI: 10.1021/Ol020223P  0.366
2003 Gallucci JC, Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. ansa-[(tert-butylamino)(isodicyclopentadienyl)dimethylsilane]Zr(NMe2 )2 prepared by an amine-elimination reaction Acta Crystallographica Section C: Crystal Structure Communications. 59: m109-m111. DOI: 10.1107/S0108270103003172  0.598
2003 Gallucci JC, Gentil S, Pirio N, Meunier P, Gallou F, Paquette LA. A doubly bridged isodicyclopentadienyl zirconium complex: bis{N-(3,5-dimethylphenyl)-N-[(η5-isodicyclopentadien-2-yl) dimethylsilyl]amido-κN}zirconium(II) diethyl ether solvate Acta Crystallographica Section C: Crystal Structure Communications. 59: m67-m69. DOI: 10.1107/S0108270103000751  0.513
2003 Vilotijevic I, Yang J, Hilmey D, Paquette LA. Base-promoted ring contraction of eight-membered cyclic acyloins and their ethers to Cs-symmetric α-ketols Synthesis. 1872-1874. DOI: 10.1055/S-2003-41003  0.502
2003 Paquette LA. Fundamental mechanistic characteristics and synthetic applications of allylations promoted by indium metal in aqueous media Synthesis. 765-774. DOI: 10.1055/S-2003-38061  0.395
2003 Bennett GD, Paquette LA. Allylindation in Aqueous Media: Methyl 3‐(Hydroxymethyl)‐4‐Methyl‐2‐Methylenepentanoate Organic Syntheses. 107-107. DOI: 10.1002/0471264180.Os077.11  0.302
2003 Behrens C, Paquette LA. N‐Benzyl‐2,3‐Azetidinedione Organic Syntheses. 106-106. DOI: 10.1002/0471264180.Os075.13  0.344
2003 Dahnke KR, Paquette LA. Inverse Electron‐Demand Diels‐Alder Cycloaddition of a Ketene Dithioacetal. Copper Hydride‐Promoted Reduction of a Conjugated Enone. 9‐Dithiolanobicyclo[3.2.2]Non‐6‐En‐2‐One from Tropone Organic Syntheses. 181-181. DOI: 10.1002/0471264180.Os071.23  0.349
2003 Dahnke KR, Paquette LA. 2‐Methylene‐1,3‐Dithiolane Organic Syntheses. 175-175. DOI: 10.1002/0471264180.Os071.22  0.394
2003 Poupart M, Lassalle G, Paquette LA. Intramolecular Oxidative Coupling of a Bisenolate: 4‐Methyltricyclo[2.2.2.03,5]Octane‐2,6‐dione Organic Syntheses. 220-220. DOI: 10.1002/0471264180.Os068.27  0.397
2003 Lin H, Paquette LA. Reductive Annulation of Vinyl Sulfones: Bicyclo[4.3.0.]non‐1‐en‐4‐one Organic Syntheses. 163-163. DOI: 10.1002/0471264180.Os067.21  0.345
2003 Lin H, Coghlan MJ, Paquette LA. Dienophile Activation via Selenosulfonation: 1‐(Phenylsulfonyl)cyclopentene Organic Syntheses. 157-157. DOI: 10.1002/0471264180.Os067.20  0.311
2003 Paquette LA, Carr RVC. Phenyl Vinyl Sulfone and Sulfoxide Organic Syntheses. 157-157. DOI: 10.1002/0471264180.Os064.24  0.318
2003 Taylor RT, Paquette LA. 1,6‐Dimethyltricyclo[4.1.0.01,6]hept‐3‐ene Organic Syntheses. 39-39. DOI: 10.1002/0471264180.Os061.09  0.335
2003 Photis JM, Paquette LA. 1,2‐Dimethylcyclobutenes by Reductive Ring‐Contraction of Sulfolanes: cis‐7,8‐Dimethylbicyclo[4.2.0]oct‐7‐ene Organic Syntheses. 53-53. DOI: 10.1002/0471264180.Os057.14  0.324
2003 Paquette LA, Barrett JH. 2,7-Dimethyloxepin Organic Syntheses. 62-62. DOI: 10.1002/0471264180.Os049.17  0.422
2003 Paquette LA, Wittenbrook LS. 2‐Chlorothiirane 1,1‐dioxide Organic Syntheses. 18-18. DOI: 10.1002/0471264180.Os049.06  0.332
2003 Paquette LA. 1,3‐Dihydro‐3,5,7‐Trimethyl‐2H‐Azepin‐2‐One Organic Syntheses. 41-41. DOI: 10.1002/0471264180.Os044.13  0.33
2002 Paquette LA, Geng F. A highly abbreviated synthesis of pentalenene by means of the squarate ester cascade. Organic Letters. 4: 4547-9. PMID 12465934 DOI: 10.1021/Ol020208K  0.615
2002 Paquette LA, Geng F. Applications of the squarate ester cascade to the expeditious synthesis of hypnophilin, coriolin, and ceratopicanol. Journal of the American Chemical Society. 124: 9199-203. PMID 12149025 DOI: 10.1021/Ja020474T  0.614
2002 Paquette LA, Yang J, Long YO. Concerning the antileukemic agent jatrophatrione: the first total synthesis of a [5.9.5] tricyclic diterpene. Journal of the American Chemical Society. 124: 6542-3. PMID 12047168 DOI: 10.1021/Ja020292Z  0.649
2002 Paquette LA, Cunière N. Diastereoselectivity control in the zirconocene-mediated ring contraction of 4-vinylfuranosides to enantiopure multiply functionalized cyclobutanes. Organic Letters. 4: 1927-9. PMID 12027649 DOI: 10.1021/Ol020063H  0.813
2002 Paquette LA, Duan M, Konetzki I, Kempmann C. A convergent three-component total synthesis of the powerful immunosuppressant (-)-sanglifehrin a. Journal of the American Chemical Society. 124: 4257-70. PMID 11960455 DOI: 10.1021/Ja020091V  0.601
2002 Paquette LA, Peng X, Bondar D. Pectenotoxin-2 synthetic studies. 1. Alkoxide precoordination to [Rh(NBD)(DIPHOS-4)]BF(4) allows directed hydrogenation of a 2,3-dihydrofuran-3-ol without competing furan production. Organic Letters. 4: 937-40. PMID 11893190 DOI: 10.1021/Ol010302L  0.802
2002 Chang J, Paquette LA. Studies aimed at the total synthesis of the antitumor antibiotic cochleamycin A. An enantioselective biosynthesis-based pathway to the AB bicyclic core. Organic Letters. 4: 253-6. PMID 11796063 DOI: 10.1021/Ol0102592  0.509
2002 Geng F, Liu J, Paquette LA. Three-component coupling via the squarate ester cascade as a concise route to the bioactive triquinane sesquiterpene hypnophilin. Organic Letters. 4: 71-3. PMID 11772093 DOI: 10.1021/Ol0102388  0.6
2002 Cho IH, Paquette LA. Highly functionalized pyrans designed for multipoint side chain attachment to the F-ring sector of spongistatin 1 (altohyrtin A) Heterocycles. 58: 43-46. DOI: 10.3987/Com-01-S(M)6  0.58
2002 Efremov I, Paquette LA. A regioselective route to 2,3,4-trisubstituted furans Heterocycles. 56: 35-38. DOI: 10.3987/Com-00-S(K)2  0.747
2002 Paquette LA, Arbit RM, Funel JA, Bolshakov S. The carbohydrate-sesquiterpene interface. A zirconocene-mediated synthesis of (+)-epiafricanol from D-glucose Synthesis. 2105-2109. DOI: 10.1055/S-2002-34380  0.798
2002 Boulet SL, Paquette LA. Toward a total synthesis of okilactomycin. 2. A metathesis-based approach to the heavily functionalized cyclohexane ring Synthesis. 895-900. DOI: 10.1055/S-2002-28511  0.445
2002 Paquette LA, Boulet SL. Toward a total synthesis of okilactomycin. 1. A direct, enantiocontrolled route to the western sector Synthesis. 888-894. DOI: 10.1055/S-2002-28510  0.403
2002 Gentil S, Dietz M, Pirio N, Meunier P, Gallucci JC, Gallou F, Paquette LA. A silylene-bridged (isodicyclopentadienyl)(fluorenyl) complex of zirconium for homogeneous olefin polymerization Organometallics. 21: 5162-5166. DOI: 10.1021/Om020384X  0.607
2002 Basu K, Cabral JA, Paquette LA. Comparative investigation of kinetic consequences associated with long-range electronic effects on catalytic ruthenium-promoted ring-closing metathesis Tetrahedron Letters. 43: 5453-5456. DOI: 10.1016/S0040-4039(02)01064-X  0.623
2002 Horáček M, Štěpnička P, Gentil S, Fejfarová K, Kubišta J, Pirio N, Meunier P, Gallou F, Paquette LA, Mach K. Syntheses and properties of some exo,exo-bis(isodicyclopentadienyl)titanium low-valent complexes Journal of Organometallic Chemistry. 656: 81-88. DOI: 10.1016/S0022-328X(02)01562-0  0.608
2002 Paquette LA, Boggs RA, Ward JS. Silver(I) Ion Catalyzed Rearrangements Of Strained Sigma Bonds Part 30, Rhodium(I)- And Palladium(Ii)-Promoted Rearrangements Of Homocubanes, A Comparison Of Kinetic Reactivity And Product Distribution With Substituent Alteration Cheminform. 6. DOI: 10.1002/Chin.197520158  0.308
2002 Basu K, Eppich JC, Paquette LA. Ruthenium-promoted ring-closing metathesis of ene-dienes. Competitive intramolecular regioselection as a function of chain length Advanced Synthesis and Catalysis. 344: 615-618. DOI: 10.1002/1615-4169(200208)344:6/7<615::Aid-Adsc615>3.0.Co;2-O  0.631
2002 Paquette LA, Basu K, Eppich JC, Hofferberth JE. Systematic analysis of the intramolecular competition associated with the ring closing metathesis of ene-diene systems of differing chain length with a pair of ruthenium catalysts Helvetica Chimica Acta. 85: 3033-3051. DOI: 10.1002/1522-2675(200210)85:10<3033::Aid-Hlca3033>3.0.Co;2-2  0.787
2001 Paquette LA, Owen DR, Bibart RT, Seekamp CK. Spirocyclic restriction of nucleosides. An analysis of protecting group feasibility while accessing prototype anti-1-oxaspiro[4.4]nonanyl mimics. Organic Letters. 3: 4043-5. PMID 11735580 DOI: 10.1021/Ol010212G  0.808
2001 Paquette LA, Bibart RT, Seekamp CK, Kahane AL. Spirocyclic restriction of nucleosides. Synthesis of the first exemplary syn-1-oxaspiro[4.4]nonanyl member. Organic Letters. 3: 4039-41. PMID 11735579 DOI: 10.1021/Ol010209X  0.809
2001 Paquette LA, Ra CS, Gallucci JC, Kang HJ, Ohmori N, Arrington MP, David W, Brodbelt JS. Constraining of small-ring cyclic ether triads by stereodefined spiroannulation to an inositol orthoformate platform. Solution- and gas-phase alkali metal binding affinities for three- to five-membered ring structural combinations. The Journal of Organic Chemistry. 66: 8629-39. PMID 11735548 DOI: 10.1021/Jo0107507  0.305
2001 Duan M, Paquette LA. Enantioselective Total Synthesis of the Cyclophilin-Binding Immunosuppressive Agent Sanglifehrin A This work was financially supported by Eli Lilly and Company and a Robert Mayer Graduate Fellowship (to M.D.). We thank Prof. K. C. Nicolaou for providing authentic spectra of 1. Angewandte Chemie (International Ed. in English). 40: 3632-3636. PMID 11592204 DOI: 10.1002/1521-3773(20011001)40:19<3632::Aid-Anie3632>3.0.Co;2-5  0.551
2001 Balskus EP, Méndez-Andino J, Arbit RM, Paquette LA. Intercalation of multiple carbon atoms between the carbonyls of alpha-diketones. The Journal of Organic Chemistry. 66: 6695-704. PMID 11578223 DOI: 10.1021/Jo010494Y  0.825
2001 Bernardelli P, Moradei OM, Friedrich D, Yang J, Gallou F, Dyck BP, Doskotch RW, Lange T, Paquette LA. Total asymmetric synthesis of the putative structure of the cytotoxic diterpenoid (-)-sclerophytin a and of the authentic natural sclerophytins A and B. Journal of the American Chemical Society. 123: 9021-32. PMID 11552810 DOI: 10.1021/Ja011285Y  0.734
2001 Paquette LA, Efremov I. Teubrevin G and teubrevin H: the first total syntheses of rearranged neo-clerodanes including solutions to the problems of chirality merger and furan ring assembly. Journal of the American Chemical Society. 123: 4492-501. PMID 11457235 DOI: 10.1021/Ja010313+  0.78
2001 Gallou F, MacMillan DW, Overman LE, Paquette LA, Pennington LD, Yang J. Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol. Organic Letters. 3: 135-7. PMID 11429857 DOI: 10.1021/Ol000345M  0.684
2001 Hofferberth JE, Lo HY, Paquette LA. Stereospecific anionically promoted transannular hydride shifts in medium-ring hydroxy ketones. Probe of their reversibility and the potential for regiocontrol. Organic Letters. 3: 1777-80. PMID 11405709 DOI: 10.1021/Ol0100733  0.754
2001 Paquette LA, Ra CS, Schloss JD, Leit SM, Gallucci JC. Direct synthesis of previously inaccessible bridgehead azabicyclics by intramolecular cyclization of alpha-sulfonamido and alpha-sulfonimido radicals. The Journal of Organic Chemistry. 66: 3564-73. PMID 11348146 DOI: 10.1021/Jo010216Z  0.822
2001 Paquette LA, Owen DR, Bibart RT, Seekamp CK, Kahane AL, Lanter JC, Corral MA. 1-Oxaspiro[4.4]nonan-6-ones. Synthetic access via oxonium ion technology, optical resolution, and conversion into enantiopure spirocyclic alpha,beta-butenolides. The Journal of Organic Chemistry. 66: 2828-34. PMID 11304208 DOI: 10.1021/Jo010026O  0.792
2001 Paquette LA, Méndez-Andino J. Synthesis of paddlanes having a bicyclo[1.1.1]pentane core. The consequences of olefin metathesis involving unsaturated 1,3-dicarboxylate esters of varying chain length Tetrahedron Letters. 42: 967-970. DOI: 10.1016/S0040-4039(00)02212-7  0.383
2001 Duan M, Paquette LA. Enantioselective Total Synthesis of the Cyclophilin-Binding Immunosuppressive Agent Sanglifehrin A Angewandte Chemie. 113: 3744-3748. DOI: 10.1002/1521-3757(20011001)113:19<3744::Aid-Ange3744>3.0.Co;2-B  0.499
2000 Rablen PR, Paquette LA, Borden WT. Why Doesn't all-trans-1,2,3,4,5,6-Hexaspiro(THF)cyclohexane complex metal ions? The Journal of Organic Chemistry. 65: 9180-5. PMID 11149867 DOI: 10.1021/Jo001432V  0.324
2000 Paquette LA, Tae J, Branan BM, Bolin DG, Eisenberg SW. Synthesis and conformational properties of several maximally substituted hexa(spirotetrahydrofuranyl)cyclohexanes. Assessment Of the pronounced bias of the all-trans D(3)(d)()-symmetric isomer for total equatorial oxygen occupancy The Journal of Organic Chemistry. 65: 9172-9. PMID 11149866 DOI: 10.1021/Jo0014313  0.394
2000 Paquette LA, Tae J, Hickey ER, Trego WE, Rogers RD. Preorganized ligand arrays based on spirotetrahydrofuranyl motifs. Synthesis of the stereoisomeric 1,8,14-trioxatrispiro[4.1.4.1.4. 1]octadecanes and the contrasting conformational features and ionic binding capacities of these belted ionophores. The Journal of Organic Chemistry. 65: 9160-71. PMID 11149865 DOI: 10.1021/Jo001430A  0.349
2000 Schloss JD, Leit SM, Paquette LA. Radical and anionic response of N-(Bromomethanesulfonyl)-substituted alpha,alpha'-bridged piperidine substrates The Journal of Organic Chemistry. 65: 7119-23. PMID 11031038 DOI: 10.1021/Jo000873B  0.798
2000 Paquette LA, Moradei OM, Bernardelli P, Lange T. Synthesis of the alleged structure of sclerophytin A. The setting of two oxygen bridges within the fused cyclodecanol B ring is not Nature's Way. Organic Letters. 2: 1875-8. PMID 10891180 DOI: 10.1021/Ol000083O  0.353
2000 Paquette LA, Ohmori N, Lowinger TB, Rogers RD. Vicinal tetrahydrofuranyl substitution of alkyl chains. Tetra-, penta-, and hexafunctionalized arrays. The Journal of Organic Chemistry. 65: 4303-8. PMID 10891130 DOI: 10.1021/Jo0001075  0.395
2000 Zuev D, Paquette LA. A modular approach to marine macrolide construction. 3. Enantioselective synthesis of the C1-C28 sector of spongistatin 1 (altohyrtin A). Organic Letters. 2: 679-82. PMID 10814408 DOI: 10.1021/Ol0000049  0.717
2000 Mendez-Andino J, Paquette LA. Tandem deployment of indium-, ruthenium-, and lead-promoted reactions. Four-carbon intercalation between the carbonyl groups of open-chain and cyclic alpha-diketones Organic Letters. 2: 1263-5. PMID 10810723 DOI: 10.1021/Ol000037O  0.362
2000 Paquette LA, Schloss JD, Efremov I, Fabris F, Gallou F, Mendez-Andino J, Yang J. A convenient method for removing all highly-colored byproducts generated during olefin metathesis reactions Organic Letters. 2: 1259-61. PMID 10810722 DOI: 10.1021/Ol000036W  0.801
2000 Cunière N, Paquette LA. The case for noncompetitive cyclizative options during attempted expedient construction of the core ring system of CP-263,114 Arkivoc. 2000: 274-281. DOI: 10.3998/Ark.5550190.0001.311  0.822
2000 Gentil S, Pirio N, Meunier P, Gallucci JG, Schloss JD, Paquette LA. Stereoselective access to new half-sandwich complexes containing an isodicyclopentadienyl ligand Organometallics. 19: 4169-4172. DOI: 10.1021/Om000472M  0.779
2000 Schloss JD, Leit SM, Paquette LA. Radical and anionic response of N-(bromomethanesulfonyl)-substituted α,α'-bridged piperidine substrates Journal of Organic Chemistry. 65: 7119-7123. DOI: 10.1021/jo000873b  0.771
2000 Paquette LA, Fabris F, Tae J, Gallucci JC, Hofferberth JE. Catalytic ring-closing metathesis of doubly armed, bridged bicyclic sulfones. Evaluation of chain length and possible intramolecular SO2 group ligation to the ruthenium carbenoid Journal of the American Chemical Society. 122: 3391-3398. DOI: 10.1021/Ja9943849  0.772
2000 Paquette LA, Zhao Z, Gallou F, Liu J. New photorearrangements of 2-cyclopentenones. The genesis and fate of cyclopropylcarbinyl biradical intermediates [1] Journal of the American Chemical Society. 122: 1540-1541. DOI: 10.1021/Ja994081E  0.603
2000 Paquette LA, Tae J, Arrington MP, Sadoun AH. Enantioselective double Michael addition/cyclization with an oxygen- centered nucleophile as the first step in a concise synthesis of natural (+)- asteriscanolide Journal of the American Chemical Society. 122: 2742-2748. DOI: 10.1021/Ja994053W  0.437
2000 Paquette LA, Barriault L, Pissarnitski D, Johnston JN. Stereocontrolled elaboration of natural (-)-polycavernoside A, a powerfully toxic metabolite of the red alga Polycavernosa tsudai Journal of the American Chemical Society. 122: 619-631. DOI: 10.1021/Ja993487O  0.761
2000 Paquette LA, Reddy YR, Vayner G, Houk KN. High-rate accelerations in oxy-Cope rearrangements induced by sulfur substitution: Kinetic study involving electronically and geometrically differentiated 1-alkenyl-2-(Z-1-propenyl)-7,7-dimethyl-exo-norbornan-2-ols Journal of the American Chemical Society. 122: 10788-10794. DOI: 10.1021/Ja0025402  0.349
2000 Efremov I, Paquette LA. First synthesis of a rearranged neo-clerodane diterpenoid. Development of totally regioselective trisubstituted furan ring assembly and medium-ring alkylation tactics for efficient access to (-)-teubrevin G [15] Journal of the American Chemical Society. 122: 9324-9325. DOI: 10.1021/Ja002450X  0.382
2000 Paquette LA, Gallou F, Zhao Z, Young DG, Liu J, Yang J, Friedrich D. Propensity of 4-methoxy-4-vinyl-2-cyclopentenones housed in tri- and Tetracyctic frameworks for deep-seated photochemical rearrangement Journal of the American Chemical Society. 122: 9610-9620. DOI: 10.1021/Ja001813Q  0.699
2000 Duan M, Paquette LA. Highly diastereocontrolled synthesis of the C1-C25 domain of sanglifehrin A Tetrahedron Letters. 41: 3789-3792. DOI: 10.1016/S0040-4039(00)00504-9  0.561
2000 Paquette L, Zeng Q, Wang H, Shih T. From Carbohydrates to the Discovery of Pronounced Heteroatomic Effects on Anionically Accelerated [3,3]-Sigmatropic Rearrangements European Journal of Organic Chemistry. 2000: 2187-2194. DOI: 10.1002/1099-0690(200006)2000:12<2187::Aid-Ejoc2187>3.0.Co;2-2  0.408
2000 Gallou F, Rigby JH, Paquette LA, Warshakoon NC, Payen AJ, Fales KR, Pigge CF. [6π + 2π] and [6π + 4π] higher-order cycloadditions and their deployment in total synthesis Chemtracts. 13: 223-228.  0.568
2000 Yamazaki T, Kuboki A, Ohta H, Mitzel TM, Paquette LA, Sugai T. Yamadazyma farinosa IFO 10896-mediated reduction of 4,4-dimethoxy-2- butanone as the key-step for the preparation of 1,3-diols with unsymmetrical substituents Synthetic Communications. 30: 3061-3072.  0.787
2000 Long YO, Paquette LA. Non-enzymatic kinetic resolution of racemic alcohols with chiral catalysts Chemtracts. 13: 1-8.  0.409
1999 Paquette LA, Tae J, Branan BM, Eisenberg SWE, Hofferberth JE. Synthesis and Conformational Properties of the Sterically Crowded D -Symmetric all-trans Hexa(spirotetrahydrofuranyl)cyclohexane System. Angewandte Chemie (International Ed. in English). 38: 1412-1414. PMID 29711563 DOI: 10.1002/(Sici)1521-3773(19990517)38:10<1412::Aid-Anie1412>3.0.Co;2-X  0.746
1999 Paquette LA, Edmondson SD, Monck N, Rogers RD. Studies Directed toward the Synthesis of the Unusual Antileukemic Diterpene Jatrophatrione. 2. Functionalization of Advanced Polycyclic Precursors to the 9-Epi and 8,9-Dehydro Congeners. The Journal of Organic Chemistry. 64: 3255-3265. PMID 11674428 DOI: 10.1021/Jo982526W  0.316
1999 Paquette LA, Nakatani S, Zydowsky TM, Edmondson SD, Sun LQ, Skerlj R. Studies Directed toward the Synthesis of the Unusual Antileukemic Diterpene Jatrophatrione. 1. A Solution to the Problem of Chirality Merger during Elaboration of the Entire Carbotricyclic Framework. The Journal of Organic Chemistry. 64: 3244-3254. PMID 11674427 DOI: 10.1021/Jo9825254  0.418
1999 Paquette LA, Brand S, Behrens C. An Enantioselective Ring Expansion Route Leading to Furanose and Pyranose Nucleosides Featuring Spirodiketopiperazines at the Anomeric Position. The Journal of Organic Chemistry. 64: 2010-2025. PMID 11674296 DOI: 10.1021/Jo982259U  0.419
1999 Paquette LA, Rothhaar RR. Competitive Intramolecular/Intermolecular Chelation Options Operative during Indium-Promoted Additions to Pyridyl Aldehydes and to Glyoxylic Acid under Aqueous Conditions. The Journal of Organic Chemistry. 64: 217-224. PMID 11674106 DOI: 10.1021/Jo981717W  0.388
1999 Barriault L, Boulet SL, Fujiwara K, Murai A, Paquette LA, Yotsu-Yamashita M. Synthesis and biological evaluation of analogs of the marine toxin polycavernoside A. Bioorganic & Medicinal Chemistry Letters. 9: 2069-72. PMID 10450983 DOI: 10.1016/S0960-894X(99)00341-8  0.635
1999 Zeng Q, Paquette LA. Selective Acylation Reactions of an Isotaxane Tetraol. A Direct Pathway to Introduction of the Oxetane Ring Synlett. 1999: 1547-1550. DOI: 10.1055/S-1999-2911  0.37
1999 Gobley O, Gentil S, Schloss JD, Rogers RD, Gallucci JC, Meunier P, Gautheron B, Paquette LA. Magnesiation of isodicyclopentadiene. Formation of sandwich and monomeric complexes and the stereoselectivity of their reactions with transition metal halides Organometallics. 18: 2531-2535. DOI: 10.1021/Om990200N  0.787
1999 Paquette LA, Brand S, Behrens C. An enantioselective ring expansion route leading to furanose and pyranose nucleosides featuring spirodiketopiperazines at the anomeric position Journal of Organic Chemistry. 64: 2010-2025. DOI: 10.1021/jo982259u  0.326
1999 Paquette LA, Barriault L, Pissarnitski D. A convergent total synthesis of the macrolactone disaccharide toxin (- )-polycavernoside A Journal of the American Chemical Society. 121: 4542-4543. DOI: 10.1021/Ja990384X  0.655
1999 Paquette LA, Konetzki I, Duan M. Synthesis of the tripeptide (C1-N12) and hydroxylated hexadecene (C26-C41) domains of sanglifehrin A and C Tetrahedron Letters. 40: 7441-7444. DOI: 10.1016/S0040-4039(99)01539-7  0.517
1999 Paquette LA, Jinsung T. A head-to-head comparison of α- and β-alkoxy effects on stereoselectivity. Nucleophilic additions to a cyclohexanone substituted with five axial C-O bonds Tetrahedron Letters. 40: 5971-5974. DOI: 10.1016/S0040-4039(99)01167-3  0.335
1999 Paquette LA, Usui S. Tandem use of reductive and radical cyclization protocols in an approach to the first σ-allyl cation Tetrahedron Letters. 40: 3499-3502. DOI: 10.1016/S0040-4039(99)00541-9  0.38
1999 Paquette LA, Tae J, Branan BM, Eisenberg SWE, Hofferberth JE. Synthesis and conformational properties of the sterically crowded D(3d)- symmetric all-trans hexa(spirotetrahydrofuranyl)cyclohexane system Angewandte Chemie - International Edition. 38: 1412-1414. DOI: 10.1002/(SICI)1521-3773(19990517)38:10<1412::AID-ANIE1412>3.0.CO;2-X  0.7
1999 Paquette LA, Tae J, Branan BM, Eisenberg SWE, Hofferberth JE. Synthese und konformative Eigenschaften des sterisch überladenen,D3d-symmetrischen all-trans-Hexa(spirotetrahydrofuranyl)cyclohexans Angewandte Chemie. 111: 1505-1507. DOI: 10.1002/(Sici)1521-3757(19990517)111:10<1505::Aid-Ange1505>3.0.Co;2-Q  0.725
1999 Zuev D, Bender JA, Paquette LA, Blize AE, Browder CC, Giese S, West FG, Wang Y, Arif AM. First examples of the interrupted Nazarov reaction Chemtracts. 12: 1019-1025.  0.666
1998 Zeng Q, Bailey S, Wang TZ, Paquette LA. Bicyclic Systems Related to Taxol. A Direct Means for Implementing C-2 Oxygenation and Demonstration of the Feasibility of alpha-Ketol Equilibration in a Fully Oxygenated B-Ring Setting. The Journal of Organic Chemistry. 63: 137-143. PMID 11674054 DOI: 10.1021/Jo971592F  0.337
1998 Johnston JN, Tsui HC, Paquette LA. Application of an S --> O Allylic Transposition in the Context of a Bridgehead Olefinic System. New Opportunities for the Structural Modification of Bicyclo[6.2.1]undecanes via Transannular Ring Closure. The Journal of Organic Chemistry. 63: 129-136. PMID 11674053 DOI: 10.1021/Jo971591N  0.623
1998 Paquette LA, Pissarnitski D, Barriault L. A Modular Enantioselective Approach to Construction of the Macrolactone Core of Polycavernoside A. The Journal of Organic Chemistry. 63: 7389-7398. PMID 11672388 DOI: 10.1021/Jo981083T  0.653
1998 Paquette LA. Studies Directed to the Synthesis of the Antifungal Antibiotic Aleurodiscal. Enantioselective Construction of an Advanced β-d-Xyloside Congener Synthesis. 1998: 495-508. DOI: 10.1055/S-1998-5921  0.305
1998 Gobley O, Meunier P, Gautheron B, Gallucci JC, Erker G, Dahlmann M, Schloss JD, Paquette LA. Some Newexo,exo-Bis(isodicyclopentadienyl)titanium and -zirconium Dichloride Derivatives:  Synthesis, Characterization, and Evaluation as Propene Polymerization Catalysts Organometallics. 17: 4897-4903. DOI: 10.1021/Om980542D  0.792
1998 Tsui HC, Paquette LA. Reversible charge-accelerated oxy-cope rearrangements Journal of Organic Chemistry. 63: 9968-9977. DOI: 10.1021/Jo982002W  0.311
1998 Paquette LA, Zeng Q, Tsui HC, Johnston JN. Stereochemical models for the enantiocontrolled construction of fully functionalized C rings via intramolecular aldolization in advanced precursors to paclitaxel Journal of Organic Chemistry. 63: 8491-8509. DOI: 10.1021/Jo981749J  0.623
1998 Paquette LA, Wang H, Zeng Q, Shih T. Heteroatomic Modulation of Oxyanionic Cope Rearrangement Rates. Consequences on Competing Nucleophilic Cleavage of an Oxetane Ring in Precursors to Paclitaxel Journal of Organic Chemistry. 63: 6432-6433. DOI: 10.1021/Jo981059F  0.353
1998 Paquette LA, Bolin DG, Stepanian M, Branan BM, Mallavadhani UV, Tae J, Eisenberg SWE, Rogers RD. Intramolecular Oxymercuration of Stereoisomeric Cyclohexyl-Belted Poly(spirotetrahydrofuranyl) Platforms Journal of the American Chemical Society. 120: 11603-11615. DOI: 10.1021/Ja981756P  0.328
1998 Paquette LA, Dyck BP. Studies Directed toward the Total Synthesis of Cerorubenic Acid-III. 5. A Radical Cyclization Route Leading to the Methyl Ester of the Natural Isomer1 Journal of the American Chemical Society. 120: 5953-5960. DOI: 10.1021/Ja980691N  0.411
1998 Paquette LA, Wang H, Su Z, Zhao M. Enantiospecific Total Synthesis of Natural (+)-Taxusin. 2. Functionalization of the A-Ring and Arrival at the Target Journal of the American Chemical Society. 120: 5213-5225. DOI: 10.1021/Ja980538T  0.427
1998 Paquette LA, Zhao M. Enantiospecific Total Synthesis of Natural (+)-Taxusin. 1. Retrosynthesis, Advancement to Diastereomeric trans-Δ9,10-Tricyclic Olefinic Intermediates, and the Stereocontrol Attainable Because of Intrinsic Rotational Barriers Therein Journal of the American Chemical Society. 120: 5203-5212. DOI: 10.1021/Ja9805371  0.473
1998 Paquette LA, Collado I, Purdie M. Total Synthesis of Spinosyn A. 2. Degradation Studies Involving the Pure Factor and Its Complete Reconstitution Journal of the American Chemical Society. 120: 2553-2562. DOI: 10.1021/Ja974010K  0.406
1998 Paquette LA, Gao Z, Ni Z, Smith GF. Total Synthesis of Spinosyn A. 1. Enantioselective Construction of a Key Tricyclic Intermediate by a Multiple Configurational Inversion Scheme Journal of the American Chemical Society. 120: 2543-2552. DOI: 10.1021/Ja974009L  0.404
1997 Bernardelli P, Paquette LA. Stereoselective Indium-Promoted Allylation of gamma-Hydroxy-gamma-Lactones under Aqueous Conditions. The Neighboring Carboxyl Effect. The Journal of Organic Chemistry. 62: 8284-8285. PMID 11671959 DOI: 10.1021/Jo9716800  0.784
1997 Paquette LA, Mitzel TM, Isaac MB, Crasto CF, Schomer WW. Diastereoselection during 1,2-Addition of the Allylindium Reagent to alpha-Thia and alpha-Amino Aldehydes in Aqueous and Organic Solvents. The Journal of Organic Chemistry. 62: 4293-4301. PMID 11671749 DOI: 10.1021/Jo970274D  0.781
1997 Morwick TM, Paquette LA. Combined Addition of Alkenyl and Allenic Anions to Squarate Esters. Direct Competition between Six-Ring and Eight-Ring Electrocyclization of 1,2,4,6,8-Cumulenic Pentaenes. The Journal of Organic Chemistry. 62: 627-635. PMID 11671456 DOI: 10.1021/Jo961945V  0.415
1997 Paquette LA, Kuo LH, Hamme AT, Kreuzholz R, Doyon J. Sensitivity of Substitution to the Extent of Self-Immolative Chirality Transfer during Reaction Cascades Originating from Squarate Esters The Journal of Organic Chemistry. 62: 1730-1736. DOI: 10.1021/Jo962182E  0.399
1997 Paquette LA, Kuo LH, Doyon J. Enhanced Channeling of the Squarate Cascade through the Dianionic Oxy-Cope Option. Oxy Substitution Markedly Augments Syn Delivery of the Second Alkenyllithium Journal of the American Chemical Society. 119: 3038-3047. DOI: 10.1021/Ja964140D  0.337
1997 Paquette LA, Hamme AT, Kuo LH, Doyon J, Kreuzholz R. Probe of the Stereochemically Determining Step in Squarate Ester Cascades. Proof that Helical Equilibration within the Octatetraene Intermediate Is Responsible and Definition of Steric Control Elements Journal of the American Chemical Society. 119: 1242-1253. DOI: 10.1021/Ja9632163  0.4
1997 Paquette LA, Zuev D. A modular approach to marine macrolide construction. 1. An enantiocontrolled route to the C1–C12 (AB) spiroacetal sector Tetrahedron Letters. 38: 5115-5118. DOI: 10.1016/S0040-4039(97)01140-4  0.695
1996 Paquette LA, Mitzel TM. Comparative Diastereoselectivity Analysis of Crotylindium and 3-Bromoallylindium Additions to alpha-Oxy Aldehydes in Aqueous and Nonaqueous Solvent Systems. The Journal of Organic Chemistry. 61: 8799-8804. PMID 11667857  0.775
1996 Paquette LA, Stepanian M, Mallavadhani UV, Cutarelli TD, Lowinger TB, Klemeyer HJ. Definition of Several Control Elements Relevant to the Stereodefined Serial Elaboration of Belted Poly(spirotetrahydrofurans) Fitted with a Cyclohexane Core. The Journal of Organic Chemistry. 61: 7492-7507. PMID 11667680 DOI: 10.1021/Jo960962H  0.349
1996 Paquette LA, Lowinger TB, Bolin DG, Branan BM. trans,anti,trans-Tetra(spirotetrahydrofuranyl)cyclohexane-1,2-dione. Stereocontrolled Synthesis and Definition of Its Susceptibility to Photoisomerization. The Journal of Organic Chemistry. 61: 7486-7491. PMID 11667679 DOI: 10.1021/Jo960961P  0.367
1996 Paquette LA, Doussot P. New Transformations Involving Squarate Esters. Multi-Channel Rearrangement Options Available To 2-(Dimethoxy-Methyl)-1-Cycloalken-1-Yl Adducts‡ Research On Chemical Intermediates. 22: 767-780. DOI: 10.1163/156856796X00313  0.402
1996 Landmesser NG, Tsui H, King CR, Paquette LA. Regiocontrolled C-8 Acylation of Castanospermine Synthetic Communications. 26: 2213-2221. DOI: 10.1080/00397919608003581  0.39
1996 Sivik MR, Bauer W, Schleyer PvR, Paquette LA. (1S,2S,9R,10R)-Tetracyclo[8.2.1.02,9.03,7]trideca-3,6-dienyllithium. Tentative Evidence for a Quinternary Equilibrium Involving a Cyclopentadienide Ion Organometallics. 15: 5202-5208. DOI: 10.1021/Om960533+  0.33
1996 Paquette LA, Bzowej EI, Kreuzholz R. Optically Pure C2-Symmetric Transition Metal Complexes. Steric Consequences of Flanking the Cyclopentadienyl Anion with a Pair of Bridged Bicyclic Terpene-Derived Hydrocarbon Subunits Organometallics. 15: 4857-4862. DOI: 10.1021/Om960391J  0.398
1996 Morwick TM, Paquette LA. Mapping The Chemical Reactivity Of Polyquinanes Produced By 2-Fold Addition Of Vinyl Anions To Squarate Esters. A Bicyclic Case Study Journal of Organic Chemistry. 61: 146-152. DOI: 10.1021/Jo9516751  0.416
1996 Wang TZ, Pinard E, Paquette LA. Asymmetric synthesis of the diterpenoid marine toxin (+)-acetoxycrenulide Journal of the American Chemical Society. 118: 1309-1318. DOI: 10.1021/Ja9533609  0.41
1996 Paquette LA, Doyon J, Lung Huang K. Sequenced reactions involving squarate esters. The first suggestion that helical equilibration within the advanced octatetraene intermediate is responsible for stereochemical control Tetrahedron Letters. 37: 3299-3302. DOI: 10.1016/0040-4039(96)00580-1  0.363
1996 Paquette LA, Kuo LH, Doyon J. Reaction cascades based on squarate esters. 1,3-Dioxolane as a chaperone functional group for lithium ions Tetrahedron. 52: 11625-11636. DOI: 10.1016/0040-4020(96)00644-8  0.359
1995 Paquette LA, Branan BM. Isomerizations of 1,7-Diheteradispiro[4.0.4.4]tetradeca-11,13-dienes in the Presence of Tetracyanoethylene Heterocycles. 40: 101. DOI: 10.3987/Com-94-S19  0.398
1995 Wilson PD, Friedrich D, Paquette LA. Successive electrocyclic rearrangements initiated by the addition of a lithiated cyclopropenone acetal to a squarate ester Journal of the Chemical Society, Chemical Communications. 1351-1352. DOI: 10.1039/C39950001351  0.417
1995 Mach K, Hiller J, Thewalt U, Sivik MR, Bzowej EI, Paquette LA, Zaegel F, Meunier P, Gautheron B. Stereoselective Redox Reaction Of Isodicyclopentadiene With The Bis(Tetrachloroaluminato)(Benzene)Titanium(Ii) Complex Organometallics. 14: 2609-2612. DOI: 10.1021/Om00005A072  0.328
1995 Paquette LA, Montgomery FJ, Wang T. An Abbreviated, Highly Stereocontrolled Route to Precursors of Taxol. Elaboration of a Fully Functionalized C Ring by Means of Intramolecular Aldol Cyclization Journal of Organic Chemistry. 60: 7857-7864. DOI: 10.1021/Jo00129A027  0.433
1995 Paquette LA, Bailey S. Evaluation of D-Ribose as an Enantiopure Building Block for Construction of the C-Ring of Taxol and Its Congeners The Journal of Organic Chemistry. 60: 7849-7856. DOI: 10.1021/Jo00129A026  0.321
1995 Paquette LA, Borrelly S. Studies Directed Toward The Total Synthesis Of Kalmanol. An Approach To Construction Of The C/D Diquinane Substructure Journal of Organic Chemistry. 60: 6912-6921. DOI: 10.1021/Jo00126A049  0.338
1995 Paquette LA, Hormuth S, Lovely CJ. Studies Directed toward the Total Synthesis of Cerorubenic Acid-III. 4. Exploration of an Organometallic Approach to Construction of the Eastern Sector Journal of Organic Chemistry. 60: 4813-4821. DOI: 10.1021/Jo00120A026  0.611
1995 Paquette LA, Su Z, Bailey S, Montgomery FJ. Evaluation of 2-Bromocyclohexenone Acetals as Vehicles for the Introduction of C-7 Oxygen Preliminary to the Synthesis of Taxane Diterpenes The Journal of Organic Chemistry. 60: 897-902. DOI: 10.1021/Jo00109A021  0.31
1995 Elmore SW, Paquette LA. Stereocontrolled Oxygenation of Camphor Derivatives as a Prelude to the Complete .beta.-Ring Functionalization of Potential Precursors to Taxol and Structural Analogs Thereof Journal of Organic Chemistry. 60: 889-896. DOI: 10.1021/Jo00109A020  0.322
1995 Detert H, Lanter JC, Paquette LA. Weiss-Cook Condensations Involving Unsaturated And Transannularly Alkylated Cyclododecane-1,2-Diones Journal of Organic Chemistry. 60: 353-356. DOI: 10.1021/Jo00107A013  0.383
1995 Lord MD, Negri JT, Paquette LA. Oxonium Ion-Initiated Pinacolic Ring Expansion Reactions. Application To The Enantioselective Synthesis Of The Spirocyclic Sesquiterpene Ethers Dactyl Oxene-B And -C Journal of Organic Chemistry. 60: 191-195. DOI: 10.1021/Jo00106A033  0.423
1995 Paquette LA, Morwick T. The Squarate Ester-1,3,5,7-Octatetraene-Polyquinane Cascade: Reaction Efficiency Is Intimately Linked to the Locus of Substitution within the Vinyl Anion Journal of the American Chemical Society. 117: 1451-1452. DOI: 10.1021/Ja00109A039  0.41
1994 Lin H, Paquette LA. A Convenient Method for Determining the Concentration of Grignard Reagents Synthetic Communications. 24: 2503-2506. DOI: 10.1080/00397919408010560  0.305
1994 Klemeyer HJ, Paquette LA. Consequences of .alpha.-Bromo Substitution on the Course of Allylmetal Additions to 1-Oxaspiro[4.5]dec-7-en-6-one Journal of Organic Chemistry. 59: 7924-7927. DOI: 10.1021/Jo00104A062  0.327
1994 Branan BM, Paquette LA. In Quest of Tricyclo[4.4.1.04,11]undeca-1,3,5,7,9-pentaene, a Highly Strained, Cyclic 10.pi.-Electron, Polyunsaturated Hydrocarbon. Synthesis of a Methoxyl-Substituted Dihydro Derivative Journal of Organic Chemistry. 59: 7709-7713. DOI: 10.1021/Jo00104A029  0.33
1994 Paquette LA, Wang X. Total Synthesis of 18-Oxo-3-virgene, a Constituent of the Waxy Surface Resins of Tobacco The Journal of Organic Chemistry. 59: 2052-2057. DOI: 10.1021/Jo00087A019  0.368
1994 Houk KN, Li Y, McAllister MA, O'Doherty G, Paquette LA, Siebrand W, Smedarchina ZK. Mechanistic Analysis of Double Hydrogen Dyotropy in syn-Sesquinorbornene Disulfones. A Combined Kinetic and Theoretical Evaluation of Primary Deuterium Isotope Effects Journal of the American Chemical Society. 116: 10895-10913. DOI: 10.1021/Ja00103A005  0.528
1994 O'Doherty GA, Rogers RD, Paquette LA. Consequences of Modulated Precompression along Reaction Coordinates. Synthesis, Crystallographic Structural Studies, and Rate of Intramolecular Dyotropy in an Extended Series of syn-Sesquinorbornene Disulfones Journal of the American Chemical Society. 116: 10883-10894. DOI: 10.1021/Ja00103A004  0.604
1994 Williams JP, St. Laurent DR, Friedrich D, Pinard E, Roden BA, Paquette LA. Total synthesis of the Lycopodium alkaloids magellanine and magellaninone by three-fold annulation of 2-cyclopentenone Journal of the American Chemical Society. 116: 4689-4696. DOI: 10.1021/Ja00090A017  0.356
1993 Paquette LA, Deaton DN, Endo Y, Poupart MA. Studies directed toward the total synthesis of cerorubenic acid-III. 3. A convergent enantioselective approach involving new arrangements for the actuation of ring D cyclization The Journal of Organic Chemistry. 58: 4262-4273. DOI: 10.1021/Jo00068A021  0.411
1993 Paquette LA, Lassalle GY, Lovely CJ. Studies directed toward the total synthesis of cerorubenic acid-III. 2. Analysis of the inability to realize D ring formation by means of extraannular Robinson annulation Journal of Organic Chemistry. 58: 4254-4261. DOI: 10.1021/Jo00068A020  0.662
1993 Paquette LA, Poupart MA. Studies directed toward the total synthesis of cerorubenic acid-III. 1. Expedient construction of the tetracyclic core by oxyanionic sigmatropy Journal of Organic Chemistry. 58: 4245-4253. DOI: 10.1021/Jo00068A019  0.442
1993 Paquette LA, Astles PC. Total synthesis of furanocembranolides. 3. A concise convergent route to acerosolide Journal of Organic Chemistry. 58: 165-169. DOI: 10.1021/Jo00053A031  0.35
1993 Negri J, Morwick T, Doyon J, Wilson PD, Hickey ER, Paquette LA. Direct elaboration of complex polyquinanes through twofold addition of vinyl anions to squarate esters Journal of the American Chemical Society. 115: 12189-12190. DOI: 10.1021/Ja00078A077  0.326
1993 Paquette LA, Wang TZ, Huu VN. Access to naturally occurring cyclooctanoids by two-carbon intercalation. Total synthesis of (+)-ceroplastol I Journal of the American Chemical Society. 115: 1676-1683. DOI: 10.1021/Ja00058A011  0.349
1993 Gallucci JC, Opromolla G, Paquette LA, Pardi L, Schirch PFT, Sivik MR, Zanello P. Redox behavior of ferrocene derivatives. 2. Bis(.eta.5-tricyclo[5.2.1.02,6]deca-2,5,8-trien-6-yl)iron and related molecules Inorganic Chemistry. 32: 2292-2297. DOI: 10.1021/Ic00063A018  0.333
1993 Guevel R, Paquette LA. An enzyme-based synthesis of (S)-(−)-3-methyl-2-[(phenylsiilfonyl)-methyl]butyl phenyl sulfide and the stereochemical course of its alkylation Tetrahedron-Asymmetry. 4: 947-956. DOI: 10.1016/S0957-4166(00)80137-8  0.364
1993 Paquette LA, Ting-Zhong W, Wang S, Philippo CMG. Enantioselective synthesis of (+)-cleomeolide, the structurally unique diterpene lactone constituent of Cleome viscosa Tetrahedron Letters. 34: 3523-3526. DOI: 10.1016/S0040-4039(00)73626-4  0.384
1993 Rogers RD, Sivik MR, Paquette LA. Isodicyclopentadienes and related molecules Journal of Organometallic Chemistry. 450: 125-135. DOI: 10.1016/0022-328X(93)80148-5  0.353
1992 Liang S, Paquette LA. Palladium-catalyzed intramolecular cyclization of vinyl and aryl triflates. Associated regioselectivity of the beta-hydride elimination step. Acta Chemica Scandinavica (Copenhagen, Denmark : 1989). 46: 597-605. PMID 1419434  0.314
1992 Ladouceur G, Paquette LA. Application of the anionic oxy-cope rearrangement to stereocontrolled synthesis of the A/B subunit of cytoxic 8,9-seco-ent-kaurenes Synthesis. 1992: 185-191. DOI: 10.1055/S-1992-34185  0.375
1992 Paquette LA, Sivik MR. Isodicyclopentadienes and related molecules. 57. Stereocontrolled synthesis of sterically crowded titanocenes of high enantiomeric purity by electrophilic capture of C-silylated ligands with configurational inversion Organometallics. 11: 3503-3505. DOI: 10.1021/Om00059A009  0.367
1992 Paquette LA, Maleczka RE. Enantioselective construction of natural (+)-pallescensin A. A sigmatropic pathway to furanosesquiterpenes Journal of Organic Chemistry. 57: 7118-7122. DOI: 10.1021/Jo00052A026  0.685
1992 Brown DS, Paquette LA. Synthetic studies on furanoheliangolides. Stereocontrolled construction of the oxygen-bridged tricyclic framework The Journal of Organic Chemistry. 57: 4512-4521. DOI: 10.1021/Jo00042A036  0.338
1992 Paquette LA, Andrews JFP, Vanucci C, Lawhorn DE, Negri JT, Rogers RD. Regio- and stereochemical course of the ring expansion of bridged bicyclic ketones to spirocyclic .alpha.-keto tetrahydrofurans. The Journal of Organic Chemistry. 57: 3956-3965. DOI: 10.1021/Jo00040A042  0.383
1992 Paquette LA, Underiner TL, Gallucci JC. Structural analysis of cis-[n.3.1]bicyclic ketones by x-ray crystallography. Impact of the observed conformational crossover by .pi.-facially diastereoselective nucleophilic additions to this class of ketones and on the stereochemical course of electrophilic reactions involving their methylene analogs Journal of Organic Chemistry. 57: 86-96. DOI: 10.1021/Jo00027A018  0.355
1992 Gree D, Gree R, Lowinger TB, Martelli J, Negri JT, Paquette LA. Acid-catalyzed cyclization of 1,4-diols tethered to (butadiene)iron tricarbonyl segments. Isotopic labeling as a mechanistic probe of stereochemical retention during tetrahydrofuran formation Journal of the American Chemical Society. 114: 8841-8846. DOI: 10.1021/Ja00049A015  0.333
1992 Paquette LA, Sauer DR, Cleary DG, Kinsella MA, Blackwell CM, Anderson LG. Application of palladium-catalyzed [3 + 2] cycloaddition technology to the elaboration of kempane diterpenes. Stereocontrolled synthesis of (.+-.)-3.alpha.-hydroxy-7.beta.-kemp-8(9)-en-6-one and (.+-.)-3.beta.-hydroxykemp-7(8)-en-6-one Journal of the American Chemical Society. 114: 7375-7387. DOI: 10.1021/Ja00045A007  0.313
1992 Rayner CM, Astles PC, Paquette LA. Total synthesis of furanocembranolides. 2. Macrocyclization studies culminating in the synthesis of a dihydropseudopterolide and gorgiacerone. Related furanocembranolide interconversions. Journal of the American Chemical Society. 114: 3926-3936. DOI: 10.1021/Ja00036A046  0.405
1992 Paquette LA, Doherty AM, Rayner CM. Total synthesis of furanocembranolides. 1. Stereocontrolled preparation of key heterocyclic building blocks and assembly of a complete seco-pseudopterane framework Journal of the American Chemical Society. 114: 3910-3926. DOI: 10.1021/Ja00036A045  0.392
1992 Paquette LA, Zhao M, Friedrich D. An unprecedented silyl triflate-promoted hydride shift within a taxane derivative Tetrahedron Letters. 33: 7311-7314. DOI: 10.1016/S0040-4039(00)60174-0  0.409
1992 Paquette LA, Branan BM, Rogers RD. X-ray crystallographic study of α-brominated diketo teraquinanes. Conformational effects of the number of halogens and their position on bond length and solit-state conformation Tetrahedron. 48: 297-306. DOI: 10.1016/S0040-4020(01)88141-2  0.339
1992 Graham RJ, Paquette LA. A Diepoxide Belonging to the Rare C1Point Group Journal of the Chinese Chemical Society. 39: 279-283. DOI: 10.1002/Jccs.199200049  0.355
1992 Paquette LA, Combrink KD, Elmore SW, Zhao M. Setting the Bridgehead Oxidation Level intrans-Tricyclo[9.3.1.03,8]pentadecanes as a Prelude to the Dual Synthesis of Taxol and Taxusin Helvetica Chimica Acta. 75: 1772-1791. DOI: 10.1002/hlca.19920750604  0.645
1991 Sornay C, Meunier P, Gautheron B, O'Doherty GA, Paquette LA. Isodicyclopentadienes and related molecules. Part 54. Stereoselective access to the three diisodicyclopentadienyltitanium dichlorides Organometallics. 10: 2082-2083. DOI: 10.1021/Om00052A068  0.568
1991 Maleczka RE, Paquette LA. Adaptation of oxyanionic sigmatropy to the convergent enantioselective synthesis of ambergris-type odorants The Journal of Organic Chemistry. 56: 6538-6546. DOI: 10.1021/Jo00023A018  0.606
1991 Paquette LA, Dahnke K, Doyon J, He W, Wyant K, Friedrich D. Regioselective conversion of cycloalkanones to vinyl bromides with 1,2-functionality transposition. A general stratagem Journal of Organic Chemistry. 56: 6199-6205. DOI: 10.1021/Jo00021A044  0.307
1991 Friedrich D, Paquette LA. Cyclopentenyllithium additions to chiral aldehydes. Diastereofacial selectivity indicating the absence of a pronounced neighboring carboxylate anion effect Journal of Organic Chemistry. 56: 3831-3840. DOI: 10.1021/Jo00012A013  0.412
1991 Paquette LA, Maleczka RE, Qiu FY. Regio- and stereoselective oxidation of unsaturated bicyclo[2.2.2]octanones with selenium dioxide The Journal of Organic Chemistry. 56: 2455-2461. DOI: 10.1021/Jo00007A037  0.646
1991 Paquette LA, Maleczka RE. Enantioselective Total Synthesis Of (-)-9-Epi-Ambrox, A Potent Ambergris-Type Olfactory Agent Journal of Organic Chemistry. 56: 912-913. DOI: 10.1021/Jo00003A004  0.62
1991 Paquette LA, O'Doherty GA, Rogers RD. Intramolecular reaction rate is not determined exclusively by the distance separating reaction centers. The kinetic consequences of modulated ground state strain on dyotropic hydrogen migration in systems of very similar geometric disposition [Erratum to document cited in CA115(17):182353r] Journal of the American Chemical Society. 113: 9710-9710. DOI: 10.1021/Ja00025A067  0.561
1991 Paquette LA, O'Doherty GA, Rogers RD. Intramolecular reaction rate is not determined exclusively by the distance separating reaction centers. The kinetic consequences of modulated ground state strain on dyotropic hydrogen migration in systems of very similar geometric disposition Journal of the American Chemical Society. 113: 7761-7762. DOI: 10.1021/Ja00020A048  0.569
1991 Bauer W, O'Doherty GA, Schleyer PvR, Paquette LA. Isodicyclopentadienes and related molecules. 58. Structural analysis of a camphor-derived cyclopentadienyllithium compound by NMR and MNDO. A ternary equilibrium in tetrahydrofuran Journal of the American Chemical Society. 113: 7093-7100. DOI: 10.1021/Ja00019A001  0.538
1991 Philippo CMG, Huu VN, Paquette LA. Two-carbon intercalation. 4-Cyclooctenones by tandem application of double-Tebbe and Claisen reactions Journal of the American Chemical Society. 113: 2762-2764. DOI: 10.1021/Ja00007A066  0.305
1991 Gugelchuk M, Paquette LA. Isodicyclopentadienes and related molecules. 54. Remote electronic perturbation of .pi.-facial stereoselectivity in [4+2] cycloadditions to isodicyclopentafulvenes. The consequences of p-phenyl substitution Journal of the American Chemical Society. 113: 246-253. DOI: 10.1021/Ja00001A035  0.36
1991 Elmore SW, Combrink KD, Paquette LA. A convenient means for controlling the oxidation level of bridgehead carbon C-1 in functionalized tricyclo[9.3.1.03,8]pentadecanes Tetrahedron Letters. 32: 6679-6682. DOI: 10.1016/S0040-4039(00)93573-1  0.672
1990 Paquette LA, Fristad WE. Oxidation chemistry of a cis-2-(3-flurylidene)ethanol Heterocycles. 31: 2219-2224. DOI: 10.3987/Com-90-5597  0.338
1990 Paquette LA, Lawhorn DE, Teleha CA. Response of 2-lithio-4,5-dihydrofuran : ketone adducts to acid catalysis Heterocycles. 30: 765-769. DOI: 10.3987/Com-89-S87  0.37
1990 Paquette LA, Ra CS, Edmonson SD. Regiocontrolled cyclohexenone annulation via acylation of a ketone carbonyl Journal of Organic Chemistry. 55: 2443-2445. DOI: 10.1021/Jo00295A037  0.425
1990 Paquette LA, Sweeney TJ. A concise total synthesis of enantiomerically pure (+)-cis- and (+)-trans-lauthisan Journal of Organic Chemistry. 55: 1703-1704. DOI: 10.1021/Jo00293A006  0.38
1990 Paquette LA, Ross RJ, Shi YJ. Regioselective routes to nucleophilic optically active 2- and 3-carene systems Journal of Organic Chemistry. 55: 1589-1598. DOI: 10.1021/Jo00292A039  0.511
1990 Paquette LA, Macdonald D, Anderson LG. Total synthesis of (+)-ikarugamycin. 2. Elaboration of the macrocyclic lactam and tetramic acid substructures and complete assembly of the antibiotic Journal of the American Chemical Society. 112: 9292-9299. DOI: 10.1021/Ja00181A035  0.438
1990 Paquette LA, Romine JL, Lin HS, Wright J. Total synthesis of (+)-ikarugamycin. 1. Stereocontrolled construction of the decahydro-as-indacene subunit Journal of the American Chemical Society. 112: 9284-9292. DOI: 10.1021/Ja00181A034  0.341
1990 Paquette LA, Bauer W, Sivik MR, Buehl M, Feigel M, Schleyer PvR. Structure of lithium isodicyclopentadienide and lithium cyclopentadienide in tetrahydrofuran solution. A combined NMR, IGLO, and MNDO study Journal of the American Chemical Society. 112: 8776-8789. DOI: 10.1021/Ja00180A020  0.317
1990 Paquette LA, Rayner CM, Doherty AM. Synthesis of (.+-.)-11,0(3)-dihydropseudopterolide Journal of the American Chemical Society. 112: 4078-4079. DOI: 10.1021/Ja00166A077  0.372
1990 Paquette LA, Shen CC. Isodicyclopentadienes and related molecules. 49. Synthesis, static structure, and kinetic stability of a syn-sesquinorbornatriene Journal of the American Chemical Society. 112: 1159-1164. DOI: 10.1021/Ja00159A041  0.311
1990 Paquette LA, Wang TZ, Luo J, Cottrell CE, Clough AE, Anderson LB. Is pseudorotation the operational pathway for bond shifting within [8]annulenes? Probe of planarization requirements by 1,3-annulation of the cyclooctatetraene ring. Kinetic analysis of racemization and 2-D NMR quantitation of .pi.-bond alternation and ring inversion as a function of polymethylene chain length Journal of the American Chemical Society. 112: 239-253. DOI: 10.1021/Ja00157A038  0.353
1990 Liang S, Paquette LA. Biocatalytic-based synthesis of optically pure (C-6)-functionalized 1-(tert-butyldimethylsilyloxy) 2-methyl-(E)-2-heptenes Tetrahedron-Asymmetry. 1: 445-452. DOI: 10.1016/S0957-4166(00)86349-1  0.347
1990 Ezquerra J, He W, Paquette LA. Enantiospecific synthesis of the the tricyclxc nucleus of acetoxycrenulide by claisen ring exfansion Tetrahedron Letters. 31: 6979-6982. DOI: 10.1016/S0040-4039(00)97221-6  0.396
1990 Paquette LA, Sweeney TJ. Stereospecific approach to 3-oxocen-7-ones via aliphatic claisen rearrangement. synthesis of (+)-(2R,8S)- and (+)-(2R,8J)-lauthisan Tetrahedron. 46: 4487-4502. DOI: 10.1016/S0040-4020(01)85577-0  0.387
1990 Paquette LA. Stereocontrolled Construction of Complex Cyclic Ketones via Oxy‐Cope Rearrangement Angewandte Chemie. 29: 609-626. DOI: 10.1002/Anie.199006091  0.425
1989 Gallucci JC, Taylor RT, Kobayashi T, Weber JC, Krause J, Paquette LA. X-ray crystallographic analysis of the structural distortions induced by substitution and annulation of the dodecahedrane nucleus Acta Crystallographica, Section C: Crystal Structure Communications. 45. PMID 2610983 DOI: 10.1107/S0108270188013721  0.309
1989 Paquette LA, O'Doherty GA, Miller BL, Rogers RD, Rheingold AL, Geib SL. Isodicyclopentadienes and related molecules. 48. Stereochemically uniform mode of iron carbonyl complexation to spirocyclic isodicyclopentadienes Organometallics. 8: 2167-2172. DOI: 10.1021/Om00111A012  0.507
1989 Paquette LA, Shi YJ. Stereocontrolled construction of hydroazulenones by sequential anionic oxy-Cope rearrangement - SN' allylic ether displacement Journal of Organic Chemistry. 54: 5205-5207. DOI: 10.1021/Jo00283A007  0.366
1989 Paquette LA, Galatsis P. Functional group manipulation along the perimeter of a hemispherical molecule. Synthesis of dihydro- and tetrahydro-C16-hexaquinacene The Journal of Organic Chemistry. 54: 5039-5043. DOI: 10.1021/Jo00282A018  0.309
1989 Paquette LA, DeRussy DT, Pegg NA, Taylor RT, Zydowsky TM. Direct oxygenation of enolates generated by anionic oxy-Cope rearrangement. Expedient preparation of polycyclic .alpha.-hydroxy ketones Journal of Organic Chemistry. 54: 4576-4581. DOI: 10.1021/Jo00280A023  0.35
1989 Cheney DL, Paquette LA. Studies directed toward the total synthesis of trixikingolide. Analysis of the capacity for transannular carbon-carbon bond formation in various bicyclic and tricyclic intermediates Journal of Organic Chemistry. 54: 3334-3347. DOI: 10.1021/Jo00275A018  0.326
1989 Paquette LA, Maynard GD, Ra CS, Hoppe M. Cleavage of carbon-carbon bonds with high stereochemical control. 7. Chiral .alpha.-silyl benzoylcycloalkanes undergo base-catalyzed cleavage with retention of configuration when not sterically congested Journal of Organic Chemistry. 54: 1408-1418. DOI: 10.1021/Jo00267A032  0.343
1989 Gilday JP, Gallucci JC, Paquette LA. Cleavage of carbon-carbon bonds with high stereochemical control. 6. Asymmetric synthesis of chiral C-centered organosilanes by Haller-Bauer cleavage of optically active, nonenolizable .alpha.-silyl phenyl ketones Journal of Organic Chemistry. 54: 1399-1408. DOI: 10.1021/Jo00267A031  0.376
1989 Paquette LA, Macdonald D, Anderson LG, Wright J. A triply convergent enantioselective total synthesis of (+)-ikarugamycin Journal of the American Chemical Society. 111: 8037-8039. DOI: 10.1021/Ja00202A067  0.371
1989 Paquette LA, Reagan J, Schreiber SL, Teleha CA. Intramolecular SN' cleavage of allylic ethers by enolate anions Journal of the American Chemical Society. 111: 2331-2332. DOI: 10.1021/Ja00188A073  0.536
1989 Paquette LA, Choon SR, Silvestri TW. Free radical cyclization approach to a functionalized [3] peristylane Tetrahedron. 45: 3099-3106. DOI: 10.1016/S0040-4020(01)80136-8  0.456
1989 Paquette LA, Oplinger JA. Limitations in the application of anionic oxy-cope sigmatropy to elaboration of the forskolin nucleus Tetrahedron. 45: 107-124. DOI: 10.1016/0040-4020(89)80038-9  0.388
1989 Gugelchuk M, Paquette LA. Can Electron Transmission from Aza-Crown Ethers Contribute to Diels-Alder π-Facial Selectivity? Israel Journal of Chemistry. 29: 165-169. DOI: 10.1002/Ijch.198900024  0.35
1988 Weber JC, Paquette LA. Synthesis of amino-substituted dodecahedranes, secododecahedranes, and homododecahedranes, and their antiviral relationship to 1-aminoadamantane The Journal of Organic Chemistry. 53: 5315-5320. DOI: 10.1021/Jo00257A021  0.339
1988 Paquette LA, Ra CS. Cleavage of carbon-carbon bonds with high stereochemical control. 5. Course of the Haller-Bauer reaction of cyclic .alpha.-phenyl ketones Journal of Organic Chemistry. 53: 4978-4985. DOI: 10.1021/Jo00256A014  0.35
1988 Paquette LA, Gugelchuk M. Modulation of .pi.-facial selectivity in Diels-Alder cycloaddition to isodicyclopentafulvenes by remote para substitution of an exocyclic phenyl group The Journal of Organic Chemistry. 53: 1835-1837. DOI: 10.1021/Jo00243A054  0.313
1988 Paquette LA, Pansegrau PD, Wiedeman PE, Springer JP. (+)-Pleuromutilin synthetic studies. Examples of intramolecular hydrogen abstraction by the .beta.-carbon of a 2-cyclopentenone subunit with resultant .alpha.-coupling Journal of Organic Chemistry. 53: 1461-1466. DOI: 10.1021/Jo00242A021  0.322
1988 Paquette LA, Bulman-Page PC, Pansegrau PD, Wiedeman PE. (+)-Pleuromutilin synthetic studies. Direct degradation to and independent preparation of an advanced diketone intermediate. Demonstration that reconstruction of the eight-membered ring suffers from serious kinetic retardation Journal of Organic Chemistry. 53: 1450-1460. DOI: 10.1021/Jo00242A020  0.347
1988 Paquette LA, Okazaki ME, Caille JC. A formal total synthesis of (.+-.)-laurenene Journal of Organic Chemistry. 53: 477-481. DOI: 10.1021/Jo00238A003  0.362
1988 Wright J, Drtina GJ, Roberts RA, Paquette LA. A convergent synthesis of triquinane sesterterpenes. Enantioselective synthesis of (-)-retigeranic acid A Journal of the American Chemical Society. 110: 5806-5817. DOI: 10.1021/Ja00225A036  0.365
1988 Paquette LA, Wang TZ. The first cyclooctatetraene to which bond shifting is more accessible than ring inversion Journal of the American Chemical Society. 110: 3663-3665. DOI: 10.1021/Ja00219A054  0.336
1988 Paquette LA, Kobayashi T, Gallucci JC. Cyclopropanation of spherical hydrocarbons without need for prior olefination. The synthesis of cyclopropadodecahedranes Journal of the American Chemical Society. 110: 1305-1307. DOI: 10.1021/Ja00212A057  0.371
1988 Gilday JP, Paquette LA. Stabilized carbanions by alkyllithium-induced decarboxylation of non-enolizable carboxylic acids. An anionic equivalent to the hunsdiecker reaction Tetrahedron Letters. 29: 4505-4508. DOI: 10.1016/S0040-4039(00)80532-8  0.375
1988 Paquette LA, Shen C. Extended functionalized of the fluted [4]peristylane perimeter Tetrahedron Letters. 29: 4069-4072. DOI: 10.1016/S0040-4039(00)80419-0  0.318
1988 Paquette LA, Poupart M. Rapid construction of the tetracyclic nucleus of cerorubenic acid-III by oxyanionic cope chemistry Tetrahedron Letters. 29: 273-276. DOI: 10.1016/S0040-4039(00)80072-6  0.31
1988 Poupart M, Paquette LA. Conformational consequences of intramolecular cyclopropanation within small bicyclic systems. Synthesis and desymmetrization of 1-methyltricyclo[2.2.2.02,6]octane-3,5-dione Tetrahedron Letters. 29: 269-272. DOI: 10.1016/S0040-4039(00)80071-4  0.322
1988 Blankenship C, Wells GJ, Paquette LA. Desilylative condensation reactions of electronegatively substituted 1-(trimethylsilyl)cyclopropanes1 Tetrahedron. 44: 4023-4032. DOI: 10.1016/S0040-4020(01)86653-9  0.396
1988 Paquette LA, DeRussy DT, Rogers RD. On possible redirection of the course of anionic oxy-cope rearrangements Tetrahedron. 44: 3139-3148. DOI: 10.1016/S0040-4020(01)85945-7  0.33
1987 Paquette LA, Learn KS, Romine JL. Double Diastereoselection Operative During π-Facially Selective Addition of Chiral 1-Cyclopentenyllithium Reagents to (7R)-7-Methyl-7-Vinylbicyclo[3.2.0]Hept-2-En-6-One Synthetic Communications. 17: 369-375. DOI: 10.1080/00397918708063913  0.353
1987 Cleary DG, Paquette LA. Cycloaddition of the Trimethylenemethane-Palladium Complex to Activated Six-Membered and Medium-Ring Enones Synthetic Communications. 17: 497-501. DOI: 10.1080/00397918708056435  0.353
1987 Paquette LA, Burke LD. Triplet-state benzonorbornadiene di-.pi.-methane photorearrangements. Competition between bridgehead and vinyl substituents for control of the product-determining 1,2-aryl shift step Journal of Organic Chemistry. 52: 2674-2679. DOI: 10.1021/Jo00389A008  0.31
1987 Paquette LA, Miyahara Y. Directed alkyl substitution of the dodecahedrane nucleus. The 1,4-dimethyl, 1,6-dimethyl, and 1,4,16-trimethyl derivatives. Indanododecahedrane by stepwise dehydrogenation of a benzylated seco derivative Journal of Organic Chemistry. 52: 1265-1272. DOI: 10.1021/Jo00383A017  0.383
1987 Paquette L, Fristad W, Dime D, Bailey T. Additions and Corrections - Silanes in Organic Synthesis. 8. Preparation of Vinylsilanes from Ketones and Their Regiospecific Cyclopentenone Annulation. Journal of Organic Chemistry. 52: 1176-1176. DOI: 10.1021/Jo00382A600  0.364
1987 Ross RJ, Paquette LA. Ingenane synthetic studies. Stereocontrolled introduction of all oxygenated and unsaturated centers in an ingenol prototype Journal of Organic Chemistry. 52: 5497-5498. DOI: 10.1021/Jo00233A048  0.517
1987 Paquette LA, Gugelchuk M, McLaughlin ML. Isodicyclopentadienes and related molecules. 38. Homochiral pinene-fused cyclopentadienes. Synthesis and .pi.-facially selective course of Diels-Alder cycloadditions and metallocene formation The Journal of Organic Chemistry. 52: 4732-4740. DOI: 10.1021/Jo00230A015  0.561
1987 Paquette LA, Gilday JP, Ra CS. Haller-Bauer cleavage of open-chain and cyclic .alpha.-phenyl ketones proceeds with retention of configuration Journal of the American Chemical Society. 109: 6858-6860. DOI: 10.1021/Ja00256A054  0.334
1987 Paquette LA, Pierre F, Cottrell CE. Anionic rearrangements of syn- and anti-7-cyclopentenyl-7-hydroxynorbornenes. The case for sequential ring cleavage and intramolecular Michael addition Journal of the American Chemical Society. 109: 5731-5740. DOI: 10.1021/Ja00253A027  0.373
1987 Waykole L, Paquette LA. Synthesis of [4.4.4]propellahexaene Journal of the American Chemical Society. 109: 3174-3175. DOI: 10.1021/Ja00244A067  0.372
1987 Paquette LA, Ham WH. Total synthesis of the marine sesquiterpenes dactylol and africanol. De novo construction of a cyclooctanoid natural product from cycloheptane precursors Journal of the American Chemical Society. 109: 3025-3036. DOI: 10.1021/Ja00244A026  0.34
1987 Dressel J, Paquette LA. Tricyclo[5.3.0.02,8]deca-3,5,9-triene Journal of the American Chemical Society. 109: 2857-2858. DOI: 10.1021/Ja00243A067  0.332
1987 Oplinger JA, Paquette LA. Synthesis of the forskolin skeleton via anionic oxy-cope rearrangement Tetrahedron Letters. 28: 5441-5444. DOI: 10.1016/S0040-4039(00)96749-2  0.36
1987 Paquette LA, Lin H, Coghlan MJ. Total synthesis of (±)-sterpuric acid Tetrahedron Letters. 28: 5017-5020. DOI: 10.1016/S0040-4039(00)96684-X  0.319
1987 Paquette LA, Trova MP. Belting of the cyclooctatetraene ring across the transannular 1- and 5-positions Tetrahedron Letters. 28: 2795-2798. DOI: 10.1016/S0040-4039(00)96211-7  0.381
1987 Paquette LA, Romine JL, Lin H. Diastereoselective π-facially controlled nucleophilic additions of chiral vinylorganometallics to chiral β,γ-unsaturated ketones. 2. A practical method for stereocontrolled elaboration of the decahydro--indacene subunit of ikarugamycin Tetrahedron Letters. 28: 31-34. DOI: 10.1016/S0040-4039(00)95641-7  0.346
1987 Paquette LA, Schaefer AG, Springer JP. Synthesis of (±)-14-epiupial by manganese(III) -γ-lactone annulation Tetrahedron. 43: 5567-5582. DOI: 10.1016/S0040-4020(01)87738-3  0.437
1987 Paquette LA, Learn KS, Romine JL. Doubly diastereoselective nucleophilic additions to a bicyclic β,γ-unsaturated ketone possessing a conformationally mobile double bond Tetrahedron. 43: 4989-5002. DOI: 10.1016/S0040-4020(01)87678-X  0.428
1987 MCLAUGHLIN ML, MCKINNEY JA, PAQUETTE LA. ChemInform Abstract: Efficient Preparation of Homochiral Bicyclo-Annulated Cyclopentadienes via the Skattebol Rearrangement. Avoidance of Limitations due to Angle Strain. Part 36. Cheminform. 18. DOI: 10.1002/chin.198721142  0.468
1986 Paquette LA, Learn KS. .pi.-Facially controlled nucleophilic additions of chiral vinylorganometallics to chiral .beta.,.gamma.-unsaturated ketones. 1. Double diastereoselection studies involving 7,7-dimethoxy-5-norbornen-2-one Journal of the American Chemical Society. 108: 7873-7875. PMID 22283323 DOI: 10.1021/Ja00284A085  0.32
1986 Paquette LA, Lau CJ. Kinetic and Thermodynamic Control of Aldolization in Higher Order Polyquinane Systems Synthetic Communications. 16: 103-110. DOI: 10.1080/00397918608057696  0.32
1986 Wang TZ, Paquette LA. Photochemical route to a representative 1,8-annulated 7-methylene-1,3,5-cyclooctatriene Journal of Organic Chemistry. 51: 5232-5234. DOI: 10.1021/Jo00376A034  0.344
1986 St. Laurent DR, Paquette LA. Cyclopentannulation with a 1,3-dicarbonyl dipole equivalent. Synthesis of bicyclo[3.3.0]oct-1(5)-ene-2,6-dione The Journal of Organic Chemistry. 51: 3861-3864. DOI: 10.1021/Jo00370A021  0.37
1986 Paquette LA, Coghlan MJ, Cottrell CE, Irie T, Tanida H. Regioselectivity of pyridine ring migration during triplet-sensitized di-.pi.-methane photorearrangements of 5,8-dihydro-5,8-methanoisoquinoline derivatives. The case for heteroatom control The Journal of Organic Chemistry. 51: 696-699. DOI: 10.1021/Jo00355A020  0.337
1986 Paquette LA, Kunzer H. Photoinitiated quadricyclane-quadricyclane rearrangements Journal of the American Chemical Society. 108: 7431-7433. DOI: 10.1021/Ja00283A061  0.317
1986 Jendralla H, Jelich K, DeLucca G, Paquette LA. Functionalized polyunsaturated [4.4.4]propellanes. Synthesis, intraring chemistry, and backbone rearrangements. [4.4.4]propella-2,4,7,9,12-pentaene and its thermal frangibility Journal of the American Chemical Society. 108: 3731-3739. DOI: 10.1021/Ja00273A030  0.311
1986 Paquette LA, Kuenzer H, Green KE, De Lucchi O, Licini G, Pasquato L, Valle G. Consequences of fixing three parallel coplanar double bonds in close proximity with different geometries. Synthesis and spectral parameters of syn- and anti-sesquinorbornatriene Journal of the American Chemical Society. 108: 3453-3460. DOI: 10.1021/Ja00272A047  0.304
1986 Paquette LA, McKinney JA, McLaughlin ML, Rheingold AL. Transition metal complexation of optically pure annulated cyclopentadies. Face selectivity, three-dimensional structural features, and utilization for asymmetric hydrogenation Tetrahedron Letters. 27: 5599-5602. DOI: 10.1016/S0040-4039(00)85275-2  0.471
1986 McLaughlin ML, McKinney JA, Paquette LA. Efficient preparation of homochiral bicyclo-annulated cyclopentadienes via the skattebøl rearrangement. Avoidance of limitations due to angle strain Tetrahedron Letters. 27: 5595-5598. DOI: 10.1016/S0040-4039(00)85274-0  0.515
1986 Paquette LA, Ham WH. Total synthesis of africanol Tetrahedron Letters. 27: 2341-2344. DOI: 10.1016/S0040-4039(00)84524-4  0.399
1986 Paquette LA, Kravetz TM, Charumilind P. The 1,7-cyclohexenonorbornadiene system Tetrahedron. 42: 1789-1795. DOI: 10.1016/S0040-4020(01)87596-7  0.431
1986 Jendralla H, Jelich K, Delucca G, Paquette LA. Functionalized Polyunsaturated [4.4.4]Propellanes. Synthesis, Intraring Chemistry, and Backbone Rearrangements. Cheminform. 17. DOI: 10.1002/Chin.198642165  0.364
1986 Paquette LA, Coghlan MJ, Cottrell CE, Irie T, Tanida H. Regioselectivity of Pyridine Ring Migration During Triplet-Sensitized Di-n-methane Photorearrangements of 5,8-Dihydro-5,8-methanoisoquinoline Derivatives. Cheminform. 17. DOI: 10.1002/Chin.198636116  0.357
1986 Hill RK, Morton GH, Peterson JR, Walsh JA, Paquette LA. Synthesis and Chiroptical Properties of 5,7-Dioxobicyclo[2.2.2]oct-2-ene and Bicyclo[2.2.2]octane-2,5-dione. Cheminform. 17. DOI: 10.1002/Chin.198627163  0.351
1986 Paquette LA, Nakamura K, Engel P. Synthesis of hexacyclo[5.4.1.02,6.03,10.04,8.09,12]dodecane‐5,11‐dione and its conversion to di‐, tri‐, and tetranitro‐1,3‐bishomopentaprismanes Chemische Berichte. 119: 3782-3800. DOI: 10.1002/Cber.19861191222  0.366
1985 Haraldsson GG, Paquette LA, Springer JP. Stereoselective epoxidation of a 5,6,6-trisubstituted cyclohex-2-enone Journal of the Chemical Society, Chemical Communications. 1035-1036. DOI: 10.1039/C39850001035  0.309
1985 Hill RK, Morton GH, Peterson JR, Walsh JA, Paquette LA. Synthesis and chiroptical properties of 5,7-dioxobicyclo[2.2.2]oct-2-ene and bicyclo[2.2.2]octane-2,5-dione Journal of Organic Chemistry. 50: 5528-5533. DOI: 10.1021/Jo00350A019  0.331
1985 Paquette LA, Peterson JR, Ross RJ. Migratory selectivity in the ring expansion of .alpha.,.beta.-unsaturated cyclic ketones via .beta.-hydroxy selenides Journal of Organic Chemistry. 50: 5200-5204. DOI: 10.1021/Jo00225A043  0.542
1985 Paquette LA, Belmont DT, Asu YL. Regiospecific and stereoselective alkylation of the octahydronaphthal-8(9)-en-3-one nucleus Journal of Organic Chemistry. 50: 4667-4672. DOI: 10.1021/Jo00224A001  0.321
1985 Paquette LA, Hathaway SJ, Schirch PFT. Electronic control of stereoselectivity. 29. Stereochemical and regiochemical course of isodicyclopentadiene-tropone cycloaddition reactions The Journal of Organic Chemistry. 50: 4199-4205. DOI: 10.1021/Jo00222A005  0.304
1985 Barth W, Paquette LA. Synthesis of a representative cis/trans pair of 4,5-disubstituted cyclopentenyllithium reagents Journal of Organic Chemistry. 50: 2438-2443. DOI: 10.1021/Jo00214A008  0.318
1985 Galemmo RA, Paquette LA. Contrasting directed-Aldol reactivity of a pair of epimeric trimethylsilyl enol ethers The Journal of Organic Chemistry. 50: 1768-1770. DOI: 10.1021/Jo00210A045  0.355
1985 Kinney WA, Coghlan MJ, Paquette LA. General approach to annulated 4-cyclooctenones by aliphatic Claisen rearrangement. Stereospecific total synthesis of (.+-.)-precapnelladiene Journal of the American Chemical Society. 107: 7352-7360. DOI: 10.1021/Ja00311A023  0.366
1985 Paquette LA, Kravetz TM, Hsu LY. Electronic control of stereoselectivity. 31. .pi.-Facial course of Diels-Alder cycloadditions to 10-isopropylideneisodicyclopentadiene Journal of the American Chemical Society. 107: 6598-6603. DOI: 10.1021/Ja00309A029  0.306
1985 Paquette LA, Kuenzer H, Green KE. syn-Sesquinorbornatriene and its quadricyclane valence isomer Journal of the American Chemical Society. 107: 4788-4790. DOI: 10.1021/Ja00302A036  0.306
1985 Paquette LA, Ham WH, Dime DS. A formal total synthesis of dactylol Tetrahedron Letters. 26: 4983-4986. DOI: 10.1016/S0040-4039(01)80832-7  0.429
1985 Paquette LA, Wiedeman PE, Bulman-Page PC. A relay approach to (+)-pleuromutilin. III. direct degradation of the natural product to the key diketone intermediate and its chemospecific functionalization Tetrahedron Letters. 26: 1611-1614. DOI: 10.1016/S0040-4039(00)98565-4  0.313
1985 Paquette LA, Bulman-Page PC. A relay approach to (+)-pleuromutilin. II. preparation of an advanced optically pure intermediate Tetrahedron Letters. 26: 1607-1610. DOI: 10.1016/S0040-4039(00)98564-2  0.305
1985 Paquette LA, Wiedeman PE. A relay to (+)-pleuromutilin. I. synthesis of a levorotatory tricyclic lactone subunit Tetrahedron Letters. 26: 1603-1606. DOI: 10.1016/S0040-4039(00)98563-0  0.31
1985 Paquette LA, Nakamura K, Fischer JW. Synthesis of a versatile functionalized tetraquinane. Convenient access to 1,3-bishomopentaprismanedione Tetrahedron Letters. 26: 4051-4054. DOI: 10.1016/S0040-4039(00)89290-4  0.402
1985 Hathaway SJ, Paquette LA. Electronic control of stereoselectivity-21. Stereochemical parallelism between dienophilic capture and singlet oxygenation of isodicyclopentadiene derivatives1 1 Part 20:Y.-L. Hsu, S.J. Hathaway and L.A. Paquette, Tetrahedron Lett. 259(1984) Tetrahedron. 41: 2037-2043. DOI: 10.1016/S0040-4020(01)96574-3  0.328
1985 Haraldsson GG, Paquette LA, Springer JP. Stereoselective Epoxidation Of A 5,6,6-Trisubstituted Cyclohex-2-Enone Cheminform. 16. DOI: 10.1002/Chin.198548165  0.452
1985 Kinney WA, Coghlan MJ, Paquette LA. Claisen Rearrangement Of 6-Alkenyl-2-Methylenetetrahydropyrans. A New Approach To Annulated 4-Cyclooctenones And A Stereospecific Synthesis O Precapnelladiene Cheminform. 16. DOI: 10.1002/Chin.198508307  0.31
1985 Paquette LA, Roberts RA, Drtina GJ. Total Synthesis Of (-)-Silphiperfol-6-Ene And (-)-5-Oxosilphiperfol-6-Ene Cheminform. 16. DOI: 10.1002/Chin.198508306  0.368
1985 Paquette LA, Blankenship C, Wells GJ. Silicon In Organic Synthesis. 27. A Method For The Generation Of Electronegatively Substituted Cyclopropyl Anions Under Preparatively Useful Conditions. Aldol Condensation With Carbonyl Partners Cheminform. 16. DOI: 10.1002/Chin.198506140  0.37
1985 PAQUETTE LA, HSU L, GALLLUCCI JC, KORP JD, BERNAL I, KRAVETZ TM, HATHAWAY SJ. ChemInform Abstract: Electronic Control of Stereoselectivity. Part 24. Interrelationship of π-Bond Tilting and the Stereochemical Disposition of Substituents at C-2 and C-7 within Norbornyl-Fused 4-Cycloheptenones. Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198502058  0.322
1984 Paquette LA, Stevens KE. Stereocontrolled total synthesis of the triquinane marine sesquiterpene Δ9(12)-capnellene Canadian Journal of Chemistry. 62: 2415-2420. DOI: 10.1139/V84-415  0.372
1984 Blankenship C, Paquette LA. Double Hunsdiecker Reactions. Convenient Preparation of 1,1-Dibromocyclopropane and 1,1-Dibromocyclobutane Synthetic Communications. 14: 983-987. DOI: 10.1080/00397918408059624  0.415
1984 Paquette LA, Daniels RG, Gleiter R. Silanes in organic synthesis. 24. Synthesis, reactivity, and electronic structure of [2-(trimethylsilyl)-1,3-cyclohexadiene]iron tricarbonyl complexes Organometallics. 3: 560-567. DOI: 10.1021/Om00082A009  0.305
1984 Paquette LA, Green KE, Gleiter R, Schaefer W, Gallucci JC. Electronic control of stereoselectivity. 27. The effect of apical spirocyclopropane substitution on the stereochemical course of Diels-Alder cycloadditions to norbornyl-fused diene systems Journal of the American Chemical Society. 106: 8232-8240. DOI: 10.1021/Ja00338A037  0.328
1984 Kinney WA, Coghlan MJ, Paquette LA. Claisen rearrangement of 6-alkenyl-2-methylenetetrahydropyrans. A new approach to annulated 4-cyclooctenones and a stereospecific synthesis of precapnelladiene Journal of the American Chemical Society. 106: 6868-6870. DOI: 10.1021/Ja00334A081  0.354
1984 Paquette LA, Roberts RA, Drtina GJ. Total synthesis of (−)-silphiperfol-6-ene and ()-5-oxosilphiperfol-6-ene Journal of the American Chemical Society. 106: 6690-6693. DOI: 10.1021/Ja00334A038  0.305
1984 Paquette LA, Blankenship C, Wells GJ. Silicon in organic synthesis. 27. A method for the generation of electronegatively substituted cyclopropyl anions under preparatively useful conditions. Aldol condensation with carbonyl partners Journal of the American Chemical Society. 106: 6442-6443. DOI: 10.1021/Ja00333A068  0.349
1984 Paquette LA, Hsu LY, Gallucci JC, Korp JD, Bernal I, Kravetz TM, Hathaway SJ. Interrelationship of .pi.-bond tilting and the stereochemical disposition of substituents at C-2 and C-7 within norbornyl-fused 4-cycloheptenones Journal of the American Chemical Society. 106: 5743-5744. DOI: 10.1021/Ja00331A063  0.303
1984 Paquette LA, Nitz TJ, Ross RJ, Springer JP. Ingenane synthetic studies. An expedient approach to highly oxygenated ABC subunits of ingenol via reductive dialkylative annulation and .alpha.,.beta.-epoxy ketone photoisomerization Journal of the American Chemical Society. 106: 1446-1454. DOI: 10.1021/Ja00317A043  0.539
1984 Paquette LA, Hathaway SJ, Gallucci JC. Selective trapping of rearranged spirocyclic isodicyclopentadienes by tropone Tetrahedron Letters. 25: 2659-2662. DOI: 10.1016/S0040-4039(01)81256-9  0.364
1984 Hsu LY, Hathaway SJ, Paquette LA. Electronic control of stereoselectivity. 20. Crystal and molecular structure of the ferrocene derived from tricyclo[5.2.1.02,6]Deca-2,5,8-triene Tetrahedron Letters. 25: 259-262. DOI: 10.1016/S0040-4039(00)99855-1  0.304
1984 Charumilind P, Paquette LA. Electronic control of stereoselectivity. 26. On the inability of fused cyclopropane rings to direct the stereochemical course of dienophile capture by tetracyclo[5.3.2.02,6.08,10]dodeca-2,5,11-triene and its dihydro derivative Journal of the American Chemical Society. 106: 8225-8232. DOI: 10.1002/Chin.198517089  0.344
1984 Wells GJ, Yan TH, Paquette LA. Silicon in organic synthesis. 24. Preparation and selected reactions of functionalized 1-(trimethylsilyl)-substituted cyclopropanes The Journal of Organic Chemistry. 49: 3604-3609. DOI: 10.1002/Chin.198509281  0.364
1984 Paquette LA, Valpey RS, Annis GD. SILICON IN ORGANIC SYNTHESIS. 23. CHLORO((TRIMETHYLSILYL)METHYL)KETENE AS A USEFUL INTERMEDIATE FOR THE ELABORATION OF α-METHYLENECYCLOBUTANONES AND -CYCLOPENTANONES Cheminform. 15. DOI: 10.1002/Chin.198435177  0.33
1984 Carr RVC, Williams RV, Paquette LA. Dienophilic Properties Of Phenyl Vinyl Sulfone And Trans-1-(Phenylsulfonyl)-2-(Trimethylsilyl)Ethylene. Their Utilization As Synthons For Ethylene, 1-Alkenes, Acetylene, And Monosubstituted Alkynes In The Construction Of Functionalize Cheminform. 15. DOI: 10.1002/Chin.198426094  0.367
1984 Paquette LA, Gardlik JM, Mccullough KJ, Samodral R, Delucca G, Ouellette RJ. Bond Fixation In Annulenes. 16. Synthesis Of The 1,2-Dimethyl-3-Phenylcyclooctatetraene ⇄ 1,8-Dimethyl-2-Phenylcyclooctatetraene Bond Shift Isomer Pair. Probe Of The Relative Size Of A Flanking Phenyl Substituent By Means Of Racemizat Cheminform. 15. DOI: 10.1002/Chin.198414173  0.346
1984 Paquette LA, Annis GD. Total Synthesis Of (.+-.)-Pentalenene, The Least Oxidized Neutral Triquinane Metabolite Of Streptomyces Griseochromogenes Cheminform. 15. DOI: 10.1002/Chin.198412314  0.302
1983 Carr RVC, Williams RV, Paquette LA. Dienophilic properties of phenyl vinyl sulfone and trans-1-(phenylsulfonyl)-2-(trimethylsilyl)ethylene. Their utilization as synthons for ethylene, 1-alkenes, acetylene, and monosubstituted alkynes in the construction of functionalized six-membered rings via [4 + 2] .pi. cycloaddition methodology Journal of Organic Chemistry. 48: 4976-4986. DOI: 10.1021/Jo00173A039  0.417
1983 Hathaway SJ, Paquette LA. Silanes in organic synthesis. 19. Examination of (-)-.alpha.-naphthylphenylmethylallylsilane as a template for effecting chirality transfer from silicon to carbon The Journal of Organic Chemistry. 48: 3351-3353. DOI: 10.1021/Jo00167A047  0.304
1983 Roberts RA, Schuell V, Paquette LA. Electrophile-initiated ring-opening reactions of 2-methylene-6,6-dimethylbicyclo[3.1.0]hexanes. New methodology for the synthesis of highly functionalized 1,2,3-trisubstituted cyclopentenes Journal of Organic Chemistry. 14: 2076-2084. DOI: 10.1021/Jo00160A028  0.452
1983 Paquette LA, Gardlik JM, McCullough KJ, Samodral R, DeLucca G, Ouellette RJ. Bond fixation in annulenes. 16. Synthesis of the 1,2-dimethyl-3-phenylcyclooctatetraene .dblarw. 1,8-dimethyl-2-phenylcyclooctatetraene bond shift isomer pair. Probe of the relative size of a flanking phenyl substituent by means of racemization kinetics Journal of the American Chemical Society. 105: 7649-7655. DOI: 10.1021/Ja00364A031  0.358
1983 Paquette LA, Charumilind P, Gallucci JC. Silanes in organic synthesis. 20. Regio- and stereochemical definition of silatropic migration within trimethylsilyl-substituted isodicyclopentadienes Journal of the American Chemical Society. 105: 7364-7375. DOI: 10.1021/Ja00363A026  0.337
1983 Paquette LA, Galemmo RA, Springer JP. Synthesis of the alleged structure of senoxydene, the triquinane sesquiterpene derived from Senecio oxyodontus Journal of the American Chemical Society. 105: 6975-6976. DOI: 10.1021/Ja00361A046  0.326
1983 Browne AR, Kearney FR, Mason SF, Paquette LA, Drake AF. Electronic absorption and circular dichroism spectra of the perturbed coplanar cis-diene chromophore in deuterium- and methyl-substituted 7,7-dimethylbicyclo[4.1.1]octa-2,4-dienes Journal of the American Chemical Society. 105: 6123-6129. DOI: 10.1021/Ja00357A025  0.348
1983 Paquette LA, Browne AR, Doecke CW, Williams RV. Short, stereocontrolled synthesis of [4]peristylane Journal of the American Chemical Society. 105: 4113-4115. DOI: 10.1021/Ja00350A072  0.332
1983 Paquette LA, Wells GJ, Horn KA, Yan TH. Silicon in organic synthesis-17. Cyclopentannulation by thermolysis of (1-trimethylsilylcyclopropyl)ethylenes-the 1-trimethylsilylcyclopropyl anion1 1 Part 16. T.-H. Yan and L.A. Paquette, Tetrahedron Letters 3227 (1982) Tetrahedron. 39: 913-924. DOI: 10.1016/S0040-4020(01)88590-2  0.427
1983 Paquette LA, Balogh DW, Ternansky RJ, Begley WJ, Banwell MG. Dissolving-metal reduction of a hemispherical dichloro diester. Tests of relative enolate nucleophilicity within a mixed dianion and oxidative behavior of a trisecododecahedryl alcohol The Journal of Organic Chemistry. 48: 3282-3288. DOI: 10.1002/Chin.198407183  0.356
1982 Paquette LA. Ring inversion and bond shifting energetics in substituted chiral cyclooctatetraenes Pure and Applied Chemistry. 54: 987-1004. DOI: 10.1351/Pac198254050987  0.368
1982 Daniels RG, Paquette LA. Silanes in organic synthesis. 18. Preparation and reactivity of optically active vinyl- and dienylsilanes Organometallics. 14: 1449-1453. DOI: 10.1021/Om00071A007  0.301
1982 Paquette LA, Daniels RG. Silanes in organic synthesis. 15. Silicon-directed hydride abstraction from [2-(trimethylsilyl)-1,3-cyclohexadiene]iron tricarbonyl complexes and nucleophilic addition to the derived cations Organometallics. 1: 757-760. DOI: 10.1021/Om00065A018  0.326
1982 Paquette LA, Klinger F. Electronic control of stereoselectivity. 11. Long-range modulation of stereoselection in Diels-Alder cycloadditions of N-methyltriazolinedione to aryl-substituted 9-allylidenebenzonorbornenes The Journal of Organic Chemistry. 47: 272-275. DOI: 10.1021/Jo00341A017  0.316
1982 Leone-Bay A, Paquette LA. Total synthesis of racemic silphinene Journal of Organic Chemistry. 14: 4173-4174. DOI: 10.1021/Jo00142A037  0.367
1982 Annis GD, Paquette LA. Total synthesis of (.+-.)-pentalenene Journal of the American Chemical Society. 104: 4504-4506. DOI: 10.1021/Ja00380A041  0.357
1982 Paquette LA, Ternansky RJ, Balogh DW. A strategy for the synthesis of monosubstituted dodecahedrane and the isolation of an isododecahedrane Journal of the American Chemical Society. 104: 4502-4503. DOI: 10.1021/Ja00380A039  0.304
1982 Paquette LA, Crouse GD, Sharma AK. Relationship of the anionic behavior of unsaturated medium-ring alcohols to structure. Generation and antarafacial cyclization of coiled 8.pi.-electron carbanions Journal of the American Chemical Society. 104: 4411-4423. DOI: 10.1021/Ja00380A016  0.301
1982 Paquette LA, Balogh DW. An Expedient Synthesis Of 1,16-Dimethyldodecahedrane Journal of the American Chemical Society. 104: 774-783. DOI: 10.1021/Ja00367A021  0.374
1982 Tu-Hsin Y, Paquette LA. Silicon in organic synthesis. 16. A short synthesis of (+±)-α-vetispirene Tetrahedron Letters. 23: 3227-3230. DOI: 10.1016/S0040-4039(00)87576-0  0.33
1982 Paquette LA, Wells GJ, Horn KA, Yan TH. Silicon in organic synthesis. 14. Five ring annulation processes based upon thermal rearrangement of (1-trimethylsilylcyclopropyl)ethylenes Tetrahedron Letters. 23: 263-266. DOI: 10.1016/S0040-4039(00)86804-5  0.415
1982 Paquette LA, Horn KA, Wells GJ. Silicon in organic syntheis. 13. The 1-trimethylsilylcyclopropyl anion and its formal equivalent Tetrahedron Letters. 23: 259-262. DOI: 10.1016/S0040-4039(00)86803-3  0.38
1982 Paquette LA, Kinney WA. A new synthon for the regiospecific γ-alkylation of 2-cyclohexenones. Application to the synthesis of zingiberenol and oxygenated bicycle[3.3.1] nonanes Tetrahedron Letters. 23: 131-134. DOI: 10.1016/S0040-4039(00)86766-0  0.334
1982 Paquette LA, Kinney WA. A vinyl sulfone-mediated diels-alder approach to the fully regiocontrolled elaboration of 4,5-disubstituted 2- and 3-cyclohexenones Tetrahedron Letters. 23: 5127-5130. DOI: 10.1016/S0040-4039(00)85776-7  0.338
1982 Hanzawa Y, Paquette L. Photochemical Preparation Of 5-Tert-Butyl-4-Methoxycarbonyltetracyclo(3.3.0.02,4.03,6)Oct-7-Ene Synthesis. 1982: 661-662. DOI: 10.1002/Chin.198301116  0.345
1981 Crouse GD, Paquette LA. Total synthesis of (.+-.)-multifidene, the gamete attractant of the phaeophyte Cutleria multifida Journal of Organic Chemistry. 13: 4272-4274. DOI: 10.1021/Jo00334A034  0.361
1981 Klobucar WD, Paquette LA, Blount JF. Synthesis of and absolute configurational assignment to enantiomerically pure unsaturated [4.4.2]propellanes Journal of Organic Chemistry. 13: 4021-4030. DOI: 10.1021/Jo00333A017  0.403
1981 Daniels RG, Paquette LA. Silanes in organic synthesis. 10. Cleavage reactions of silylcyclopropanes with titanium tetrachloride and hydrogen chloride Journal of Organic Chemistry. 12: 2901-2910. DOI: 10.1021/Jo00327A013  0.366
1981 Pfeil JL, Kukolja S, Paquette LA. Azetidinone antibiotics. 20. Synthesis of 7.beta.-amido-7.alpha.-methoxy-3-methyl-1-oxacephalosporin The Journal of Organic Chemistry. 46: 827-829. DOI: 10.1021/Jo00317A043  0.301
1981 Paquette LA, Crouse GD. Mild base-promoted conversion of tertiary cis,cis-2,4-cyclononadienols to bicyclo[4.3.1]nona-2,4-dienes. Antarafacial cyclization of coiled 8.pi.-7C conjugated anions Journal of the American Chemical Society. 103: 6235-6236. DOI: 10.1021/Ja00410A052  0.311
1981 Bohm M, Carr R, Gleiter R, Paquette L. Additions and Corrections - Electronic Control of Stereoselectivity. 4. Effects of Neighboring Fused Bicyclic Frameworks on the Stereochemical Outcome of Diels-Alder Cycloadditions to Cyclopentadiene Rings Journal of the American Chemical Society. 103: 2910-2910. DOI: 10.1021/Ja00400A604  0.329
1981 Hanzawa Y, Paquette LA. Bond fixation in annulenes. 12. Effect of vicinal di-tert-butyl substitution on cyclooctatetraene valence isomerization. 7,8-Di-tert-butylbicyclo[4.2.0]octa-2,4,7-triene Journal of the American Chemical Society. 103: 2269-2272. DOI: 10.1021/Ja00399A022  0.353
1981 Paquette LA, Han Y. Total synthesis of (.+-.)-isocomene, a naturally occurring triquinane Journal of the American Chemical Society. 103: 1835-1838. DOI: 10.1021/Ja00397A044  0.354
1981 Daniels RG, Paquette LA. Silanes in organic syuthesis. 11. Regiocontrolled synthesis of α-hydroxymethylated (trimethylsilyl)allenes☆ Tetrahedron Letters. 22: 1579-1582. DOI: 10.1016/S0040-4039(01)90382-X  0.369
1981 Paquette LA, Williams RV. Silicon in organic synthesis. 12. trans-1-benzenesulfonyl-2-(trimethylsilyl)ethylene, a Diels-Alder dienophile equivalent of acetylene and monosubstituted acetylenes Tetrahedron Letters. 22: 4643-4646. DOI: 10.1016/S0040-4039(01)83002-1  0.388
1981 Stevens KE, Paquette LA. Stereocontrolled total synthesis of (±)-Δ9(12)-capnellene Tetrahedron Letters. 22: 4393-4396. DOI: 10.1016/S0040-4039(01)82965-8  0.315
1981 Crouse GD, Paquette LA. Relative kinetic ordering of [1,3]-hydrogen migration, anionic oxy-cope rearrangement, and base-accelerated dehydration in tertiary cyclononatrienyl alkoxides Tetrahedron Letters. 22: 3167-3170. DOI: 10.1016/S0040-4039(01)81854-2  0.337
1981 Paquette LA, Vazeux M. Threefold transannular epoxide cyclization. Synthesis of a heterocyclic C17-hexaquinane Tetrahedron Letters. 22: 291-294. DOI: 10.1016/0040-4039(81)80078-0  0.415
1981 Schostarez H, Paquette LA. Highly stereocontrolled synthesis of [3.3.3] propellane sesquiterpenes. ( ± )-Modhephene and (±)-epimodhephene Tetrahedron. 37: 4431-4435. DOI: 10.1016/0040-4020(81)80009-9  0.366
1981 Paquette LA, Doehner RFJ. Synthesis Of Optically Active Triazolinediones And Examination Of Their Utility For Inducing Asymmetry In Diels-Alder Cycloaddition Reactions Cheminform. 12. DOI: 10.1002/Chin.198115239  0.354
1980 Matsumoto K, Ikemi-Kono Y, Uchida T, Paquette LA. Synthesis and Cycloaddition Reactions of 3-Cyanoindolizines Heterocycles. 14: 103. DOI: 10.3987/R-1980-01-0103  0.399
1980 Fristad W, Bailey T, Paquette L. Additions and Corrections - Silanes in Organic Synthesis. 9. Enesilylation as a Method for 1,2-Carbonyl Migration within Ketones and for the Conversion to 1,2-Transposed Allylic Alcohols. Journal of Organic Chemistry. 45: 5434-5434. DOI: 10.1021/Jo01314A625  0.306
1980 Park H, Paquette LA. Synthesis of the C2v- and S4-symmetric tetraesters of tricyclo[3.3.0.03,7]octane Journal of Organic Chemistry. 12: 5378-5379. DOI: 10.1021/Jo01314A037  0.304
1980 Paquette LA, Doehner RF. Synthesis of optically active triazolinediones and examination of their utility for inducing asymmetry in Diels-Alder cycloaddition reactions Journal of Organic Chemistry. 45: 5105-5113. DOI: 10.1021/Jo01313A018  0.354
1980 Paquette LA, Carr RVC, Arnold E, Clardy J. Electronic control of stereoselectivity. 5. Stereochemistry of singlet oxygen capture by cyclopentadiene rings fused to norbornyl and norbornenyl frameworks The Journal of Organic Chemistry. 45: 4907-4913. DOI: 10.1021/Jo01312A018  0.304
1980 Paquette LA, Fristad WE, Dime DS, Bailey TR. Silanes in organic synthesis. 8. Preparation of vinylsilanes from ketones and their regiospecific cyclopentenone annulation Journal of Organic Chemistry. 11: 3017-3028. DOI: 10.1021/Jo01303A020  0.338
1980 Boehm MC, Carr RVC, Gleiter R, Paquette LA. Electronic control of stereoselectivity. 4. Effects of neighboring fused bicyclic frameworks on the stereochemical outcome of Diels-Alder cycloadditions to cyclopentadiene rings Journal of the American Chemical Society. 102: 7218-7228. DOI: 10.1021/Ja00544A008  0.323
1980 Gree R, Park H, Paquette LA. Regio- and stereoselective 1,2 Wagner-Meerwein shifts during trifluoroacetic acid catalyzed isomerization of unsymmetrically substituted tricyclo[3.2.0.02,4]heptanes Journal of the American Chemical Society. 102: 4397-4403. DOI: 10.1021/Ja00533A018  0.371
1980 Paquette LA, Crouse GD, Sharma AK. A stereocontrolled synthetic entry to the primary prostaglandins from butadiene. Oxy anionic substituent effects on [1,5]-hydrogen sigmatropy Journal of the American Chemical Society. 102: 3972-3974. DOI: 10.1021/Ja00531A060  0.305
1980 Jenkins JA, Doehner RE, Paquette LA. Synthesis and absolute configuration of 4,5-diazatwist-4-ene Journal of the American Chemical Society. 102: 2131-2133. DOI: 10.1021/Ja00526A082  0.389
1980 Paquette LA, Carr RVC, Boehm MC, Gleiter R. Electronic control of stereoselectivity. 3. Stereoselection operative in [4 + 2].pi. cycloadditions to cyclopentadiene rings fused at C2,C3 to bicyclic frameworks Journal of the American Chemical Society. 102: 1186-1188. DOI: 10.1021/Ja00523A058  0.338
1980 Ohkata K, Paquette LA. Geometric dependence to long-range interaction of fused cyclopropane rings in tris-.sigma.-homotropylium cations Journal of the American Chemical Society. 102: 1082-1092. DOI: 10.1021/Ja00523A027  0.309
1980 Paquette LA, Browne AR, Chamot E, Blount JF. Silver(I) catalyzed rearrangements of strained .sigma. bonds. 39. Twofold cyclopropylidene carbon-hydrogen insertion as a route to hexacyclic bis(bicyclo[1.1.0]butanes) and their silver(I) ion promoted rearrangement. A direct synthesis of heptalene from naphthalene Journal of the American Chemical Society. 102: 643-651. DOI: 10.1021/Ja00522A034  0.341
1980 Paquette LA, Chamot E, Browne AR. Silver(I) catalyzed rearrangements of strained .sigma. bonds. 38. Regiospecificity of cyclopropylidene carbon-hydrogen insertion reactions within [m.n.1]propellane frameworks Journal of the American Chemical Society. 102: 637-643. DOI: 10.1021/Ja00522A033  0.318
1980 Ohkata K, Doecke CW, Klein G, Paquette LA. Stereoelectronic effects on cyclobutyl participation. The 10-tetracyclo[5.2.1.02,6.O3,9]decyl cation Tetrahedron Letters. 21: 3253-3256. DOI: 10.1016/S0040-4039(00)78660-6  0.32
1980 Jenkins JA, Doehner REJ, Paquette LA. Synthesis and absolute configuration of 4,5-diazatwist-4-ene Cheminform. 11. DOI: 10.1002/Chin.198025236  0.389
1980 Paquette LA, Browne AR, Chamot E, Blount JF. Silver(I) Ion Catalyzed Rearrangements of Strained σ Bonds. Part 39. Twofold Cyclo-propylidene C-H Insertion as a Route to Hexacyclic Bis(bicyclo[1.1.0]butanes and Their Silver(I) Ion Promoted Rearrangement. A Direct Synthesis of Hept Cheminform. 11. DOI: 10.1002/Chin.198017122  0.344
1980 Paquette LA, Chamot E, Browne AR. Silver(I) Catalyzed Rearrangements Of Strained Σ Bonds. 38. Regiospecificity Of Cyclopropylidene Carbon‐Hydrogen Insertion Reactions Within (M.N.1)Propellane Frameworks Cheminform. 11. DOI: 10.1002/Chin.198017121  0.32
1980 Ku AY, Paquette LA, Rozeboom MD, Houk KN. Polar Effects On Di-Π-Methane Rearrangements. Regiospecificity In The Triplet-Sensitized Photoisomerizations Of 2-Cyanobenzonorbornadienes Carrying Methoxy Aryl Substituents Cheminform. 11. DOI: 10.1002/Chin.198003145  0.33
1979 Matsumoto K, Uchida T, Paquette LA. Synthesis of 3-Cyanoindolizines via Cycloaddition-Extrusion Reactions of Dicyanomethylids with Phenyl Vinyl Sulfoxide Synthesis. 1979: 746-747. DOI: 10.1055/S-1979-28826  0.396
1979 Paquette LA, Wyvratt MJ, Schallner O, Muthard JL, Begley WJ, Blankenship RM, Balogh D. Topologically spherical molecules. Synthesis of a pair of C2-symmetric hexaquinane dilactones and insights into their chemical reactivity. An efficient .pi.-mediated 1,6-dicarbonyl reduction Cheminform. 11: 3616-3630. DOI: 10.1021/Jo01335A003  0.336
1979 Ku AY, Paquette LA, Rozeboom MD, Houk KN. Polar effects on di-.pi.-methane rearrangements. Regiospecificity in the triplet-sensitized photoisomerizations of 2-cyanobenzonorbornadienes carrying methoxy aryl substituents Journal of the American Chemical Society. 101: 5981-5985. DOI: 10.1021/Ja00514A018  0.302
1979 Paquette LA, Ku AY, Santiago C, Rozeboom MD, Houk KN. Control of regioselectivity in the di-.pi.-methane rearrangements. Triplet-sensitized photoisomerization of benzonorbornadienes carrying cyano substituents in the aryl and vinyl segments Journal of the American Chemical Society. 101: 5972-5980. DOI: 10.1021/Ja00514A017  0.319
1979 Paquette LA, Fristad WE, Schuman CA, Beno MA, Christoph GG. Reappraisal of the stereochemistry of electrophilic additions to 3-norcarenes. X-ray and proton NMR analysis of norcarene epoxide conformation. The role of magnetic anisotropic contributions of epoxide rings Journal of the American Chemical Society. 101: 4645-4655. DOI: 10.1021/Ja00510A034  0.309
1979 Gardlik JM, Paquette LA. Bond fixation in annulenes. 7. Direct resolution of chiral cyclooctatetraenes Tetrahedron Letters. 20: 3597-3600. DOI: 10.1016/S0040-4039(01)95473-5  0.318
1979 Paquette LA. The development of polyquinane chemistry Cheminform. 10: 41-165. DOI: 10.1007/Bfb0048476  0.326
1979 Fristad WE, Han Y, Paquette LA. Silanes in organic synthesis: VI. Conversion of unsubstituted and 2-aryl ketones to (1-arylallyl)silanes Cheminform. 10: 27-40. DOI: 10.1002/Chin.197947270  0.397
1979 Paquette LA, Fristad WE, Schuman CA, Beno MA, Christoph GG. Reappraisal Of The Stereochemistry Of Electrophilic Additions To 3-Norcarenes. X-Ray And Proton Nmr Analysis Of Norcarene Epoxide Conformation. The Role O Magnetic Anisotropic Contributions Of Epoxide Rings Cheminform. 10. DOI: 10.1002/Chin.197947093  0.303
1979 Paquette LA, Browne AR, Chamot E. Productive Synthesis Of Heptalene From Naphthalene Via A Bis(Bicyclo(1.1.0)Butane) Derivative Cheminform. 10. DOI: 10.1002/Chin.197943194  0.373
1979 Wells G, Hanzawa Y, Paquette LA. 1,3-Di-Tert-Butylcyclooctatetraene Cheminform. 10. DOI: 10.1002/Chin.197943193  0.323
1979 Fristad WE, Dime DS, Bailey TR, Paquette LA. Silanes In Organic Synthesis. Part 5. Vinylsilane Mediated Regiospecific Cyclopentenone Annulation Of Ketones Cheminform. 10. DOI: 10.1002/Chin.197937176  0.344
1979 Paquette LA, Browne AR, Chamot E. An Expeditious Synthesis of Heptalene from Naphthalene via a Bis(bicyclo[1.1.0]butane) Intermediate Angewandte Chemie. 18: 546-547. DOI: 10.1002/Anie.197905461  0.427
1979 Paquette LA, Browne AR, Chamot E. Ergiebige Synthese von Heptalen aus Naphthalin über ein Bis(bicyclo[1.1.0]butan)‐Derivat Angewandte Chemie. 91: 581-582. DOI: 10.1002/Ange.19790910724  0.306
1979 Wells G, Hanzawa Y, Paquette LA. 1, 3-Di-tert-butylcyclooctatetraen Angewandte Chemie. 91: 578-579. DOI: 10.1002/Ange.19790910722  0.311
1978 Paquette LA, Ewing GD, Ley SV, Berk HC, Traynor SG. Synthesis and reducibility of homo-2-methoxyazocines and their benzo-fused derivatives. An examination of heteroatomic influences on the possible generation of 9C-10.pi. homoaromatic dianions The Journal of Organic Chemistry. 43: 4712-4720. DOI: 10.1021/Jo00419A007  0.487
1978 Chamot E, Paquette LA. Silver(I) ion catalyzed rearrangements of strained .sigma. bonds. 37. Steric inhibition of a silver(I)-catalyzed 1,8-bishomocubana-snoutane rearrangement Journal of Organic Chemistry. 43: 4527-4530. DOI: 10.1021/Jo00417A031  0.303
1978 Fristad WE, Bailey TR, Paquette LA. 1,2-Transposition of ketones via vinylsilanes Journal of Organic Chemistry. 43: 1620-1623. DOI: 10.1021/Jo00402A043  0.372
1978 Detty MR, Paquette LA. Comparative study of syn- and anti-1,5-bishomocycloheptatrien-2-yl radicals and carbocations Journal of Organic Chemistry. 43: 1118-1121. DOI: 10.1021/Jo00400A021  0.509
1978 Taylor RT, Paquette LA. Silver (I) ion catalyzed rearrangements of strained .delta. bonds. 34. A study of the capacity of Group 4 substituents for directing the course of silver(I)-catalyzed tricyclo[4.1.0.02,7]heptane rearrangement into the elusive type .delta. manifold Journal of Organic Chemistry. 43: 242-250. DOI: 10.1021/Jo00396A014  0.336
1978 Paquette LA, Detty MR. Synthesis and protonation studies of syn- and anti-2,4-bishomotropone. Comparison with the behavior of epimeric 2,4-bishomocycloheptatrienols under long- and short-lived ionization conditions Journal of the American Chemical Society. 100: 5856-5863. DOI: 10.1021/Ja00486A043  0.52
1978 Paquette LA, Wyvratt MJ, Berk HC, Moerck RE. Domino Diels-Alder reactions. 6. Domino Diels-Alder cycloadditions to 9,10-dihydrofulvalene and 11,12-dihydrosesquifulvalene. A synthetic tool for the elaboration of polycondensed alicyclic systems Journal of the American Chemical Society. 100: 5845-5855. DOI: 10.1021/Ja00486A042  0.33
1978 Spanget-Larsen J, Gleiter R, Detty MR, Paquette LA. Interaction of Walsh orbitals in trishomocycloheptatrienes and related hydrocarbons Journal of the American Chemical Society. 100: 3005-3014. DOI: 10.1021/Ja00478A012  0.414
1978 Paquette LA, Snow RA, Muthard JL, Cynkowski T. Domino Diels-Alder reactions. 4. C16-Hexaquinacene Journal of the American Chemical Society. 100: 1600-1602. DOI: 10.1021/Ja00473A046  0.334
1978 Paquette LA, Moerck RE, Harirchian B, Magnus PD. Use of phenyl vinyl sulfoxide as an acetylene equivalent in Diels-Alder cycloadditions Journal of the American Chemical Society. 100: 1597-1599. DOI: 10.1021/Ja00473A044  0.343
1978 Paquette LA, Detty MR. The rhodium (I)-catalyzed rearraugememt of syn-1,3-bishomocycloheptatriene Tetrahedron Letters. 19: 713-716. DOI: 10.1016/S0040-4039(01)85374-0  0.596
1978 Paquette LA, Grée R. Rhodium(I) catalysis of cycloprop[a]acenaphthylene isomerizations Journal of Organometallic Chemistry. 146: 319-329. DOI: 10.1016/S0022-328X(00)88759-8  0.35
1978 Paquette LA, Bunson RL. Substituent influences on the cope equilibrium in semibullvalene Tetrahedron. 34: 1301-1306. DOI: 10.1016/0040-4020(78)88323-9  0.343
1978 SPANGET-LARSEN J, GLEITER R, DETTY MR, PAQUETTE LA. ChemInform Abstract: INTERACTION OF WALSH ORBITALS IN TRISHOMOCYCLOHEPTATRIENES AND RELATED HYDROCARBONS Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197834048  0.435
1977 Paquette LA, Wallis TG, Kempe T, Christoph GG, Springer JP, Clardy J. Silver(I) ion catalyzed rearrangements of strained .sigma. bonds. 33. Benzoannulation as a probe of structural dimension and .pi.-electron distribution in elassovalenes. A mathematical model for the assessment of homoaromaticity Journal of the American Chemical Society. 99: 6946-6954. DOI: 10.1021/Ja00463A029  0.332
1977 Paquette L, Carmody M. Additions and Corrections - Thermally Promoted Ring Cleavage Reactions of Stereoisomeric Tetracyclo[4.3.0.02,5.07,9]non-3-enes. Pentacycl[5.3.0.02,6.03,5.08,10]decanes and Their Epoxide Counterparts Journal of the American Chemical Society. 99: 6153-6153. DOI: 10.1021/Ja00460A601  0.365
1977 Paquette LA, Taylor RT. The consequences of methyl substitution on the efficiency and regioselectivity of C-H insertion during intramolecular cyclization of norcaran-7-, 3-norcaren-7-, and tricyclo[5.1.0.03,5]octan-8-ylidenes Journal of the American Chemical Society. 99: 5708-5715. DOI: 10.1021/Ja00459A031  0.358
1977 Paquette LA, Kukla MJ, Ley SV, Traynor SG. The question of delocalization in "anchored" ions with potential trishomoaromatic character. 1. Reduction of tricyclo[5.4.1.04,12]dodeca-2,5,8,10-tetraene as a route to the 10.pi.11C dianion Journal of the American Chemical Society. 99: 4756-4763. DOI: 10.1021/Ja00456A037  0.416
1977 Paquette LA, Wallis TG, Hirotsu K, Clardy J. Stereospecific [3,3] shift of a cyclobutene ring involving photofragmentation of a 1,8-bishomocubane as the relay Journal of the American Chemical Society. 99: 2815-2816. DOI: 10.1021/Ja00450A077  0.375
1977 Detty MR, Paquette LA. The fate of bishomocycloheptadienyl cations generated by deamination Journal of the American Chemical Society. 99: 834-842. DOI: 10.1021/Ja00445A028  0.511
1977 Paquette LA, Detty MR. Stereoisomeric bishomo-3,5-cycloheptadienyl p-toluenesulfonates as probes of the geometric and conformational dependence to long-range cyclopropyl interaction during acetolysis Journal of the American Chemical Society. 99: 828-834. DOI: 10.1021/Ja00445A027  0.49
1977 Detty MR, Paquette LA. The question of hexahomobenzene automerization. New synthetic approaches to cis3-1,4,7-cyclononatriene Tetrahedron Letters. 18: 347-350. DOI: 10.1016/S0040-4039(01)92633-4  0.503
1977 Taylor RT, Degenhardt CR, Melega WP, Paquette LA. Direct conversion of ketones to vinylsilanes, -germanes, and -stannanes Tetrahedron Letters. 18: 159-162. DOI: 10.1016/S0040-4039(01)92576-6  0.345
1977 Detty MR, Paquette LA. The Fate Of Bishomocycloheptadienyl Cations Generated By Deamination Cheminform. 8. DOI: 10.1002/Chin.197717133  0.511
1977 PAQUETTE LA, DETTY MR. ChemInform Abstract: STEREOISOMERIC BISHOMO-3,5-CYCLOHEPTADIENYL P-TOLUENESULFONATES AS PROBES OF THE GEOMETRIC AND CONFORMATIONAL DEPENDENCE TO LONG-RANGE CYCLOPROPYL INTERACTION DURING ACETOLYSIS Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197717093  0.442
1977 PAQUETTE LA, LEY SV, TRAYNOR SG, MARTIN JT, GECKLE JM. ChemInform Abstract: FORMATION OF MONOHOMOCYCLOOCTATETRAENE DIANIONS IN LIQUID AMMONIA. ANALYSIS OF THE NUCLEOPHILIC REACTIVITY OF THE CYCLONONATRIENYL ANIONS GENERATED UPO SOLVENT PROTONATION Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197710132  0.429
1976 Paquette LA, Klobucar WD, Snow RA. Halothiation as a Method for Oxidation of Primary Halides and Terminal Olefins to Aldehydes Synthetic Communications. 6: 575-581. DOI: 10.1080/00397917608063551  0.394
1976 Paquette LA, Itoh I, Lipkowitz KB. Synthesis and reactivity patterns of meso- and dl-bistriquinacene. Efficient route to the diastereomeric bivalvanes Journal of Organic Chemistry. 41: 3524-3529. DOI: 10.1021/Jo00884A007  0.336
1976 Paquette LA, Carmody MJ. Thermally promoted ring cleavage reactions of stereoisomeric tetracyclo[4.3.0.02,5.07,9]non-3-enes, pentacyclo[5.3.0.02,6.03,5.08,10]decanes, and their epoxide counterparts Journal of the American Chemical Society. 98: 8175-8181. DOI: 10.1021/Ja00441A048  0.36
1976 Paquette LA, Ley SV, Traynor SG, Martin JT, Geckle JM. Formation of monohomocyclooctatetraene dianions in liquid ammonia. Analysis of the nucleophilic reactivity of the cyclononatrienyl anions generated upon solvent protonation Journal of the American Chemical Society. 98: 8162-8172. DOI: 10.1021/Ja00441A046  0.419
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