Year |
Citation |
Score |
2024 |
Kaplan JA, Won J, Blum SA. Thioarylation of Alkynes to Generate Dihydrothiopheniums through Gold(I)/(III)-Catalyzed Cyclization-Cross-Coupling. The Journal of Organic Chemistry. 89: 14384-14398. PMID 39276336 DOI: 10.1021/acs.joc.4c01777 |
0.346 |
|
2024 |
Peacock H, Blum SA. Buildup and Consumption of Species in Emulsion Droplets during Aqueous Suzuki Coupling Correlate with Yield. The Journal of Organic Chemistry. PMID 39016689 DOI: 10.1021/acs.joc.4c00918 |
0.395 |
|
2024 |
Zhang Y, Blum SA. Surfactant-Dependent Partitioning of Organics in Aqueous-Organic Reaction Systems. The Journal of Organic Chemistry. 89: 8267-8271. PMID 38752624 DOI: 10.1021/acs.joc.4c00613 |
0.329 |
|
2023 |
Hanada E, Lou H, McShea PJ, Blum SA. Metal Activation Produces Different Reaction Environments for Intermediates during Oxidative Addition. Chemistry (Weinheim An Der Bergstrasse, Germany). e202304105. PMID 38109441 DOI: 10.1002/chem.202304105 |
0.344 |
|
2023 |
Stang M, Mycka RJ, Blum SA. Mechanistic Insight from Lewis-Acid-Dependent Selectivity and Reversible Haloboration, as Harnessed for Boron-Based Electrophilic Cyclization Reactions. The Journal of Organic Chemistry. 88: 15159-15167. PMID 37877549 DOI: 10.1021/acs.joc.3c01653 |
0.413 |
|
2023 |
Hanada EM, McShea PJ, Blum SA. Trimethylsilyl Chloride Aids in Solubilization of Oxidative Addition Intermediates from Zinc Metal. Angewandte Chemie (International Ed. in English). 62: e202307787. PMID 37672719 DOI: 10.1002/anie.202307787 |
0.335 |
|
2023 |
Kaplan JA, Blum SA. Iodination-Group-Transfer Reactions to Generate Trisubstituted Iodoalkenes with Regio- and Stereochemical Control. The Journal of Organic Chemistry. PMID 37656489 DOI: 10.1021/acs.joc.3c01495 |
0.332 |
|
2023 |
Peacock H, Blum SA. Surfactant Micellar and Vesicle Microenvironments and Structures under Synthetic Organic Conditions. Journal of the American Chemical Society. 145: 7648-7658. PMID 36951303 DOI: 10.1021/jacs.3c01574 |
0.33 |
|
2022 |
Peacock H, Blum SA. Single-Micelle and Single-Zinc-Particle Imaging Provides Insights into the Physical Processes Underpinning Organozinc Reactions in Water. Journal of the American Chemical Society. 144: 3285-3296. PMID 35156815 DOI: 10.1021/jacs.2c00421 |
0.317 |
|
2021 |
Kaplan JA, Issaian A, Stang M, Gorial D, Blum SA. Repurposing π Electrophilic Cyclization/Dealkylation for Group Transfer. Angewandte Chemie (International Ed. in English). PMID 34585500 DOI: 10.1002/anie.202112351 |
0.373 |
|
2020 |
Jess K, Hanada EM, Peacock H, Blum SA. Origins of Batch-to-Batch Variation: Organoindium Reagents from Indium Metal. Organometallics. 39: 2575-2579. PMID 33692605 DOI: 10.1021/Acs.Organomet.0C00417 |
0.375 |
|
2020 |
Gao C, Nakao S, Blum SA. Borylative Heterocyclization without Air-Free Techniques. The Journal of Organic Chemistry. PMID 32672462 DOI: 10.1021/Acs.Joc.0C01096 |
0.446 |
|
2020 |
Hanada EM, Jess K, Blum SA. Mechanism of an Elusive Solvent Effect in Organozinc Reagent Synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32378257 DOI: 10.1002/Chem.202002214 |
0.454 |
|
2019 |
Easter QT, Blum SA. Organic and Organometallic Chemistry at the Single-Molecule, -Particle, and -Molecular-Catalyst-Turnover Level by Fluorescence Microscopy. Accounts of Chemical Research. PMID 31310095 DOI: 10.1021/Acs.Accounts.9B00219 |
0.52 |
|
2019 |
Jess K, Kitagawa K, Tagawa TKS, Blum SA. Microscopy Reveals: Impact of Lithium Salts on Elementary Steps Predicts Organozinc Reagent Synthesis and Structure. Journal of the American Chemical Society. PMID 31188579 DOI: 10.1021/Jacs.9B02639 |
0.426 |
|
2019 |
Tu KN, Kim S, Blum SA. Copper-Catalyzed Aminoboration from Hydrazones To Generate Borylated Pyrazoles. Organic Letters. PMID 30753081 DOI: 10.1021/Acs.Orglett.8B04038 |
0.484 |
|
2019 |
Easter QT, Garcia A, Blum SA. Single-Polymer–Particle Growth Kinetics with Molecular Catalyst Speciation and Single-Turnover Imaging Acs Catalysis. 9: 3375-3383. DOI: 10.1021/Acscatal.9B00095 |
0.396 |
|
2018 |
Bel Abed H, Blum SA. Transition-Metal-Free Synthesis of Borylated Thiophenes via Formal Thioboration. Organic Letters. 20: 6673-6677. PMID 30350646 DOI: 10.1021/Acs.Orglett.8B02727 |
0.416 |
|
2018 |
Tu KN, Gao C, Blum SA. An Oxyboration Route to a Single Regioisomer of Borylated Dihydrofurans and Isochromenes. The Journal of Organic Chemistry. PMID 30044636 DOI: 10.1021/Acs.Joc.8B01790 |
0.466 |
|
2018 |
Easter QT, Blum SA. Kinetics of the Same Reaction over Nine Orders of Magnitude in Concentration: When Are Unique Subensemble and Single-Turnover Reactivity Displayed? Angewandte Chemie (International Ed. in English). PMID 29962079 DOI: 10.1002/Anie.201807317 |
0.474 |
|
2017 |
Easter QT, Blum SA. Evidence for Dynamic Chemical Kinetics at Individual Ruthenium Catalysts. Angewandte Chemie (International Ed. in English). PMID 29240972 DOI: 10.1002/Anie.201711314 |
0.454 |
|
2017 |
Issaian A, Tu KN, Blum SA. Boron-Heteroatom Addition Reactions via Borylative Heterocyclization: Oxyboration, Aminoboration, and Thioboration. Accounts of Chemical Research. PMID 28933550 DOI: 10.1021/Acs.Accounts.7B00365 |
0.521 |
|
2017 |
Blum SA, Easter QT. Single Turnover at Molecular Polymerization Catalysts Reveals Spatiotemporally Resolved Reactions. Angewandte Chemie (International Ed. in English). PMID 28892589 DOI: 10.1002/Anie.201708284 |
0.426 |
|
2017 |
Issaian A, Faizi DJ, Bailey JO, Mayer P, Berionni G, Singleton DA, Blum SA. Mechanistic Studies of Formal Thioboration Reactions of Alkynes. The Journal of Organic Chemistry. PMID 28671461 DOI: 10.1021/Acs.Joc.7B01500 |
0.491 |
|
2017 |
Kitagawa K, Blum SA. Structure–Reactivity Studies of Intermediates for Mechanistic Information by Subensemble Fluorescence Microscopy Acs Catalysis. 7: 3786-3791. DOI: 10.1021/Acscatal.7B00627 |
0.302 |
|
2017 |
Feng C, Easter QT, Blum SA. Structure–Reactivity Studies, Characterization, and Transformation of Intermediates by Lithium Chloride in the Direct Insertion of Alkyl and Aryl Iodides to Metallic Zinc Powder Organometallics. 36: 2389-2396. DOI: 10.1021/Acs.Organomet.6B00910 |
0.46 |
|
2016 |
Johnson JS, Chong E, Tu KN, Blum SA. Kinetic Study of Carbophilic Lewis Acid Catalyzed Oxyboration and the Noninnocent Role of Sodium Chloride. Organometallics. 35: 655-662. PMID 31007335 DOI: 10.1021/Acs.Organomet.5B00939 |
0.659 |
|
2016 |
Faizi DJ, Davis AJ, Meany FB, Blum SA. Catalyst-Free Formal Thioboration to Synthesize Borylated Benzothiophenes and Dihydrothiophenes. Angewandte Chemie (International Ed. in English). PMID 27735114 DOI: 10.1002/Anie.201608090 |
0.436 |
|
2016 |
Feng C, Cunningham DW, Easter QT, Blum SA. Role of LiCl in Generating Soluble Organozinc Reagents. Journal of the American Chemical Society. PMID 27547857 DOI: 10.1021/Jacs.6B08465 |
0.374 |
|
2016 |
Faizi DJ, Issaian A, Davis AJ, Blum SA. Catalyst-Free Synthesis of Borylated Lactones from Esters via Electrophilic Oxyboration. Journal of the American Chemical Society. PMID 26849770 DOI: 10.1021/Jacs.5B12989 |
0.389 |
|
2016 |
Tu KN, Hirner JJ, Blum SA. Oxyboration with and without a Catalyst: Borylated Isoxazoles via B-O σ-Bond Addition. Organic Letters. PMID 26771389 DOI: 10.1021/Acs.Orglett.5B03530 |
0.4 |
|
2015 |
Hirner JJ, Blum SA. NMR spectroscopy studies of electronic effects and equilibrium in the organogold-to-boron transmetalation reaction and studies towards its application to the alkoxyboration addition of boron-oxygen σ bonds to alkynes. Tetrahedron. 71: 4445-4449. PMID 30344348 DOI: 10.1016/J.Tet.2015.04.019 |
0.491 |
|
2015 |
Chong E, Blum SA. Aminoboration: Addition of B-N σ Bonds across C-C π Bonds. Journal of the American Chemical Society. PMID 26238962 DOI: 10.1021/Jacs.5B06678 |
0.582 |
|
2015 |
Easter QT, Trauschke V, Blum SA. Catalyst Inefficiencies: Supported Ring-Opening Metathesis Polymerization Catalyst Yields Its Ensemble Rate from a Small Number of Molecular Active Sites Acs Catalysis. 5: 2290-2295. DOI: 10.1021/Acscatal.5B00046 |
0.377 |
|
2014 |
Al-Amin M, Johnson JS, Blum SA. Selectivity, Compatibility, Downstream Functionalization, and Silver Effect in the Gold and Palladium Dual-Catalytic Synthesis of Lactones. Organometallics. 33: 5448-5456. PMID 25328271 DOI: 10.1021/Om500747M |
0.605 |
|
2014 |
Al-Amin M, Roth KE, Blum SA. Mechanistic Studies of Gold and Palladium Cooperative Dual-Catalytic Cross-Coupling Systems. Acs Catalysis. 4: 622-629. PMID 24757581 DOI: 10.1021/Cs400641K |
0.46 |
|
2014 |
Blum SA. Location change method for imaging chemical reactivity and catalysis with single-molecule and -particle fluorescence microscopy. Physical Chemistry Chemical Physics : Pccp. 16: 16333-9. PMID 24695617 DOI: 10.1039/C4Cp00353E |
0.484 |
|
2014 |
Hirner JJ, Faizi DJ, Blum SA. Alkoxyboration: ring-closing addition of B-O σ bonds across alkynes. Journal of the American Chemical Society. 136: 4740-5. PMID 24588331 DOI: 10.1021/Ja500463P |
0.381 |
|
2014 |
Hensle EM, Esfandiari NM, Lim S, Blum SA. BODIPY Fluorophore Toolkit for Probing Chemical Reactivity and for Tagging Reactive Functional Groups (Eur. J. Org. Chem. 16/2014) European Journal of Organic Chemistry. 2014. DOI: 10.1002/Ejoc.201490042 |
0.325 |
|
2014 |
Hensle EM, Esfandiari NM, Lim SG, Blum SA. Bodipy fluorophore toolkit for probing chemical reactivity and for tagging reactive functional groups European Journal of Organic Chemistry. 2014: 3347-3354. DOI: 10.1002/Ejoc.201400052 |
0.688 |
|
2013 |
Cordes T, Blum SA. Opportunities and challenges in single-molecule and single-particle fluorescence microscopy for mechanistic studies of chemical reactions. Nature Chemistry. 5: 993-9. PMID 24256861 DOI: 10.1038/Nchem.1800 |
0.473 |
|
2013 |
Hensle EM, Blum SA. Phase separation polymerization of dicyclopentadiene characterized by in operando fluorescence microscopy. Journal of the American Chemical Society. 135: 12324-8. PMID 23885895 DOI: 10.1021/Ja405283K |
0.391 |
|
2013 |
Fast A, Esfandiari NM, Blum SA. Small number of active sites and single-locus kinetics revealed in (salph)co-catalyzed ethylene oxide polymerization Acs Catalysis. 3: 2150-2153. DOI: 10.1021/Cs400640G |
0.589 |
|
2012 |
Hirner JJ, Roth KE, Shi Y, Blum SA. Mechanistic Studies of Azaphilic versus Carbophilic Activation by Gold(I) in the Gold/Palladium Dual-Catalyzed Rearrangement of Alkenyl Vinyl Aziridines. Organometallics. 31: 6843-6850. PMID 24465074 DOI: 10.1021/Om300671J |
0.52 |
|
2012 |
Cornell TP, Shi Y, Blum SA. Synthesis of alkenylgold(I) compounds via sequential hydrozirconation and zirconium to gold transmetalation Organometallics. 31: 5990-5993. DOI: 10.1021/Om300639H |
0.512 |
|
2012 |
Gladysz JA, Ball ZT, Bertrand G, Blum SA, Dong VM, Dorta R, Hahn FE, Humphrey MG, Jones WD, Klosin J, Manners I, Marks TJ, Mayer JM, Rieger B, Ritter JC, et al. Organometallics roundtable 2011 Organometallics. 31: 1-18. DOI: 10.1021/Om201234X |
0.7 |
|
2011 |
Esfandiari NM, Blum SA. Homogeneous vs heterogeneous polymerization catalysis revealed by single-particle fluorescence microscopy. Journal of the American Chemical Society. 133: 18145-7. PMID 22007973 DOI: 10.1021/Ja2085405 |
0.59 |
|
2011 |
Esfandiari NM, Wang Y, Bass JY, Blum SA. Deconvoluting subensemble chemical reaction kinetics of platinum-sulfur ligand exchange detected with single-molecule fluorescence microscopy. Inorganic Chemistry. 50: 9201-3. PMID 21863905 DOI: 10.1021/Ic2007952 |
0.787 |
|
2011 |
Hirner JJ, Shi Y, Blum SA. Organogold reactivity with palladium, nickel, and rhodium: transmetalation, cross-coupling, and dual catalysis. Accounts of Chemical Research. 44: 603-13. PMID 21644576 DOI: 10.1021/Ar200055Y |
0.606 |
|
2011 |
Roth KE, Blum SA. Direct observation of gold/palladium transmetalation in an organogold heck reaction Organometallics. 30: 4811-4813. DOI: 10.1021/Om2006886 |
0.535 |
|
2011 |
Shi Y, Blum SA. Gold and rhodium transmetalation: Mechanistic insights and dual-metal reactivity Organometallics. 30: 1776-1779. DOI: 10.1021/Om2001316 |
0.566 |
|
2011 |
Hirner JJ, Blum SA. Nickel-catalyzed cross-coupling of organogold reagents Organometallics. 30: 1299-1302. DOI: 10.1021/Om200060X |
0.406 |
|
2011 |
Esfandiari NM, Wang Y, McIntire TM, Blum SA. Real-time imaging of platinum-sulfur ligand exchange reactions at the single-molecule level via a general chemical technique Organometallics. 30: 2901-2907. DOI: 10.1021/Om100911N |
0.694 |
|
2010 |
Esfandiari NM, Wang Y, Bass JY, Cornell TP, Otte DA, Cheng MH, Hemminger JC, McIntire TM, Mandelshtam VA, Blum SA. Single-molecule imaging of platinum ligand exchange reaction reveals reactivity distribution. Journal of the American Chemical Society. 132: 15167-9. PMID 20731349 DOI: 10.1021/Ja105517D |
0.782 |
|
2010 |
Roth KE, Blum SA. Relative kinetic basicities of organogold compounds Organometallics. 29: 1712-1716. DOI: 10.1021/Om901101F |
0.308 |
|
2009 |
Shi Y, Roth KE, Ramgren SD, Blum SA. Catalyzed catalysis using carbophilic Lewis acidic gold and Lewis basic palladium: synthesis of substituted butenolides and isocoumarins. Journal of the American Chemical Society. 131: 18022-3. PMID 19929002 DOI: 10.1021/Ja9068497 |
0.582 |
|
2009 |
Lim SG, Blum SA. A general fluorescence resonance energy transfer (FRET) method for observation and quantification of organometallic complexes under reaction conditions Organometallics. 28: 4643-4645. DOI: 10.1021/Om900629S |
0.4 |
|
2009 |
Yili S, Ramgren SD, Blum SA. Palladium-catalyzed carboauration of alkynes and palladi cross-coupling Organometallics. 28: 1275-1277. DOI: 10.1021/Om801206G |
0.429 |
|
2008 |
Shi Y, Peterson SM, Haberaecker WW, Blum SA. Alkynes as Stille reaction pseudohalides: gold- and palladium-cocatalyzed synthesis of tri- and tetra-substituted olefins. Journal of the American Chemical Society. 130: 2168-9. PMID 18229930 DOI: 10.1021/Ja710648B |
0.623 |
|
2008 |
Canham SM, Bass JY, Navarro O, Lim SG, Das N, Blum SA. Toward the single-molecule investigation of organometallic reaction mechanisms: Single-molecule imaging of fluorophore-tagged palladium(II) complexes Organometallics. 27: 2172-2175. DOI: 10.1021/Om800228V |
0.757 |
|
2005 |
Blum SA, Rivera VA, Ruck RT, Michael FE, Bergman RG. Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes. Organometallics. 24: 1647-1659. PMID 16508693 DOI: 10.1021/Om049105R |
0.722 |
|
2005 |
Lalic G, Blum SA, Bergman RG. Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic amines. Journal of the American Chemical Society. 127: 16790-1. PMID 16316217 DOI: 10.1021/Ja056132F |
0.726 |
|
2004 |
Blum SA, Bergman RG. Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes. Organometallics. 23: 4003-4005. PMID 16508695 DOI: 10.1021/Om0495776 |
0.569 |
|
2004 |
Blum SA, Walsh PJ, Bergman RG. Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes [J. Am. Chem. Soc.2003,125, 14276−14277]. Journal of the American Chemical Society. 126: 9148-9148. DOI: 10.1021/Ja0408146 |
0.618 |
|
2003 |
Blum SA, Walsh PJ, Bergman RG. Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes. Journal of the American Chemical Society. 125: 14276-7. PMID 14624566 DOI: 10.1021/Ja037267T |
0.619 |
|
2003 |
Blum SA, Tan KL, Bergman RG. Application of physical organic methods to the investigation of organometallic reaction mechanisms. The Journal of Organic Chemistry. 68: 4127-37. PMID 12762711 DOI: 10.1021/Jo034198S |
0.696 |
|
2003 |
Blum SA, Bergman RG, Ellman JA. Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation. The Journal of Organic Chemistry. 68: 150-5. PMID 12515473 DOI: 10.1021/Jo0205560 |
0.647 |
|
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