D. Michael Heinekey - Publications

Affiliations: 
1985-1992 Chemistry Yale University, New Haven, CT 
 1992- Chemistry University of Washington, Seattle, Seattle, WA 
Area:
transition metal organometallic chemistry
Website:
http://depts.washington.edu/chem/people/faculty/heinekey.html

84 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Lekich TT, Gary JB, Bellows SM, Cundari TR, Guard LM, Heinekey DM. H addition to (PCP)Ir(CO): studies of the isomerization mechanism. Dalton Transactions (Cambridge, England : 2003). PMID 30377682 DOI: 10.1039/C8Dt02861C  0.344
2017 Goldberg JM, Goldberg KI, Heinekey DM, Burgess SA, Lao DB, Linehan JC. Detection of an Iridium-Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation. Journal of the American Chemical Society. PMID 28862847 DOI: 10.1021/Jacs.7B06480  0.82
2017 Guard LM, Hebden TJ, Linn DE, Heinekey DM. Pincer-Supported Carbonyl Complexes of Cobalt(I) Organometallics. 36: 3104-3109. DOI: 10.1021/Acs.Organomet.7B00434  0.834
2017 Goldberg JM, Berman JL, Kaminsky W, Goldberg KI, Heinekey DM. Oxidative addition of iodine to (tBu)4(POCOP)Ir(CO) complexes Journal of Organometallic Chemistry. 845: 171-176. DOI: 10.1016/J.Jorganchem.2017.04.036  0.787
2016 Brewster TP, Goldberg JM, Tran JC, Heinekey DM, Goldberg KI. High Catalytic Efficiency Combined with High Selectivity for the Aldehyde-Water Shift Reaction using (para-cymene)Ruthenium Precatalysts Acs Catalysis. 6: 6302-6305. DOI: 10.1021/Acscatal.6B02130  0.734
2016 Goldberg JM, Cherry SDT, Guard LM, Kaminsky W, Goldberg KI, Heinekey DM. Hydrogen Addition to (pincer)IrI(CO) Complexes: The Importance of Steric and Electronic Factors Organometallics. 35: 3546-3556. DOI: 10.1021/Acs.Organomet.6B00598  0.783
2015 Connelly SJ, Chanez AG, Kaminsky W, Heinekey DM. Characterization of a palladium dihydrogen complex. Angewandte Chemie (International Ed. in English). 54: 5915-8. PMID 25783481 DOI: 10.1002/anie.201412076  0.463
2015 Lehman MC, Pahls DR, Meredith JM, Sommer RD, Heinekey DM, Cundari TR, Ison EA. Oxyfunctionalization with Cp*Ir(III)(NHC)(Me)(Cl) with O₂: identification of a rare bimetallic Ir(IV) μ-oxo intermediate. Journal of the American Chemical Society. 137: 3574-84. PMID 25700811 DOI: 10.1021/Ja512905T  0.645
2015 Goldberg JM, Wong GW, Brastow KE, Kaminsky W, Goldberg KI, Heinekey DM. The importance of steric factors in iridium pincer complexes Organometallics. 34: 753-762. DOI: 10.1021/Om501166W  0.772
2014 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Regeneration of an Iridium(III) complex active for alkane dehydrogenation using molecular oxygen Organometallics. 33: 1337-1340. DOI: 10.1021/Om401241E  0.544
2014 Brewster TP, Ou WC, Tran JC, Goldberg KI, Hanson SK, Cundari TR, Heinekey DM. Iridium, rhodium, and ruthenium catalysts for the "aldehyde-water shift" reaction Acs Catalysis. 4: 3034-3038. DOI: 10.1021/Cs500843A  0.63
2013 Brewster TP, Miller AJ, Heinekey DM, Goldberg KI. Hydrogenation of carboxylic acids catalyzed by half-sandwich complexes of iridium and rhodium. Journal of the American Chemical Society. 135: 16022-5. PMID 24144194 DOI: 10.1021/Ja408149N  0.627
2013 Miller AJ, Heinekey DM, Mayer JM, Goldberg KI. Catalytic disproportionation of formic acid to generate methanol. Angewandte Chemie (International Ed. in English). 52: 3981-4. PMID 23450724 DOI: 10.1002/Anie.201208470  0.509
2013 O'Connor AR, Kaminsky W, Chan BC, Heinekey DM, Goldberg KI. Synthesis and characterization of iridium(I) and iridium(III) complexes containing dialkylbiphenylphosphines Organometallics. 32: 4016-4019. DOI: 10.1021/Om400266D  0.656
2013 Allen KE, Heinekey DM, Goldman AS, Goldberg KI. Alkane dehydrogenation by C-H activation at iridium(III) Organometallics. 32: 1579-1582. DOI: 10.1021/Om301267C  0.584
2013 Lao DB, Owens ACE, Heinekey DM, Goldberg KI. Partial deoxygenation of glycerol catalyzed by iridium pincer complexes Acs Catalysis. 3: 2391-2396. DOI: 10.1021/Cs400551G  0.653
2013 St. John A, Goldberg KI, Heinekey DM. Pincer complexes as catalysts for amine borane dehydrogenation Topics in Organometallic Chemistry. 40: 271-288. DOI: 10.1007/978-3-642-31081-2-9  0.639
2012 Connelly SJ, Zimmerman AC, Kaminsky W, Heinekey DM. Synthesis, structure, and reactivity of a nickel dihydrogen complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 15932-4. PMID 23138965 DOI: 10.1002/chem.201203675  0.47
2012 Findlater M, Schultz KM, Bernskoetter WH, Cartwright-Sykes A, Heinekey DM, Brookhart M. Dihydrogen complexes of iridium and rhodium. Inorganic Chemistry. 51: 4672-8. PMID 22364621 DOI: 10.1021/Ic202630X  0.721
2012 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. η6-tetramethylfulvene and μ-η3: η3-benzene complexes of iridium Organometallics. 31: 8459-8462. DOI: 10.1021/Om3010492  0.754
2012 Meredith JM, Robinson R, Goldberg KI, Kaminsky W, Heinekey DM. C-H bond activation by cationic iridium(III) NHC complexes: A combined experimental and computational study Organometallics. 31: 1879-1887. DOI: 10.1021/Om2012166  0.788
2012 Ahmed Foskey TJ, Heinekey DM, Goldberg KI. Partial deoxygenation of 1,2-propanediol catalyzed by iridium pincer complexes Acs Catalysis. 2: 1285-1289. DOI: 10.1021/Cs300120D  0.684
2011 Hebden TJ, St John AJ, Gusev DG, Kaminsky W, Goldberg KI, Heinekey DM. Preparation of a dihydrogen complex of cobalt. Angewandte Chemie (International Ed. in English). 50: 1873-6. PMID 21328660 DOI: 10.1002/Anie.201005281  0.839
2011 Schultz KM, Goldberg KI, Gusev DG, Heinekey DM. Synthesis, structure, and reactivity of iridium NHC pincer complexes Organometallics. 30: 1429-1437. DOI: 10.1021/Om101024X  0.817
2011 O'Connor AR, Kaminsky W, Heinekey DM, Goldberg KI. Synthesis, characterization, and reactivity of arene-stabilized rhodium complexes Organometallics. 30: 2105-2116. DOI: 10.1021/Om1009473  0.663
2011 Heinekey DM, Goldberg KI, Ahmed TJ, Camp ER. Catalytic hydrogenolysis of glycerol Acs National Meeting Book of Abstracts 0.549
2011 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. (η5-C5Me5)IrIII(N-heterocyclic carbene) complexes for catalytic alkane oxidation Acs National Meeting Book of Abstracts 0.728
2010 Hebden TJ, Goldberg KI, Heinekey DM, Zhang X, Emge TJ, Goldman AS, Krogh-Jespersen K. Dihydrogen/dihydride or tetrahydride? An experimental and computational investigation of pincer iridium polyhydrides. Inorganic Chemistry. 49: 1733-42. PMID 20095648 DOI: 10.1021/Ic902163W  0.821
2010 Egbert JD, Heinekey DM. Dihydrogen complexes of the chromium group: Synthesis and characterization of (Arene)M(CO)2(H2) complexes Organometallics. 29: 3387-3391. DOI: 10.1021/Om100416W  0.811
2009 Fantasia S, Egbert JD, Jurcík V, Cazin CS, Jacobsen H, Cavallo L, Heinekey DM, Nolan SP. Activation of hydrogen by palladium(0): formation of the mononuclear dihydride complex trans-[Pd(H)2(IPr)(PCy3)]. Angewandte Chemie (International Ed. in English). 48: 5182-6. PMID 19526472 DOI: 10.1002/Anie.200900463  0.756
2009 Meredith JM, Goldberg KI, Kaminsky W, Heinekey DM. Dinuclear iridium complexes containing cp * and carbonyl ligands: synthesis, structure, and reactivity Organometallics. 28: 3546-3551. DOI: 10.1021/Om900186J  0.799
2009 Hebden TJ, Piccoli PMB, Koetzle TF, Schultz AJ, Goldberg KI, Heinekey DM, Emge TJ, Krogh-Jespersen K, Goldman AS. Structural investigations of Ir pincer complexes relevant to catalytic H2 release from the chemical hydrogen storage material H3BNH3 Acs National Meeting Book of Abstracts 0.814
2009 Heinekey DM, Hebden TJ, Matthews SL, Goldberg KI, Dietrich BL, St John AJ. Dehydrogenation catalysts for BN and CBN hydrogen storage materials Acs National Meeting Book of Abstracts 0.764
2008 Dietrich BL, Goldberg KI, Heinekey DM, Autrey T, Linehan JC. Iridium-catalyzed dehydrogenation of substituted amine boranes: kinetics, thermodynamics, and implications for hydrogen storage. Inorganic Chemistry. 47: 8583-5. PMID 18785732 DOI: 10.1021/Ic801161G  0.666
2008 Hebden TJ, Denney MC, Pons V, Piccoli PM, Koetzle TF, Schultz AJ, Kaminsky W, Goldberg KI, Heinekey DM. Sigma-borane complexes of iridium: synthesis and structural characterization. Journal of the American Chemical Society. 130: 10812-20. PMID 18642912 DOI: 10.1021/Ja801898M  0.822
2008 Brayton DF, Goldberg KI, Kaminsky W, Heinekey DM. A convenient one-pot synthesis of Di-t-butylphosphinic chloride Phosphorus, Sulfur and Silicon and the Related Elements. 183: 2534-2540. DOI: 10.1080/10426500801967781  0.534
2008 Hanson SK, Heinekey DM, Goldberg KI. C-H bond activation by rhodium(I) phenoxide and acetate complexes: Mechanism of H-D exchange between arenes and water Organometallics. 27: 1454-1463. DOI: 10.1021/Om7012259  0.697
2007 Kloek SM, Heinekey DM, Goldberg KI. C-H bond activation by rhodium(I) hydroxide and phenoxide complexes. Angewandte Chemie (International Ed. in English). 46: 4736-8. PMID 17492734 DOI: 10.1002/Anie.200700270  0.654
2007 Egbert JD, Bullock RM, Heinekey DM. Cationic dihydrogen/dihydride complexes of osmium: Structure and dynamics Organometallics. 26: 2291-2295. DOI: 10.1021/Om0700718  0.799
2007 Heinekey DM, Mery D, Denney MC, Goldberg KI, Dietrich BL, Bennette NA, Hebden T. New catalysts for dehydrogenation of amine boranes Acs National Meeting Book of Abstracts 0.764
2006 Göttker-Schnetmann I, Heinekey DM, Brookhart M. Temperature- and solvent-dependent binding of dihydrogen in iridium pincer complexes. Journal of the American Chemical Society. 128: 17114-9. PMID 17177464 DOI: 10.1021/Ja065854J  0.41
2006 Aguirre de Carcer I, DiPasquale A, Rheingold AL, Heinekey DM. Active-site models for iron hydrogenases: reduction chemistry of dinuclear iron complexes. Inorganic Chemistry. 45: 8000-2. PMID 16999394 DOI: 10.1021/Ic0610381  0.31
2006 Denney MC, Pons V, Hebden TJ, Heinekey DM, Goldberg KI. Efficient catalysis of ammonia borane dehydrogenation. Journal of the American Chemical Society. 128: 12048-9. PMID 16967937 DOI: 10.1021/Ja062419G  0.828
2006 Matthews SL, Pons V, Heinekey DM. Silane complexes of electrophilic metal centers. Inorganic Chemistry. 45: 6453-9. PMID 16878958 DOI: 10.1021/Ic052134P  0.649
2006 Matthews SL, Heinekey DM. Photochemical generation of dihydrogen complexes of chromium and tungsten. Journal of the American Chemical Society. 128: 2615-20. PMID 16492046 DOI: 10.1021/ja057912r  0.455
2006 Schloerer N, Pons V, Gusev DG, Heinekey DM. Structure and dynamics of a compressed dihydride complex of osmium Organometallics. 25: 3481-3485. DOI: 10.1021/Om060284H  0.655
2005 Scott NM, Pons V, Stevens ED, Heinekey DM, Nolan SP. An electron-deficient iridium(III) dihydride complex capable of intramolecular C--H activation. Angewandte Chemie (International Ed. in English). 44: 2512-5. PMID 15782375 DOI: 10.1002/Anie.200463000  0.633
2005 Matthews SL, Pons V, Heinekey DM. Dihydrogen complexes of electrophilic metal centers: observation of Cr(CO)5(H2), W(CO)5(H2) and [Re(CO)5(H2)]+. Journal of the American Chemical Society. 127: 850-1. PMID 15656619 DOI: 10.1021/Ja0433370  0.697
2005 Vogt M, Pons V, Heinekey DM. Synthesis and characterization of a dicationic dihydrogen complex of iridium with a Bis-carbene ligand set Organometallics. 24: 1832-1836. DOI: 10.1021/om049045p  0.633
2005 Pons V, Denney MC, Goldberg KI, Heinekey DM. Coordination of B-N species to transition metal complexes Acs Division of Fuel Chemistry, Preprints. 50: 536-537.  0.691
2005 Pons V, Denney MC, Goldberg KI, Heinekey DM. Coordination of B-N species to transition metal complexes Acs Division of Fuel Chemistry, Preprints. 50: 536-537.  0.691
2004 Gelabert R, Moreno M, Lluch JM, Lledós A, Pons V, Heinekey DM. Synthesis and properties of compressed dihydride complexes of iridium: theoretical and spectroscopic investigations. Journal of the American Chemical Society. 126: 8813-22. PMID 15250735 DOI: 10.1021/Ja048775L  0.659
2004 Pons V, Conway SL, Green ML, Green JC, Herbert BJ, Heinekey DM. Structure and dynamics of a dihydrogen/hydride ansa molybdenocene complex. Inorganic Chemistry. 43: 3475-83. PMID 15154811 DOI: 10.1021/Ic0496875  0.66
2004 Heinekey DM, Lled?s A, Lluch JM. Elongated dihydrogen complexes: what remains of the H-H bond? Chemical Society Reviews. 33: 175-82. PMID 15026822 DOI: 10.1039/B304879A  0.46
2003 Pons V, Heinekey DM. An elongated dihydrogen complex of iridium. Journal of the American Chemical Society. 125: 8428-9. PMID 12848536 DOI: 10.1021/Ja035555J  0.657
2003 Nehring JL, Heinekey DM. Dinuclear iron isonitrile complexes: models for the iron hydrogenase active site. Inorganic Chemistry. 42: 4288-92. PMID 12844300 DOI: 10.1021/Ic034334B  0.778
2002 Wiley JS, Heinekey DM. Novel intramolecular C-H bond activation in an iridium dppm complex. Inorganic Chemistry. 41: 4961-6. PMID 12230401 DOI: 10.1021/ic0257367  0.501
2002 Taw FL, Mellows H, White PS, Hollander FJ, Bergman RG, Brookhart M, Heinekey DM. Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. Journal of the American Chemical Society. 124: 5100-8. PMID 11982375 DOI: 10.1021/Ja0165990  0.807
2002 Law JK, Mellows H, Heinekey DM. Synthesis and spectroscopic properties of elongated ruthenium dihydrogen complexes: temperature and isotope dependence of H-H distances. Journal of the American Chemical Society. 124: 1024-30. PMID 11829611 DOI: 10.1021/ja0118284  0.808
2001 Heinekey DM, Law JK, Schultz SM. Kubas complexes revisited: novel dihydride complexes of tungsten. Journal of the American Chemical Society. 123: 12728-9. PMID 11741458 DOI: 10.1021/ja016766w  0.38
2001 Law JK, Mellows H, Heinekey DM. H-H distances in elongated transition metal dihydrogen complexes: effects of temperature and isotopic substitution. Journal of the American Chemical Society. 123: 2085-6. PMID 11456843 DOI: 10.1021/ja005536z  0.79
2000 Heinekey DM, Mellows H, Pratum T. Dynamic processes in cis dihydrogen/hydride complexes of ruthenium [6] Journal of the American Chemical Society. 122: 6498-6499. DOI: 10.1021/ja993952h  0.758
1999 Heinekey DM, Radzewich CE. Synthesis, structure, and reactivity of ansa-rhenocene complexes Organometallics. 18: 3070-3074.  0.344
1998 Luther TA, Heinekey DM. Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of Osmium and Ruthenium. Inorganic Chemistry. 37: 127-132. PMID 11670270  0.468
1997 Oldham WJ, Hinkle AS, Heinekey DM. Synthesis and characterization of hydrotris(pyrazolyl)borate dihydrogen/hydride complexes of rhodium and iridium Journal of the American Chemical Society. 119: 11028-11036. DOI: 10.1021/ja971627t  0.416
1997 Luther TA, Heinekey DM. Determination of the H-H distance in transition-metal dihydrogen complexes: Effects of high magnetic fields Journal of the American Chemical Society. 119: 6688-6689. DOI: 10.1021/ja970954y  0.316
1997 Heinekey DM, Radzewich CE, Voges MH, Schomber BM. Cationic hydrogen complexes of rhenium. 2. Synthesis, reactivity, and competition studies Journal of the American Chemical Society. 119: 4172-4181. DOI: 10.1021/ja9643228  0.382
1997 Oldham WJ, Heinekey DM. Synthesis of ethylene hydridotris(1-pyrazolyl)borate triphenylphosphine complexes of rhodium and iridium and their reactions with hydrogen Organometallics. 16: 467-474.  0.393
1996 Heinekey DM, Luther TA. Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of Osmium. Inorganic Chemistry. 35: 4396-4399. PMID 11666657  0.39
1996 Heinekey DM, Oldham W.J. J, Wiley JS. Cyclometalation of a pyrazolyl arm in hydridotris(1-pyrazolyl)borate and tris(1-pyrazolyl)methane complexes of iridium Journal of the American Chemical Society. 118: 12842-12843. DOI: 10.1021/ja962320h  0.397
1996 Heinekey DM, Voges MH, Barnhart DM. Rhenium dihydrogen complexes with isonitrile coligands: Novel displacement of chloride by hydrogen Journal of the American Chemical Society. 118: 10792-10802. DOI: 10.1021/ja961994p  0.369
1996 Heinekey DM, Hinkle AS, Close JD. Quantum mechanical exchange coupling in iridium trihydride complexes Journal of the American Chemical Society. 118: 5353-5361. DOI: 10.1021/Ja952142C  0.358
1995 Heinekey DM, Fine DA, Harper TGP, Michel ST. Dinuclear dihydride complexes of iridium: a study of structure and dynamics Canadian Journal of Chemistry. 73: 1116-1125. DOI: 10.1139/v95-138  0.459
1994 Heinekey DM, Schomber BM, Radzewich CE. Cationic Hydrogen Complexes of Rhenium Journal of the American Chemical Society. 116: 4515-4516. DOI: 10.1021/ja00089a066  0.36
1994 Heinekey DM, Liegeois A, Van Roon M. Cationic dihydrogen complexes of rhodium and cobalt: A reinvestigation Journal of the American Chemical Society. 116: 8388-8389.  0.407
1991 Albeniz AC, Heinekey DM, Crabtree RH. Dihydrogen complexes in catalysis: Isotope exchange reactions Inorganic Chemistry. 30: 3632-3635.  0.336
1990 Ball RG, Graham WAG, Heinekey DM, Hoyano JK, McMaster AD, Mattson BM, Michel ST. Synthesis and structure of [(η-C5Me5)Ir(CO)]2 Inorganic Chemistry. 29: 2023-2025.  0.669
1990 Crocker LS, Mattson BM, Heinekey DM. Mechanism for thermal generation of transient rhenium(0) radicals. Reaction of a (triphenylmethyl)rhenium complex with two-electron ligands Organometallics. 9: 1011-1016.  0.692
1989 Chinn MS, Heinekey DM, Payne NG, Sofield CD. Highly reactive dihydrogen complexes of ruthenium and rhenium: Facile heterolysis of coordinated dihydrogen Organometallics. 8: 1824-1826.  0.41
1989 Heinekey DM, Michel ST, Schulte GK. Stereoselective intramolecular C-H bond activation in a dinuclear iridium complex Organometallics. 8: 1241-1246.  0.408
1988 Crocker LS, Gould GL, Heinekey DM. Improved synthesis of carbonylrhenium Journal of Organometallic Chemistry. 342: 243-244. DOI: 10.1016/S0022-328X(00)99461-0  0.404
1988 Heinekey DM, Payne NG, Schulte GK. Trihydrogen complexes of iridium Journal of the American Chemical Society. 110: 2303-2305.  0.389
1987 Chinn MS, Heinekey DM. Synthesis and properties of a series of ruthenium dihydrogen complexes Journal of the American Chemical Society. 109: 5865-5867. DOI: 10.1021/ja00253a057  0.333
1986 Del Paggio AA, Muetterties EL, Heinekey DM, Day VW, Day CS. Chemistry of (η5-C5Me5)Ir(CO)2. 1. Metal-metal bond formation employing a basic metal center Organometallics. 5: 575-581.  0.454
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